Nonconventional Three-Component Hierarchical Host-Guest Assembly Based on Mo-Blue Ring-Shaped Giant Anion, γ-Cyclodextrin, and Dawson-type Polyoxometalate

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Nonconventional Three-Component Hierarchical Host-Guest Assembly Based on Mo-Blue Ring-Shaped Giant Anion, γ-Cyclodextrin, and Dawson-type Polyoxometalate. / Moussawi, Mhamad Aly; Haouas, Mohamed; Floquet, Sébastien et al.

In: Journal of the American Chemical Society, Vol. 139, No. 41, 18.10.2017, p. 14376-14379.

Research output: Contribution to journal › Article › peer-review

Author

Moussawi, Mhamad Aly ; Haouas, Mohamed ; Floquet, Sébastien et al. / Nonconventional Three-Component Hierarchical Host-Guest Assembly Based on Mo-Blue Ring-Shaped Giant Anion, γ-Cyclodextrin, and Dawson-type Polyoxometalate. In: Journal of the American Chemical Society. 2017 ; Vol. 139, No. 41. pp. 14376-14379.

BibTeX

@article{924c17979186419296dd9f5b5b226387,

title = "Nonconventional Three-Component Hierarchical Host-Guest Assembly Based on Mo-Blue Ring-Shaped Giant Anion, γ-Cyclodextrin, and Dawson-type Polyoxometalate",

abstract = "In this communication, we report on a noteworthy hybrid supramolecular assembly built from three functional components hierarchically organized through noncovalent interactions. The one-pot synthesis procedure leads to the formation of large Mo-blue ring-shaped anion {Mo154}, which contains the supramolecular adduct based on the symmetric encapsulation of the Dawson-type [P2W18O62]6- anion by two γ-cyclodextrin units. Such a nanoscopic onion-like structure, noted [P2W18O62]@2γ-CD@{Mo154} has been characterized by single-crystal X-ray diffraction, thus demonstrating the capability of the giant inorganic torus to develop relevant supramolecular chemistry, probing the strong affinity of the inner and outer faces of the γ-CD for the polyoxometalate surfaces. Furthermore, interactions and behavior in solution have been studied by multinuclear NMR spectroscopy, which supports specific interactions between γ-CD and POM units. Finally, the formation of this three-component hybrid assembly from one-pot procedure, in water and using nearly stoichiometric conditions, is discussed in terms of the driving forces orchestrating this highly efficient multilevel recognition process.",

keywords = "CYCLIC POLYETHERS, PENTAGONAL UNITS, BUILDING-BLOCKS, DYNAMIC LIBRARY, METAL-SALTS, CHEMISTRY, CLUSTERS, KEPLERATE, BINDING, RECOGNITION",

author = "Moussawi, {Mhamad Aly} and Mohamed Haouas and S{\'e}bastien Floquet and Shepard, {William E.} and Abramov, {Pavel A.} and Sokolov, {Maxim N.} and Fedin, {Vladimir P.} and St{\'e}phane Cordier and Anne Ponchel and Eric Monflier and J{\'e}r{\^o}me Marrot and Emmanuel Cadot",

note = "Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",

year = "2017",

month = oct,

day = "18",

doi = "10.1021/jacs.7b08058",

language = "English",

volume = "139",

pages = "14376--14379",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "41",

}

RIS

TY - JOUR

T1 - Nonconventional Three-Component Hierarchical Host-Guest Assembly Based on Mo-Blue Ring-Shaped Giant Anion, γ-Cyclodextrin, and Dawson-type Polyoxometalate

AU - Moussawi, Mhamad Aly

AU - Haouas, Mohamed

AU - Floquet, Sébastien

AU - Shepard, William E.

AU - Abramov, Pavel A.

AU - Sokolov, Maxim N.

AU - Fedin, Vladimir P.

AU - Cordier, Stéphane

AU - Ponchel, Anne

AU - Monflier, Eric

AU - Marrot, Jérôme

AU - Cadot, Emmanuel

PY - 2017/10/18

Y1 - 2017/10/18

N2 - In this communication, we report on a noteworthy hybrid supramolecular assembly built from three functional components hierarchically organized through noncovalent interactions. The one-pot synthesis procedure leads to the formation of large Mo-blue ring-shaped anion {Mo154}, which contains the supramolecular adduct based on the symmetric encapsulation of the Dawson-type [P2W18O62]6- anion by two γ-cyclodextrin units. Such a nanoscopic onion-like structure, noted [P2W18O62]@2γ-CD@{Mo154} has been characterized by single-crystal X-ray diffraction, thus demonstrating the capability of the giant inorganic torus to develop relevant supramolecular chemistry, probing the strong affinity of the inner and outer faces of the γ-CD for the polyoxometalate surfaces. Furthermore, interactions and behavior in solution have been studied by multinuclear NMR spectroscopy, which supports specific interactions between γ-CD and POM units. Finally, the formation of this three-component hybrid assembly from one-pot procedure, in water and using nearly stoichiometric conditions, is discussed in terms of the driving forces orchestrating this highly efficient multilevel recognition process.

AB - In this communication, we report on a noteworthy hybrid supramolecular assembly built from three functional components hierarchically organized through noncovalent interactions. The one-pot synthesis procedure leads to the formation of large Mo-blue ring-shaped anion {Mo154}, which contains the supramolecular adduct based on the symmetric encapsulation of the Dawson-type [P2W18O62]6- anion by two γ-cyclodextrin units. Such a nanoscopic onion-like structure, noted [P2W18O62]@2γ-CD@{Mo154} has been characterized by single-crystal X-ray diffraction, thus demonstrating the capability of the giant inorganic torus to develop relevant supramolecular chemistry, probing the strong affinity of the inner and outer faces of the γ-CD for the polyoxometalate surfaces. Furthermore, interactions and behavior in solution have been studied by multinuclear NMR spectroscopy, which supports specific interactions between γ-CD and POM units. Finally, the formation of this three-component hybrid assembly from one-pot procedure, in water and using nearly stoichiometric conditions, is discussed in terms of the driving forces orchestrating this highly efficient multilevel recognition process.

KW - CYCLIC POLYETHERS

KW - PENTAGONAL UNITS

KW - BUILDING-BLOCKS

KW - DYNAMIC LIBRARY

KW - METAL-SALTS

KW - CHEMISTRY

KW - CLUSTERS

KW - KEPLERATE

KW - BINDING

KW - RECOGNITION

UR - http://www.scopus.com/inward/record.url?scp=85031719931&partnerID=8YFLogxK

U2 - 10.1021/jacs.7b08058

DO - 10.1021/jacs.7b08058

M3 - Article

C2 - 28968090

AN - SCOPUS:85031719931

VL - 139

SP - 14376

EP - 14379

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 41

ER -

ID: 9048166