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Optimal Binding of Acetylene to a Nitro-Decorated Metal-Organic Framework. / Duong, Thien D.; Sapchenko, Sergey A.; Da Silva, Ivan et al.

In: Journal of the American Chemical Society, Vol. 140, No. 47, 28.11.2018, p. 16006-16009.

Research output: Contribution to journal › Article › peer-review

Harvard

Duong, TD, Sapchenko, SA, Da Silva, I, Godfrey, HGW, Cheng, Y, Daemen, LL, Manuel, P, Ramirez-Cuesta, AJ, Yang, S & Schröder, M 2018, 'Optimal Binding of Acetylene to a Nitro-Decorated Metal-Organic Framework', Journal of the American Chemical Society, vol. 140, no. 47, pp. 16006-16009. https://doi.org/10.1021/jacs.8b08504

APA

Duong, T. D., Sapchenko, S. A., Da Silva, I., Godfrey, H. G. W., Cheng, Y., Daemen, L. L., Manuel, P., Ramirez-Cuesta, A. J., Yang, S., & Schröder, M. (2018). Optimal Binding of Acetylene to a Nitro-Decorated Metal-Organic Framework. Journal of the American Chemical Society, 140(47), 16006-16009. https://doi.org/10.1021/jacs.8b08504

Vancouver

Duong TD, Sapchenko SA, Da Silva I, Godfrey HGW, Cheng Y, Daemen LL et al. Optimal Binding of Acetylene to a Nitro-Decorated Metal-Organic Framework. Journal of the American Chemical Society. 2018 Nov 28;140(47):16006-16009. doi: 10.1021/jacs.8b08504

Author

Duong, Thien D. ; Sapchenko, Sergey A. ; Da Silva, Ivan et al. / Optimal Binding of Acetylene to a Nitro-Decorated Metal-Organic Framework. In: Journal of the American Chemical Society. 2018 ; Vol. 140, No. 47. pp. 16006-16009.

BibTeX

@article{db4f315095df44819e6b9ff1b836c3ad,
title = "Optimal Binding of Acetylene to a Nitro-Decorated Metal-Organic Framework",
abstract = "We report the first example of crystallographic observation of acetylene binding to -NO2 groups in a metal-organic framework (MOF). Functionalization of MFM-102 with -NO2 groups on phenyl groups leads to a 15% reduction in BET surface area in MFM-102-NO2. However, this is coupled to a 28% increase in acetylene adsorption to 192 cm3 g-1 at 298 K and 1 bar, comparable to other leading porous materials. Neutron diffraction and inelastic scattering experiments reveal the role of -NO2 groups, in cooperation with open metal sites, in the binding of acetylene in MFM-102-NO2.",
keywords = "ADSORPTION PROPERTIES, C2H2 ADSORPTION, CH4 STORAGE, CO2 ADSORPTION, METHANE, MOFS, SEPARATION, SITES, STORAGE CAPACITY",
author = "Duong, {Thien D.} and Sapchenko, {Sergey A.} and {Da Silva}, Ivan and Godfrey, {Harry G.W.} and Yongqiang Cheng and Daemen, {Luke L.} and Pascal Manuel and Ramirez-Cuesta, {Anibal J.} and Sihai Yang and Martin Schr{\"o}der",
year = "2018",
month = nov,
day = "28",
doi = "10.1021/jacs.8b08504",
language = "English",
volume = "140",
pages = "16006--16009",
journal = "Journal of the American Chemical Society",
issn = "0002-7863",
publisher = "American Chemical Society",
number = "47",

}

RIS

TY - JOUR

T1 - Optimal Binding of Acetylene to a Nitro-Decorated Metal-Organic Framework

AU - Duong, Thien D.

AU - Sapchenko, Sergey A.

AU - Da Silva, Ivan

AU - Godfrey, Harry G.W.

AU - Cheng, Yongqiang

AU - Daemen, Luke L.

AU - Manuel, Pascal

AU - Ramirez-Cuesta, Anibal J.

AU - Yang, Sihai

AU - Schröder, Martin

PY - 2018/11/28

Y1 - 2018/11/28

N2 - We report the first example of crystallographic observation of acetylene binding to -NO2 groups in a metal-organic framework (MOF). Functionalization of MFM-102 with -NO2 groups on phenyl groups leads to a 15% reduction in BET surface area in MFM-102-NO2. However, this is coupled to a 28% increase in acetylene adsorption to 192 cm3 g-1 at 298 K and 1 bar, comparable to other leading porous materials. Neutron diffraction and inelastic scattering experiments reveal the role of -NO2 groups, in cooperation with open metal sites, in the binding of acetylene in MFM-102-NO2.

AB - We report the first example of crystallographic observation of acetylene binding to -NO2 groups in a metal-organic framework (MOF). Functionalization of MFM-102 with -NO2 groups on phenyl groups leads to a 15% reduction in BET surface area in MFM-102-NO2. However, this is coupled to a 28% increase in acetylene adsorption to 192 cm3 g-1 at 298 K and 1 bar, comparable to other leading porous materials. Neutron diffraction and inelastic scattering experiments reveal the role of -NO2 groups, in cooperation with open metal sites, in the binding of acetylene in MFM-102-NO2.

KW - ADSORPTION PROPERTIES

KW - C2H2 ADSORPTION

KW - CH4 STORAGE

KW - CO2 ADSORPTION

KW - METHANE

KW - MOFS

KW - SEPARATION

KW - SITES

KW - STORAGE CAPACITY

UR - http://www.scopus.com/inward/record.url?scp=85056789220&partnerID=8YFLogxK

U2 - 10.1021/jacs.8b08504

DO - 10.1021/jacs.8b08504

M3 - Article

C2 - 30285424

AN - SCOPUS:85056789220

VL - 140

SP - 16006

EP - 16009

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 47

ER -

ID: 17472742