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Phosphine-substituted Cubane Clusters with the Mo3S4Ga Core. / Petrov, P. A.; Sukhikh, T. S.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 45, No. 5, 01.05.2019, p. 333-339.

Research output: Contribution to journal › Article › peer-review

Harvard

Petrov, PA & Sukhikh, TS 2019, 'Phosphine-substituted Cubane Clusters with the Mo3S4Ga Core', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 45, no. 5, pp. 333-339. https://doi.org/10.1134/S1070328419040079

APA

Petrov, P. A., & Sukhikh, T. S. (2019). Phosphine-substituted Cubane Clusters with the Mo3S4Ga Core. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 45(5), 333-339. https://doi.org/10.1134/S1070328419040079

Vancouver

Petrov PA, Sukhikh TS. Phosphine-substituted Cubane Clusters with the Mo3S4Ga Core. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2019 May 1;45(5):333-339. doi: 10.1134/S1070328419040079

Author

Petrov, P. A. ; Sukhikh, T. S. / Phosphine-substituted Cubane Clusters with the Mo3S4Ga Core. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2019 ; Vol. 45, No. 5. pp. 333-339.

BibTeX

@article{3c2361068f10422d8ec72e9d6e14149f,
title = "Phosphine-substituted Cubane Clusters with the Mo3S4Ga Core",
abstract = "The reaction of cationic clusters [Mo3S4(Dppet)3X3]X (I; Dppet = cis-1,2-bis(diphenylphosphino)ethylene; X = Cl, Br) with gallium metal in tetrahydrofuran (THF) affords cubane-like clusters [Mo3S4(GaX)(Dppet)3X3] (IIa, X = Cl; IIb, X = Br). In the synthesis of IIb, the crystals of the cationic cluster [Mo3S4(Dppet)3Br3](GaBr4) (III) were isolated from the mother liquor. The structures of complexes IIa ∙ 1.5THF, IIb ∙ 1.5THF, III ∙ 1.625THF, and [Mo3S4(Dppe)3Br3](GaBr4) ∙ 2THF (IV ∙ 2THF; Dppe = 1,2-bis(diphenylphosphino)ethane) were established by X-ray diffraction (CIF files CCDC № 1851341–1851344).",
keywords = "clusters, gallium, molybdenum, phosphines, X-ay diffraction",
author = "Petrov, {P. A.} and Sukhikh, {T. S.}",
year = "2019",
month = may,
day = "1",
doi = "10.1134/S1070328419040079",
language = "English",
volume = "45",
pages = "333--339",
journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",
issn = "1070-3284",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "5",

}

RIS

TY - JOUR

T1 - Phosphine-substituted Cubane Clusters with the Mo3S4Ga Core

AU - Petrov, P. A.

AU - Sukhikh, T. S.

PY - 2019/5/1

Y1 - 2019/5/1

N2 - The reaction of cationic clusters [Mo3S4(Dppet)3X3]X (I; Dppet = cis-1,2-bis(diphenylphosphino)ethylene; X = Cl, Br) with gallium metal in tetrahydrofuran (THF) affords cubane-like clusters [Mo3S4(GaX)(Dppet)3X3] (IIa, X = Cl; IIb, X = Br). In the synthesis of IIb, the crystals of the cationic cluster [Mo3S4(Dppet)3Br3](GaBr4) (III) were isolated from the mother liquor. The structures of complexes IIa ∙ 1.5THF, IIb ∙ 1.5THF, III ∙ 1.625THF, and [Mo3S4(Dppe)3Br3](GaBr4) ∙ 2THF (IV ∙ 2THF; Dppe = 1,2-bis(diphenylphosphino)ethane) were established by X-ray diffraction (CIF files CCDC № 1851341–1851344).

AB - The reaction of cationic clusters [Mo3S4(Dppet)3X3]X (I; Dppet = cis-1,2-bis(diphenylphosphino)ethylene; X = Cl, Br) with gallium metal in tetrahydrofuran (THF) affords cubane-like clusters [Mo3S4(GaX)(Dppet)3X3] (IIa, X = Cl; IIb, X = Br). In the synthesis of IIb, the crystals of the cationic cluster [Mo3S4(Dppet)3Br3](GaBr4) (III) were isolated from the mother liquor. The structures of complexes IIa ∙ 1.5THF, IIb ∙ 1.5THF, III ∙ 1.625THF, and [Mo3S4(Dppe)3Br3](GaBr4) ∙ 2THF (IV ∙ 2THF; Dppe = 1,2-bis(diphenylphosphino)ethane) were established by X-ray diffraction (CIF files CCDC № 1851341–1851344).

KW - clusters

KW - gallium

KW - molybdenum

KW - phosphines

KW - X-ay diffraction

UR - http://www.scopus.com/inward/record.url?scp=85066953548&partnerID=8YFLogxK

U2 - 10.1134/S1070328419040079

DO - 10.1134/S1070328419040079

M3 - Article

AN - SCOPUS:85066953548

VL - 45

SP - 333

EP - 339

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 5

ER -

ID: 20531840