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Orientation-controlled, low-temperature plasma growth and applications of h-BN nanosheets. / Merenkov, Ivan Sergeevich; Myshenkov, Mikhail Sergeevich; Zhukov, Yuri Mikhailovich et al.

In: Nano Research, Vol. 12, No. 1, 01.01.2019, p. 91-99.

Research output: Contribution to journal › Article › peer-review

Harvard

Merenkov, IS, Myshenkov, MS, Zhukov, YM, Sato, Y, Frolova, TS, Danilov, DV, Kasatkin, IA, Medvedev, OS, Pushkarev, RV, Sinitsyna, OI, Terauchi, M, Zvereva, IA, Kosinova, ML & Ostrikov, K 2019, 'Orientation-controlled, low-temperature plasma growth and applications of h-BN nanosheets', Nano Research, vol. 12, no. 1, pp. 91-99. https://doi.org/10.1007/s12274-018-2185-7

APA

Merenkov, I. S., Myshenkov, M. S., Zhukov, Y. M., Sato, Y., Frolova, T. S., Danilov, D. V., Kasatkin, I. A., Medvedev, O. S., Pushkarev, R. V., Sinitsyna, O. I., Terauchi, M., Zvereva, I. A., Kosinova, M. L., & Ostrikov, K. (2019). Orientation-controlled, low-temperature plasma growth and applications of h-BN nanosheets. Nano Research, 12(1), 91-99. https://doi.org/10.1007/s12274-018-2185-7

Vancouver

Merenkov IS, Myshenkov MS, Zhukov YM, Sato Y, Frolova TS, Danilov DV et al. Orientation-controlled, low-temperature plasma growth and applications of h-BN nanosheets. Nano Research. 2019 Jan 1;12(1):91-99. doi: 10.1007/s12274-018-2185-7

Author

Merenkov, Ivan Sergeevich ; Myshenkov, Mikhail Sergeevich ; Zhukov, Yuri Mikhailovich et al. / Orientation-controlled, low-temperature plasma growth and applications of h-BN nanosheets. In: Nano Research. 2019 ; Vol. 12, No. 1. pp. 91-99.

BibTeX

@article{3a3e94ef3a20499e8b8815496c88931a,
title = "Orientation-controlled, low-temperature plasma growth and applications of h-BN nanosheets",
abstract = "Dimensionality and orientation of hexagonal boron nitride (h-BN) nanosheets are promising to create and control their unique properties for diverse applications. However, low-temperature deposition of vertically oriented h-BN nanosheets is a significant challenge. Here we report on the low-temperature plasma synthesis of maze-like h-BN nanowalls (BNNWs) from a mixture of triethylamine borane (TEAB) and ammonia at temperatures as low as 400 °C. The maze-like BNNWs contained vertically aligned stacks of h-BN nanosheets. Wavy h-BN nanowalls with randomly oriented nanocrystalline structure are also fabricated. Simple and effective control of morphological type of BNNWs by the deposition temperature is demonstrated. Despite the lower synthesis temperature, thermal stability and oxidation resistivity of the maze-like BNNWs are higher than for the wavy nanowalls. The structure and oxidation of the nanowalls was found to be the critical factor for their thermal stability and controlled luminescence properties. Cytotoxic study demonstrated significant antibacterial effect of both maze-like and wavy h-BN nanowalls against E. coli. The reported results reveal a significant potential of h-BN nanowalls for a broad range of applications from electronics to biomedicine.",
keywords = "boron nitride nanosheets, chemical vapor deposition, cytotoxicity, light emission, nanowalls, thermal stability, THIN-FILMS, CHEMICAL-VAPOR-DEPOSITION, FINE-STRUCTURE, CARBON NANOWALLS, PHOTOELECTRON, X-RAY-ABSORPTION, GRAPHENE, VERTICALLY ALIGNED LAYERS, BORON-NITRIDE NANOTUBES, PECVD SYNTHESIS",
author = "Merenkov, {Ivan Sergeevich} and Myshenkov, {Mikhail Sergeevich} and Zhukov, {Yuri Mikhailovich} and Yohei Sato and Frolova, {Tatyana Sergeevna} and Danilov, {Denis Vasilevich} and Kasatkin, {Igor Alekseevich} and Medvedev, {Oleg Sergeevich} and Pushkarev, {Roman Vladimirovich} and Sinitsyna, {Olga Ivanovna} and Masami Terauchi and Zvereva, {Irina Alekseevna} and Kosinova, {Marina Leonidovna} and Ken Ostrikov",
year = "2019",
month = jan,
day = "1",
doi = "10.1007/s12274-018-2185-7",
language = "English",
volume = "12",
pages = "91--99",
journal = "Nano Research",
issn = "1998-0124",
publisher = "Press of Tsinghua University",
number = "1",

}

RIS

TY - JOUR

T1 - Orientation-controlled, low-temperature plasma growth and applications of h-BN nanosheets

AU - Merenkov, Ivan Sergeevich

AU - Myshenkov, Mikhail Sergeevich

AU - Zhukov, Yuri Mikhailovich

AU - Sato, Yohei

AU - Frolova, Tatyana Sergeevna

AU - Danilov, Denis Vasilevich

AU - Kasatkin, Igor Alekseevich

AU - Medvedev, Oleg Sergeevich

AU - Pushkarev, Roman Vladimirovich

AU - Sinitsyna, Olga Ivanovna

AU - Terauchi, Masami

AU - Zvereva, Irina Alekseevna

AU - Kosinova, Marina Leonidovna

AU - Ostrikov, Ken

PY - 2019/1/1

Y1 - 2019/1/1

N2 - Dimensionality and orientation of hexagonal boron nitride (h-BN) nanosheets are promising to create and control their unique properties for diverse applications. However, low-temperature deposition of vertically oriented h-BN nanosheets is a significant challenge. Here we report on the low-temperature plasma synthesis of maze-like h-BN nanowalls (BNNWs) from a mixture of triethylamine borane (TEAB) and ammonia at temperatures as low as 400 °C. The maze-like BNNWs contained vertically aligned stacks of h-BN nanosheets. Wavy h-BN nanowalls with randomly oriented nanocrystalline structure are also fabricated. Simple and effective control of morphological type of BNNWs by the deposition temperature is demonstrated. Despite the lower synthesis temperature, thermal stability and oxidation resistivity of the maze-like BNNWs are higher than for the wavy nanowalls. The structure and oxidation of the nanowalls was found to be the critical factor for their thermal stability and controlled luminescence properties. Cytotoxic study demonstrated significant antibacterial effect of both maze-like and wavy h-BN nanowalls against E. coli. The reported results reveal a significant potential of h-BN nanowalls for a broad range of applications from electronics to biomedicine.

AB - Dimensionality and orientation of hexagonal boron nitride (h-BN) nanosheets are promising to create and control their unique properties for diverse applications. However, low-temperature deposition of vertically oriented h-BN nanosheets is a significant challenge. Here we report on the low-temperature plasma synthesis of maze-like h-BN nanowalls (BNNWs) from a mixture of triethylamine borane (TEAB) and ammonia at temperatures as low as 400 °C. The maze-like BNNWs contained vertically aligned stacks of h-BN nanosheets. Wavy h-BN nanowalls with randomly oriented nanocrystalline structure are also fabricated. Simple and effective control of morphological type of BNNWs by the deposition temperature is demonstrated. Despite the lower synthesis temperature, thermal stability and oxidation resistivity of the maze-like BNNWs are higher than for the wavy nanowalls. The structure and oxidation of the nanowalls was found to be the critical factor for their thermal stability and controlled luminescence properties. Cytotoxic study demonstrated significant antibacterial effect of both maze-like and wavy h-BN nanowalls against E. coli. The reported results reveal a significant potential of h-BN nanowalls for a broad range of applications from electronics to biomedicine.

KW - boron nitride nanosheets

KW - chemical vapor deposition

KW - cytotoxicity

KW - light emission

KW - nanowalls

KW - thermal stability

KW - THIN-FILMS

KW - CHEMICAL-VAPOR-DEPOSITION

KW - FINE-STRUCTURE

KW - CARBON NANOWALLS

KW - PHOTOELECTRON

KW - X-RAY-ABSORPTION

KW - GRAPHENE

KW - VERTICALLY ALIGNED LAYERS

KW - BORON-NITRIDE NANOTUBES

KW - PECVD SYNTHESIS

UR - http://www.scopus.com/inward/record.url?scp=85053426396&partnerID=8YFLogxK

U2 - 10.1007/s12274-018-2185-7

DO - 10.1007/s12274-018-2185-7

M3 - Article

AN - SCOPUS:85053426396

VL - 12

SP - 91

EP - 99

JO - Nano Research

JF - Nano Research

SN - 1998-0124

IS - 1

ER -

ID: 16603328