On the Cause of Solvent Effect in PtIVCl62− Photochemistry

Standard

On the Cause of Solvent Effect in Pt^IVCl₆²⁻ Photochemistry. / Glebov, E. M.; Plyusnin, V. F.

In: High Energy Chemistry, Vol. 55, No. 3, 05.2021, p. 203-211.

Research output: Contribution to journal › Article › peer-review

Harvard

Glebov, EM & Plyusnin, VF 2021, 'On the Cause of Solvent Effect in Pt^IVCl₆²⁻ Photochemistry', High Energy Chemistry, vol. 55, no. 3, pp. 203-211. https://doi.org/10.1134/S0018143921030036

APA

Glebov, E. M., & Plyusnin, V. F. (2021). On the Cause of Solvent Effect in Pt^IVCl₆²⁻ Photochemistry. High Energy Chemistry, 55(3), 203-211. https://doi.org/10.1134/S0018143921030036

Vancouver

Glebov EM , Plyusnin VF. On the Cause of Solvent Effect in Pt^IVCl₆²⁻ Photochemistry. High Energy Chemistry. 2021 May;55(3):203-211. doi: 10.1134/S0018143921030036

Author

Glebov, E. M. ; Plyusnin, V. F. / On the Cause of Solvent Effect in Pt^IVCl₆²⁻ Photochemistry. In: High Energy Chemistry. 2021 ; Vol. 55, No. 3. pp. 203-211.

BibTeX

@article{21251cc54342490faa05a255d0d4ca9a,

title = "On the Cause of Solvent Effect in PtIVCl62− Photochemistry",

abstract = "The photochemistry of hexachloroplatinate(IV) paradoxically depends on the solvent. Chain photosolvation of the complex occurs in water, chloroform, and acetonitrile, with the photolysis mechanism being quite identical in water and chloroform, whereas the formation of a chain carrier in acetonitrile has a peculiar feature. In alcohols, the photochemical reaction is not a chain process, being a combination of photosolvation and photoreduction of Pt(IV) to Pt(II). It has been shown that the principal factors accounting for the solvent effect are the values of the rate constants of key reactions.",

keywords = "laser pulse photolysis, photochemistry, primary photophysical and photochemical processes, PtClcomplex, ultrafast kinetic spectroscopy",

author = "Glebov, {E. M.} and Plyusnin, {V. F.}",

note = "Funding Information: The study was supported by the Russian Science Foundation, project no. 18-13-00246. Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd.",

year = "2021",

month = may,

doi = "10.1134/S0018143921030036",

language = "English",

volume = "55",

pages = "203--211",

journal = "High Energy Chemistry",

issn = "0018-1439",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "3",

}

RIS

TY - JOUR

T1 - On the Cause of Solvent Effect in PtIVCl62− Photochemistry

AU - Glebov, E. M.

AU - Plyusnin, V. F.

PY - 2021/5

Y1 - 2021/5

N2 - The photochemistry of hexachloroplatinate(IV) paradoxically depends on the solvent. Chain photosolvation of the complex occurs in water, chloroform, and acetonitrile, with the photolysis mechanism being quite identical in water and chloroform, whereas the formation of a chain carrier in acetonitrile has a peculiar feature. In alcohols, the photochemical reaction is not a chain process, being a combination of photosolvation and photoreduction of Pt(IV) to Pt(II). It has been shown that the principal factors accounting for the solvent effect are the values of the rate constants of key reactions.

AB - The photochemistry of hexachloroplatinate(IV) paradoxically depends on the solvent. Chain photosolvation of the complex occurs in water, chloroform, and acetonitrile, with the photolysis mechanism being quite identical in water and chloroform, whereas the formation of a chain carrier in acetonitrile has a peculiar feature. In alcohols, the photochemical reaction is not a chain process, being a combination of photosolvation and photoreduction of Pt(IV) to Pt(II). It has been shown that the principal factors accounting for the solvent effect are the values of the rate constants of key reactions.

KW - laser pulse photolysis

KW - photochemistry

KW - primary photophysical and photochemical processes

KW - PtClcomplex

KW - ultrafast kinetic spectroscopy

UR - http://www.scopus.com/inward/record.url?scp=85107126080&partnerID=8YFLogxK

U2 - 10.1134/S0018143921030036

DO - 10.1134/S0018143921030036

M3 - Article

AN - SCOPUS:85107126080

VL - 55

SP - 203

EP - 211

JO - High Energy Chemistry

JF - High Energy Chemistry

SN - 0018-1439

IS - 3

ER -

ID: 34034600