Research output: Contribution to journal › Article › peer-review
New one-, two-, and three-dimensional metal-organic frameworks based on magnesium(II) : synthesis and structure. / Marakulin, A. V.; Lysova, A. A.; Samsonenko, D. G. et al.
In: Russian Chemical Bulletin, Vol. 69, No. 2, 02.2020, p. 360-368.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - New one-, two-, and three-dimensional metal-organic frameworks based on magnesium(II)
T2 - synthesis and structure
AU - Marakulin, A. V.
AU - Lysova, A. A.
AU - Samsonenko, D. G.
AU - Dorovatovskii, P. V.
AU - Lazarenko, V. A.
AU - Dybtsev, D. N.
AU - Fedin, V. P.
PY - 2020/2
Y1 - 2020/2
N2 - Six new metal-organic frameworks based on magnesium(II) ions of various dimensionality were synthesized: chain-like [Mg(Hazdc)2(nmp)2] (1, H2azdc is 4,4′-azobenzenedicarboxylic acid, nmp is N-methylpyrrolidone), layered [Mg(H2btc)(nmp)2] (2, H4btc is 1,2,4,5-benzene-tetracarboxylic acid), [Mg3(sdc)3(def)4] •3DEF (3, H2sdc is 4,4’-stilbenedicarboxylic acid, def or DEF is N,N-diethylformamide), [Mg3(azdc)3(dma)4] • 3DMA (4, dma or DMA is N,N-di-methylacetamide), [Mg3(azdc)3(dmf)4] (5, dmf is N,N-dimethylformamide), and doubly-interpenetrated three-dimensional [Mg3(azdc)3(nmp)4] •NMP (6, NMP is N-methylpyrrolidone). According to the single-crystal X-ray dif raction data, compounds 1 and 2 are built from mononuclear carboxylate units {Mg(RCOOH)2(RCOO)2(nmp)2}. Compounds 3-6 are composed on trinuclear carboxylate units {Mg3(RCOO)6}. In isostructural compounds 3-5, these units are linked to each other through carboxylate bridges to form polymer layers; in compound 6, these units are linked together to form a doubly-interpenetrated three-dimensional metal-organic framework.
AB - Six new metal-organic frameworks based on magnesium(II) ions of various dimensionality were synthesized: chain-like [Mg(Hazdc)2(nmp)2] (1, H2azdc is 4,4′-azobenzenedicarboxylic acid, nmp is N-methylpyrrolidone), layered [Mg(H2btc)(nmp)2] (2, H4btc is 1,2,4,5-benzene-tetracarboxylic acid), [Mg3(sdc)3(def)4] •3DEF (3, H2sdc is 4,4’-stilbenedicarboxylic acid, def or DEF is N,N-diethylformamide), [Mg3(azdc)3(dma)4] • 3DMA (4, dma or DMA is N,N-di-methylacetamide), [Mg3(azdc)3(dmf)4] (5, dmf is N,N-dimethylformamide), and doubly-interpenetrated three-dimensional [Mg3(azdc)3(nmp)4] •NMP (6, NMP is N-methylpyrrolidone). According to the single-crystal X-ray dif raction data, compounds 1 and 2 are built from mononuclear carboxylate units {Mg(RCOOH)2(RCOO)2(nmp)2}. Compounds 3-6 are composed on trinuclear carboxylate units {Mg3(RCOO)6}. In isostructural compounds 3-5, these units are linked to each other through carboxylate bridges to form polymer layers; in compound 6, these units are linked together to form a doubly-interpenetrated three-dimensional metal-organic framework.
KW - dimensionality
KW - magnesium
KW - metal-organic frameworks
KW - X-ray dif raction
KW - POROUS COORDINATION POLYMERS
KW - SORPTION
KW - SEPARATION
KW - ADSORPTION
UR - http://www.scopus.com/inward/record.url?scp=85083105526&partnerID=8YFLogxK
U2 - 10.1007/s11172-020-2768-9
DO - 10.1007/s11172-020-2768-9
M3 - Article
AN - SCOPUS:85083105526
VL - 69
SP - 360
EP - 368
JO - Russian Chemical Bulletin
JF - Russian Chemical Bulletin
SN - 1066-5285
IS - 2
ER -
ID: 23996016