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[Pd(acac)(L)2][BF4] (L = morpholine, diethylamine, dibutylamine, dioctylamine) : Synthesis, structure and their catalytic activity. / Suslov, D. S.; Bykov, M. V.; Ratovskii, G. V. et al.

In: Journal of Molecular Structure, Vol. 1133, 05.04.2017, p. 411-421.

Research output: Contribution to journal › Article › peer-review

Harvard

Suslov, DS, Bykov, MV, Ratovskii, GV, Abramov, PA, Pahomova, MV, Ushakov, IA, Voronov, VK & Tkach, VS 2017, '[Pd(acac)(L)2][BF4] (L = morpholine, diethylamine, dibutylamine, dioctylamine): Synthesis, structure and their catalytic activity', Journal of Molecular Structure, vol. 1133, pp. 411-421. https://doi.org/10.1016/j.molstruc.2016.12.025

APA

Suslov, D. S., Bykov, M. V., Ratovskii, G. V., Abramov, P. A., Pahomova, M. V., Ushakov, I. A., Voronov, V. K., & Tkach, V. S. (2017). [Pd(acac)(L)2][BF4] (L = morpholine, diethylamine, dibutylamine, dioctylamine): Synthesis, structure and their catalytic activity. Journal of Molecular Structure, 1133, 411-421. https://doi.org/10.1016/j.molstruc.2016.12.025

Vancouver

Suslov DS, Bykov MV, Ratovskii GV, Abramov PA, Pahomova MV, Ushakov IA et al. [Pd(acac)(L)2][BF4] (L = morpholine, diethylamine, dibutylamine, dioctylamine): Synthesis, structure and their catalytic activity. Journal of Molecular Structure. 2017 Apr 5;1133:411-421. doi: 10.1016/j.molstruc.2016.12.025

Author

Suslov, D. S. ; Bykov, M. V. ; Ratovskii, G. V. et al. / [Pd(acac)(L)2][BF4] (L = morpholine, diethylamine, dibutylamine, dioctylamine) : Synthesis, structure and their catalytic activity. In: Journal of Molecular Structure. 2017 ; Vol. 1133. pp. 411-421.

BibTeX

@article{aa5f752261c44073aa4183141145e18d,
title = "[Pd(acac)(L)2][BF4] (L = morpholine, diethylamine, dibutylamine, dioctylamine): Synthesis, structure and their catalytic activity",
abstract = "Cationic acetylacetonate bis(secondary amine) palladium (II) complexes were synthesized by nitrile substitution of [Pd(acac)(MeCN)2][BF4] with L (L = morpholine, diethylamine, dibutylamine, dioctylamine) which yielded [Pd(acac)(L)2][BF4] as a mononuclear species with chelating acac ligand. An X-ray diffraction, NMR, IR and DFT study of [Pd(acac){morpholine}2][BF4] establishes the presence of hydrogen bonding between the morpholine ligand and [BF4]− anion. Crystallographic defects in the crystal and presence of pseudocrystalline structure in solution of [Pd(acac){morpholine}2][BF4] were assumed to explain IR spectra features. Preliminary investigations into the polymerization of norbornene, dimerization of styrene, and telomerization of 1,3-butadiene with diethylamine were performed.",
keywords = "1,3-Butadiene, Acetylacetonate, Norbornene, Palladium, Secondary amine, Styrene, ALPHA-OLEFINS, TRANSITION-METAL-COMPLEXES, NICKEL(II) COMPLEXES, PALLADIUM(II)-ACETYLACETONATE COMPLEXES, ORDER REGULAR APPROXIMATION, ADDITION POLYMERIZATION, LIGANDS SYNTHESIS, BASIS-SETS, CATIONIC PALLADIUM(II) COMPOUNDS, SELECTIVE LINEAR DIMERIZATION",
author = "Suslov, {D. S.} and Bykov, {M. V.} and Ratovskii, {G. V.} and Abramov, {P. A.} and Pahomova, {M. V.} and Ushakov, {I. A.} and Voronov, {V. K.} and Tkach, {V. S.}",
note = "Publisher Copyright: {\textcopyright} 2016 Elsevier B.V.",
year = "2017",
month = apr,
day = "5",
doi = "10.1016/j.molstruc.2016.12.025",
language = "English",
volume = "1133",
pages = "411--421",
journal = "Journal of Molecular Structure",
issn = "0022-2860",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - [Pd(acac)(L)2][BF4] (L = morpholine, diethylamine, dibutylamine, dioctylamine)

T2 - Synthesis, structure and their catalytic activity

AU - Suslov, D. S.

AU - Bykov, M. V.

AU - Ratovskii, G. V.

AU - Abramov, P. A.

AU - Pahomova, M. V.

AU - Ushakov, I. A.

AU - Voronov, V. K.

AU - Tkach, V. S.

N1 - Publisher Copyright: © 2016 Elsevier B.V.

PY - 2017/4/5

Y1 - 2017/4/5

N2 - Cationic acetylacetonate bis(secondary amine) palladium (II) complexes were synthesized by nitrile substitution of [Pd(acac)(MeCN)2][BF4] with L (L = morpholine, diethylamine, dibutylamine, dioctylamine) which yielded [Pd(acac)(L)2][BF4] as a mononuclear species with chelating acac ligand. An X-ray diffraction, NMR, IR and DFT study of [Pd(acac){morpholine}2][BF4] establishes the presence of hydrogen bonding between the morpholine ligand and [BF4]− anion. Crystallographic defects in the crystal and presence of pseudocrystalline structure in solution of [Pd(acac){morpholine}2][BF4] were assumed to explain IR spectra features. Preliminary investigations into the polymerization of norbornene, dimerization of styrene, and telomerization of 1,3-butadiene with diethylamine were performed.

AB - Cationic acetylacetonate bis(secondary amine) palladium (II) complexes were synthesized by nitrile substitution of [Pd(acac)(MeCN)2][BF4] with L (L = morpholine, diethylamine, dibutylamine, dioctylamine) which yielded [Pd(acac)(L)2][BF4] as a mononuclear species with chelating acac ligand. An X-ray diffraction, NMR, IR and DFT study of [Pd(acac){morpholine}2][BF4] establishes the presence of hydrogen bonding between the morpholine ligand and [BF4]− anion. Crystallographic defects in the crystal and presence of pseudocrystalline structure in solution of [Pd(acac){morpholine}2][BF4] were assumed to explain IR spectra features. Preliminary investigations into the polymerization of norbornene, dimerization of styrene, and telomerization of 1,3-butadiene with diethylamine were performed.

KW - 1,3-Butadiene

KW - Acetylacetonate

KW - Norbornene

KW - Palladium

KW - Secondary amine

KW - Styrene

KW - ALPHA-OLEFINS

KW - TRANSITION-METAL-COMPLEXES

KW - NICKEL(II) COMPLEXES

KW - PALLADIUM(II)-ACETYLACETONATE COMPLEXES

KW - ORDER REGULAR APPROXIMATION

KW - ADDITION POLYMERIZATION

KW - LIGANDS SYNTHESIS

KW - BASIS-SETS

KW - CATIONIC PALLADIUM(II) COMPOUNDS

KW - SELECTIVE LINEAR DIMERIZATION

UR - http://www.scopus.com/inward/record.url?scp=85006791159&partnerID=8YFLogxK

U2 - 10.1016/j.molstruc.2016.12.025

DO - 10.1016/j.molstruc.2016.12.025

M3 - Article

AN - SCOPUS:85006791159

VL - 1133

SP - 411

EP - 421

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

SN - 0022-2860

ER -

ID: 10042356