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NHC adducts of tantalum amidohalides : the first example of NHC abnormally coordinated to an early transition metal. / Petrov, Pavel A.; Sukhikh, Taisiya S.; Sokolov, Maxim N.

In: Dalton Transactions, Vol. 46, No. 15, 21.04.2017, p. 4902-4906.

Research output: Contribution to journal › Article › peer-review

Harvard

Petrov, PA, Sukhikh, TS & Sokolov, MN 2017, 'NHC adducts of tantalum amidohalides: the first example of NHC abnormally coordinated to an early transition metal', Dalton Transactions, vol. 46, no. 15, pp. 4902-4906. https://doi.org/10.1039/c7dt00748e

APA

Petrov, P. A., Sukhikh, T. S., & Sokolov, M. N. (2017). NHC adducts of tantalum amidohalides: the first example of NHC abnormally coordinated to an early transition metal. Dalton Transactions, 46(15), 4902-4906. https://doi.org/10.1039/c7dt00748e

Vancouver

Petrov PA, Sukhikh TS, Sokolov MN. NHC adducts of tantalum amidohalides: the first example of NHC abnormally coordinated to an early transition metal. Dalton Transactions. 2017 Apr 21;46(15):4902-4906. doi: 10.1039/c7dt00748e

Author

Petrov, Pavel A. ; Sukhikh, Taisiya S. ; Sokolov, Maxim N. / NHC adducts of tantalum amidohalides : the first example of NHC abnormally coordinated to an early transition metal. In: Dalton Transactions. 2017 ; Vol. 46, No. 15. pp. 4902-4906.

BibTeX

@article{8f2c6d1f88d541008165e2354cae7c9b,
title = "NHC adducts of tantalum amidohalides: the first example of NHC abnormally coordinated to an early transition metal",
abstract = "The reaction of Ta(NMe2)5 with NHC·HBF4 (NHC = IMes and SIMes) leads to new carbene adducts of the mixed TaV amidofluoride, [(NHC)TaF3(NMe2)2]. On the contrary, the reaction of Ta(NMe2)5 with IMes·HCl gives a complex mixture, where [(aIMes)TaCl2(NMe2)3] is identified as one of the products. This is the first example of abnormal NHC coordination to an early transition metal.",
keywords = "HETEROCYCLIC CARBENE COMPLEXES, WHITE PHOSPHORUS, REACTIVITY, ACTIVATION, P-4, NIOBIUM, REARRANGEMENT, CLUSTER",
author = "Petrov, {Pavel A.} and Sukhikh, {Taisiya S.} and Sokolov, {Maxim N.}",
year = "2017",
month = apr,
day = "21",
doi = "10.1039/c7dt00748e",
language = "English",
volume = "46",
pages = "4902--4906",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "15",

}

RIS

TY - JOUR

T1 - NHC adducts of tantalum amidohalides

T2 - the first example of NHC abnormally coordinated to an early transition metal

AU - Petrov, Pavel A.

AU - Sukhikh, Taisiya S.

AU - Sokolov, Maxim N.

PY - 2017/4/21

Y1 - 2017/4/21

N2 - The reaction of Ta(NMe2)5 with NHC·HBF4 (NHC = IMes and SIMes) leads to new carbene adducts of the mixed TaV amidofluoride, [(NHC)TaF3(NMe2)2]. On the contrary, the reaction of Ta(NMe2)5 with IMes·HCl gives a complex mixture, where [(aIMes)TaCl2(NMe2)3] is identified as one of the products. This is the first example of abnormal NHC coordination to an early transition metal.

AB - The reaction of Ta(NMe2)5 with NHC·HBF4 (NHC = IMes and SIMes) leads to new carbene adducts of the mixed TaV amidofluoride, [(NHC)TaF3(NMe2)2]. On the contrary, the reaction of Ta(NMe2)5 with IMes·HCl gives a complex mixture, where [(aIMes)TaCl2(NMe2)3] is identified as one of the products. This is the first example of abnormal NHC coordination to an early transition metal.

KW - HETEROCYCLIC CARBENE COMPLEXES

KW - WHITE PHOSPHORUS

KW - REACTIVITY

KW - ACTIVATION

KW - P-4

KW - NIOBIUM

KW - REARRANGEMENT

KW - CLUSTER

UR - http://www.scopus.com/inward/record.url?scp=85017354941&partnerID=8YFLogxK

U2 - 10.1039/c7dt00748e

DO - 10.1039/c7dt00748e

M3 - Article

C2 - 28327773

AN - SCOPUS:85017354941

VL - 46

SP - 4902

EP - 4906

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 15

ER -

ID: 10264090