Research output: Chapter in Book/Report/Conference proceeding › Chapter › Research › peer-review
Octahedral Chalcogenide Rhenium Clusters : From Solids to Isolated Cluster Complexes. / Fedorov, Vladimir E.; Naumov, Nikolay G.
Structure and Bonding: The legacy of Marcel Sergent. ed. / JF Halet. Cham : Springer International Publishing AG, 2019. p. 31-74 (Structure and Bonding; Vol. 179).Research output: Chapter in Book/Report/Conference proceeding › Chapter › Research › peer-review
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TY - CHAP
T1 - Octahedral Chalcogenide Rhenium Clusters
T2 - From Solids to Isolated Cluster Complexes
AU - Fedorov, Vladimir E.
AU - Naumov, Nikolay G.
N1 - Publisher Copyright: © Springer International Publishing Switzerland 2015.
PY - 2019
Y1 - 2019
N2 - This review summarizes the numerous studies on the chemistry of molybdenum and rhenium octahedral chalcogenide cluster compounds carried out over the years at the Nikolaev Institute of Inorganic Chemistry in collaboration with international research groups. A pathway from classical solid-state cluster compounds Mo6Se8, Re6Te15, and K4Re6S12, influenced by the French school of solid-state cluster chemistry, to soluble molecular complexes with Re(6)Q(8) and Mo(6)Q(8) cluster cores is provided. Both inorganic and organic ligands can be grafted onto cluster cages, resulting in a drastic change in the charge and properties of such complexes.
AB - This review summarizes the numerous studies on the chemistry of molybdenum and rhenium octahedral chalcogenide cluster compounds carried out over the years at the Nikolaev Institute of Inorganic Chemistry in collaboration with international research groups. A pathway from classical solid-state cluster compounds Mo6Se8, Re6Te15, and K4Re6S12, influenced by the French school of solid-state cluster chemistry, to soluble molecular complexes with Re(6)Q(8) and Mo(6)Q(8) cluster cores is provided. Both inorganic and organic ligands can be grafted onto cluster cages, resulting in a drastic change in the charge and properties of such complexes.
KW - Cluster
KW - Complex
KW - Crystal structure
KW - Luminescence
KW - Molybdenum
KW - Rhenium
KW - Solid state
KW - PARAMAGNETIC-RESONANCE PARAMETERS
KW - MOLECULAR BUILDING-BLOCKS
KW - SUPER-PRUSSIAN-BLUE
KW - METAL ATOM CLUSTERS
KW - BRIDGED RE(6)Q(8) Q
KW - CRYSTAL-STRUCTURES
KW - THERMOELECTRIC PROPERTIES
KW - BIOCTAHEDRAL CLUSTER
KW - DFT CALCULATIONS
KW - CHEVREL-PHASE
UR - http://www.scopus.com/inward/record.url?scp=85144116276&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/a2cbdbe8-f2dc-3224-b331-544a2a37f84a/
U2 - 10.1007/430_2019_33
DO - 10.1007/430_2019_33
M3 - Chapter
SN - 978-3-030-25123-9
T3 - Structure and Bonding
SP - 31
EP - 74
BT - Structure and Bonding
A2 - Halet, JF
PB - Springer International Publishing AG
CY - Cham
ER -
ID: 28278220