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Oxidative Transformations of Ethane and Ethylene on VMoTeNbO Catalysts. / Bondareva, V. M.; Lazareva, E. V.; Kardash, T. Yu et al.

In: Russian Journal of Applied Chemistry, Vol. 92, No. 1, 01.01.2019, p. 122-127.

Research output: Contribution to journal › Article › peer-review

Harvard

Bondareva, VM, Lazareva, EV, Kardash, TY & Sobolev, VI 2019, 'Oxidative Transformations of Ethane and Ethylene on VMoTeNbO Catalysts', Russian Journal of Applied Chemistry, vol. 92, no. 1, pp. 122-127. https://doi.org/10.1134/S10704272190100178

APA

Bondareva, V. M., Lazareva, E. V., Kardash, T. Y., & Sobolev, V. I. (2019). Oxidative Transformations of Ethane and Ethylene on VMoTeNbO Catalysts. Russian Journal of Applied Chemistry, 92(1), 122-127. https://doi.org/10.1134/S10704272190100178

Vancouver

Bondareva VM, Lazareva EV, Kardash TY, Sobolev VI. Oxidative Transformations of Ethane and Ethylene on VMoTeNbO Catalysts. Russian Journal of Applied Chemistry. 2019 Jan 1;92(1):122-127. doi: 10.1134/S10704272190100178

Author

Bondareva, V. M. ; Lazareva, E. V. ; Kardash, T. Yu et al. / Oxidative Transformations of Ethane and Ethylene on VMoTeNbO Catalysts. In: Russian Journal of Applied Chemistry. 2019 ; Vol. 92, No. 1. pp. 122-127.

BibTeX

@article{2bbfbaf6cf6f41ee8dea9c6ed68ff520,
title = "Oxidative Transformations of Ethane and Ethylene on VMoTeNbO Catalysts",
abstract = "Comparative studies of oxidative transformations of ethane and ethylene were conducted on multi-component oxide catalysts of the preset cationic composition, V 0.3Mo 1Te 0.23Nb 0.12, differing in the final calcination temperature. At 400°С in the reaction mixture with the hydrocarbon:oxygen ratio of 1 : 1, all the synthesized catalysts were more active in oxidative dehydrogenation of ethane than in oxidation of ethylene. The catalyst calcination temperature determining the qualitative and quantitative phase composition influenceD the ratio of the overall ethane and ethylene transformation rates. The highest ethylene yield in oxidative dehydrogenation of ethane was attained on the catalysts calcined in the temperature interval 550°C - 650°C, which is due to the formation of the maximal amount of the active M1 phase. ",
keywords = "ethane, ethylene, oxidative dehydrogenation, VMoTeNbO catalysts, SELECTIVE OXIDATION, DEHYDROGENATION, M1, M2, BEHAVIOR, PROPANE, MIXED-OXIDE CATALYSTS",
author = "Bondareva, {V. M.} and Lazareva, {E. V.} and Kardash, {T. Yu} and Sobolev, {V. I.}",
year = "2019",
month = jan,
day = "1",
doi = "10.1134/S10704272190100178",
language = "English",
volume = "92",
pages = "122--127",
journal = "Russian Journal of Applied Chemistry",
issn = "1070-4272",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "1",

}

RIS

TY - JOUR

T1 - Oxidative Transformations of Ethane and Ethylene on VMoTeNbO Catalysts

AU - Bondareva, V. M.

AU - Lazareva, E. V.

AU - Kardash, T. Yu

AU - Sobolev, V. I.

PY - 2019/1/1

Y1 - 2019/1/1

N2 - Comparative studies of oxidative transformations of ethane and ethylene were conducted on multi-component oxide catalysts of the preset cationic composition, V 0.3Mo 1Te 0.23Nb 0.12, differing in the final calcination temperature. At 400°С in the reaction mixture with the hydrocarbon:oxygen ratio of 1 : 1, all the synthesized catalysts were more active in oxidative dehydrogenation of ethane than in oxidation of ethylene. The catalyst calcination temperature determining the qualitative and quantitative phase composition influenceD the ratio of the overall ethane and ethylene transformation rates. The highest ethylene yield in oxidative dehydrogenation of ethane was attained on the catalysts calcined in the temperature interval 550°C - 650°C, which is due to the formation of the maximal amount of the active M1 phase.

AB - Comparative studies of oxidative transformations of ethane and ethylene were conducted on multi-component oxide catalysts of the preset cationic composition, V 0.3Mo 1Te 0.23Nb 0.12, differing in the final calcination temperature. At 400°С in the reaction mixture with the hydrocarbon:oxygen ratio of 1 : 1, all the synthesized catalysts were more active in oxidative dehydrogenation of ethane than in oxidation of ethylene. The catalyst calcination temperature determining the qualitative and quantitative phase composition influenceD the ratio of the overall ethane and ethylene transformation rates. The highest ethylene yield in oxidative dehydrogenation of ethane was attained on the catalysts calcined in the temperature interval 550°C - 650°C, which is due to the formation of the maximal amount of the active M1 phase.

KW - ethane

KW - ethylene

KW - oxidative dehydrogenation

KW - VMoTeNbO catalysts

KW - SELECTIVE OXIDATION

KW - DEHYDROGENATION

KW - M1

KW - M2

KW - BEHAVIOR

KW - PROPANE

KW - MIXED-OXIDE CATALYSTS

UR - http://www.scopus.com/inward/record.url?scp=85064848183&partnerID=8YFLogxK

U2 - 10.1134/S10704272190100178

DO - 10.1134/S10704272190100178

M3 - Article

AN - SCOPUS:85064848183

VL - 92

SP - 122

EP - 127

JO - Russian Journal of Applied Chemistry

JF - Russian Journal of Applied Chemistry

SN - 1070-4272

IS - 1

ER -

ID: 19646717