Standard

New volatile zirconium(IV) complex with methoxy substituted β-diketonate. / Krisyuk, V. V.; Baidina, I. A.; Turgambaeva, A. E. et al.

In: Journal of Structural Chemistry, Vol. 58, No. 4, 01.07.2017, p. 831-834.

Research output: Contribution to journal › Article › peer-review

Harvard

Krisyuk, VV, Baidina, IA, Turgambaeva, AE, Korolkov, IV, Urkasym kyz, S & Igumenov, IK 2017, 'New volatile zirconium(IV) complex with methoxy substituted β-diketonate', Journal of Structural Chemistry, vol. 58, no. 4, pp. 831-834. https://doi.org/10.1134/S0022476617040308

APA

Krisyuk, V. V., Baidina, I. A., Turgambaeva, A. E., Korolkov, I. V., Urkasym kyz, S., & Igumenov, I. K. (2017). New volatile zirconium(IV) complex with methoxy substituted β-diketonate. Journal of Structural Chemistry, 58(4), 831-834. https://doi.org/10.1134/S0022476617040308

Vancouver

Krisyuk VV, Baidina IA, Turgambaeva AE, Korolkov IV, Urkasym kyz S, Igumenov IK. New volatile zirconium(IV) complex with methoxy substituted β-diketonate. Journal of Structural Chemistry. 2017 Jul 1;58(4):831-834. doi: 10.1134/S0022476617040308

Author

Krisyuk, V. V. ; Baidina, I. A. ; Turgambaeva, A. E. et al. / New volatile zirconium(IV) complex with methoxy substituted β-diketonate. In: Journal of Structural Chemistry. 2017 ; Vol. 58, No. 4. pp. 831-834.

BibTeX

@article{be78ac857d804516b4ef30e51b24e588,
title = "New volatile zirconium(IV) complex with methoxy substituted β-diketonate",
abstract = "A new zirconium(VI) complex with fluorinated methoxy substituted β-diketonate ZrL4 is synthesized where L = 1,1,1-trifluoro-5-methoxy-5-methylhexane-2,4-dionate. The complex sublimates without decomposition at a low pressure (10–2 Torr) at 140 °C. The crystal structure of the complex is molecular and composed of mononuclear ZrL4 molecules. Crystallographic data for C32H40F12O12Zr are: C2/c, a = 12.193(2) {\AA}, b = 21.922(4) {\AA}, c = 15.585(3) {\AA}, β = 101.51(3)°, V = 4082.1(14) {\AA}3, Z = 4, d = 1.523 g/cm3. The coordination environment of the zirconium atom is formed by eight oxygen atoms of four β-diketonate ligands; the coordination polymer is a square antriprism. The Zr–O distances are in the range 2.16-2.19 {\AA}. The thermal properties of the complex are studied by TG–DTA.",
keywords = "crystal structure, diketonates, MOCVD precursor, volatile organometallic complex, zirconium, THERMAL-PROPERTIES",
author = "Krisyuk, {V. V.} and Baidina, {I. A.} and Turgambaeva, {A. E.} and Korolkov, {I. V.} and {Urkasym kyz}, S. and Igumenov, {I. K.}",
note = "Publisher Copyright: {\textcopyright} 2017, Pleiades Publishing, Ltd.",
year = "2017",
month = jul,
day = "1",
doi = "10.1134/S0022476617040308",
language = "English",
volume = "58",
pages = "831--834",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "4",

}

RIS

TY - JOUR

T1 - New volatile zirconium(IV) complex with methoxy substituted β-diketonate

AU - Krisyuk, V. V.

AU - Baidina, I. A.

AU - Turgambaeva, A. E.

AU - Korolkov, I. V.

AU - Urkasym kyz, S.

AU - Igumenov, I. K.

N1 - Publisher Copyright: © 2017, Pleiades Publishing, Ltd.

PY - 2017/7/1

Y1 - 2017/7/1

N2 - A new zirconium(VI) complex with fluorinated methoxy substituted β-diketonate ZrL4 is synthesized where L = 1,1,1-trifluoro-5-methoxy-5-methylhexane-2,4-dionate. The complex sublimates without decomposition at a low pressure (10–2 Torr) at 140 °C. The crystal structure of the complex is molecular and composed of mononuclear ZrL4 molecules. Crystallographic data for C32H40F12O12Zr are: C2/c, a = 12.193(2) Å, b = 21.922(4) Å, c = 15.585(3) Å, β = 101.51(3)°, V = 4082.1(14) Å3, Z = 4, d = 1.523 g/cm3. The coordination environment of the zirconium atom is formed by eight oxygen atoms of four β-diketonate ligands; the coordination polymer is a square antriprism. The Zr–O distances are in the range 2.16-2.19 Å. The thermal properties of the complex are studied by TG–DTA.

AB - A new zirconium(VI) complex with fluorinated methoxy substituted β-diketonate ZrL4 is synthesized where L = 1,1,1-trifluoro-5-methoxy-5-methylhexane-2,4-dionate. The complex sublimates without decomposition at a low pressure (10–2 Torr) at 140 °C. The crystal structure of the complex is molecular and composed of mononuclear ZrL4 molecules. Crystallographic data for C32H40F12O12Zr are: C2/c, a = 12.193(2) Å, b = 21.922(4) Å, c = 15.585(3) Å, β = 101.51(3)°, V = 4082.1(14) Å3, Z = 4, d = 1.523 g/cm3. The coordination environment of the zirconium atom is formed by eight oxygen atoms of four β-diketonate ligands; the coordination polymer is a square antriprism. The Zr–O distances are in the range 2.16-2.19 Å. The thermal properties of the complex are studied by TG–DTA.

KW - crystal structure

KW - diketonates

KW - MOCVD precursor

KW - volatile organometallic complex

KW - zirconium

KW - THERMAL-PROPERTIES

UR - http://www.scopus.com/inward/record.url?scp=85029583590&partnerID=8YFLogxK

U2 - 10.1134/S0022476617040308

DO - 10.1134/S0022476617040308

M3 - Article

AN - SCOPUS:85029583590

VL - 58

SP - 831

EP - 834

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 4

ER -

ID: 9909872