No Catalyst Added Hydrogen Peroxide Oxidation of Dextran

Standard

No Catalyst Added Hydrogen Peroxide Oxidation of Dextran : An Environmentally Friendly Route to Multifunctional Polymers. / Pronina, Ekaterina V.; Vorotnikov, Yuri A.; Pozmogova, Tatiana N. et al.

In: ACS Sustainable Chemistry and Engineering, Vol. 8, No. 13, 06.04.2020, p. 5371-5379.

Research output: Contribution to journal › Article › peer-review

Harvard

Pronina, EV, Vorotnikov, YA, Pozmogova, TN, Solovieva, AO, Miroshnichenko, SM, Plyusnin, PE, Pishchur, DP, Eltsov, IV, Edeleva, MV, Shestopalov, MA & Efremova, OA 2020, 'No Catalyst Added Hydrogen Peroxide Oxidation of Dextran: An Environmentally Friendly Route to Multifunctional Polymers', ACS Sustainable Chemistry and Engineering, vol. 8, no. 13, pp. 5371-5379. https://doi.org/10.1021/acssuschemeng.0c01030

APA

Pronina, E. V., Vorotnikov, Y. A., Pozmogova, T. N., Solovieva, A. O., Miroshnichenko, S. M., Plyusnin, P. E., Pishchur, D. P., Eltsov, I. V., Edeleva, M. V., Shestopalov, M. A., & Efremova, O. A. (2020). No Catalyst Added Hydrogen Peroxide Oxidation of Dextran: An Environmentally Friendly Route to Multifunctional Polymers. ACS Sustainable Chemistry and Engineering, 8(13), 5371-5379. https://doi.org/10.1021/acssuschemeng.0c01030

Vancouver

Pronina EV, Vorotnikov YA, Pozmogova TN, Solovieva AO, Miroshnichenko SM, Plyusnin PE et al. No Catalyst Added Hydrogen Peroxide Oxidation of Dextran: An Environmentally Friendly Route to Multifunctional Polymers. ACS Sustainable Chemistry and Engineering. 2020 Apr 6;8(13):5371-5379. doi: 10.1021/acssuschemeng.0c01030

Author

Pronina, Ekaterina V. ; Vorotnikov, Yuri A. ; Pozmogova, Tatiana N. et al. / No Catalyst Added Hydrogen Peroxide Oxidation of Dextran : An Environmentally Friendly Route to Multifunctional Polymers. In: ACS Sustainable Chemistry and Engineering. 2020 ; Vol. 8, No. 13. pp. 5371-5379.

BibTeX

@article{0839f277d62a4fd3bc0ecf89c2505fdb,

title = "No Catalyst Added Hydrogen Peroxide Oxidation of Dextran: An Environmentally Friendly Route to Multifunctional Polymers",

abstract = "The paper demonstrates a {"}greener{"} oxidation of dextran polymer of various molecular masses, the component of many industrially and pharmaceutically important materials, by aqueous H2O2 in a no catalyst added setting that produced a multifunctional oxidized dextran. Specifically, on the top of common functional groups (hydroxo, carbonyl, and carboxylic acids), the freshly peroxide oxidized dextran had also a significant number of peroxo-groups, which endowed the polymer with significant cytotoxic properties, as demonstrated on a larynx carcinoma cell line. We also have shown that the peroxo-groups could be easily removed in an alkaline media to yield nontoxic oxidized dextran polymers.",

keywords = "Cytotoxicity, Dextran polysaccharide, Functional groups, Green oxidation, Hydrogen peroxide",

author = "Pronina, {Ekaterina V.} and Vorotnikov, {Yuri A.} and Pozmogova, {Tatiana N.} and Solovieva, {Anastasiya O.} and Miroshnichenko, {Svetlana M.} and Plyusnin, {Pavel E.} and Pishchur, {Denis P.} and Eltsov, {Ilia V.} and Edeleva, {Mariya V.} and Shestopalov, {Michael A.} and Efremova, {Olga A.}",

year = "2020",

month = apr,

day = "6",

doi = "10.1021/acssuschemeng.0c01030",

language = "English",

volume = "8",

pages = "5371--5379",

journal = "ACS Sustainable Chemistry and Engineering",

issn = "2168-0485",

publisher = "American Chemical Society",

number = "13",

}

RIS

TY - JOUR

T1 - No Catalyst Added Hydrogen Peroxide Oxidation of Dextran

T2 - An Environmentally Friendly Route to Multifunctional Polymers

AU - Pronina, Ekaterina V.

AU - Vorotnikov, Yuri A.

AU - Pozmogova, Tatiana N.

AU - Solovieva, Anastasiya O.

AU - Miroshnichenko, Svetlana M.

AU - Plyusnin, Pavel E.

AU - Pishchur, Denis P.

AU - Eltsov, Ilia V.

AU - Edeleva, Mariya V.

AU - Shestopalov, Michael A.

AU - Efremova, Olga A.

PY - 2020/4/6

Y1 - 2020/4/6

N2 - The paper demonstrates a "greener" oxidation of dextran polymer of various molecular masses, the component of many industrially and pharmaceutically important materials, by aqueous H2O2 in a no catalyst added setting that produced a multifunctional oxidized dextran. Specifically, on the top of common functional groups (hydroxo, carbonyl, and carboxylic acids), the freshly peroxide oxidized dextran had also a significant number of peroxo-groups, which endowed the polymer with significant cytotoxic properties, as demonstrated on a larynx carcinoma cell line. We also have shown that the peroxo-groups could be easily removed in an alkaline media to yield nontoxic oxidized dextran polymers.

AB - The paper demonstrates a "greener" oxidation of dextran polymer of various molecular masses, the component of many industrially and pharmaceutically important materials, by aqueous H2O2 in a no catalyst added setting that produced a multifunctional oxidized dextran. Specifically, on the top of common functional groups (hydroxo, carbonyl, and carboxylic acids), the freshly peroxide oxidized dextran had also a significant number of peroxo-groups, which endowed the polymer with significant cytotoxic properties, as demonstrated on a larynx carcinoma cell line. We also have shown that the peroxo-groups could be easily removed in an alkaline media to yield nontoxic oxidized dextran polymers.

KW - Cytotoxicity

KW - Dextran polysaccharide

KW - Functional groups

KW - Green oxidation

KW - Hydrogen peroxide

UR - http://www.scopus.com/inward/record.url?scp=85083812766&partnerID=8YFLogxK

U2 - 10.1021/acssuschemeng.0c01030

DO - 10.1021/acssuschemeng.0c01030

M3 - Article

AN - SCOPUS:85083812766

VL - 8

SP - 5371

EP - 5379

JO - ACS Sustainable Chemistry and Engineering

JF - ACS Sustainable Chemistry and Engineering

SN - 2168-0485

IS - 13

ER -

ID: 24160308