Standard

New Method for the Synthesis of Octahedral Rhenium Chalcocyanide Cluster Complexes [{Re 6 (μ 3 -Q) 8 }(CN) 6 ] 4– (Q = S, Se, Te). / Pronin, A. S.; Yarovoy, S. S.; Smolentsev, A. I. et al.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 45, No. 2, 01.02.2019, p. 119-123.

Research output: Contribution to journal › Article › peer-review

Harvard

Pronin, AS, Yarovoy, SS, Smolentsev, AI & Mironov, YV 2019, 'New Method for the Synthesis of Octahedral Rhenium Chalcocyanide Cluster Complexes [{Re 6 (μ 3 -Q) 8 }(CN) 6 ] 4– (Q = S, Se, Te)', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 45, no. 2, pp. 119-123. https://doi.org/10.1134/S1070328419020052

APA

Pronin, A. S., Yarovoy, S. S., Smolentsev, A. I., & Mironov, Y. V. (2019). New Method for the Synthesis of Octahedral Rhenium Chalcocyanide Cluster Complexes [{Re 6 (μ 3 -Q) 8 }(CN) 6 ] 4– (Q = S, Se, Te). Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 45(2), 119-123. https://doi.org/10.1134/S1070328419020052

Vancouver

Pronin AS, Yarovoy SS, Smolentsev AI, Mironov YV. New Method for the Synthesis of Octahedral Rhenium Chalcocyanide Cluster Complexes [{Re 6 (μ 3 -Q) 8 }(CN) 6 ] 4– (Q = S, Se, Te). Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2019 Feb 1;45(2):119-123. doi: 10.1134/S1070328419020052

Author

Pronin, A. S. ; Yarovoy, S. S. ; Smolentsev, A. I. et al. / New Method for the Synthesis of Octahedral Rhenium Chalcocyanide Cluster Complexes [{Re 6 (μ 3 -Q) 8 }(CN) 6 ] 4– (Q = S, Se, Te). In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2019 ; Vol. 45, No. 2. pp. 119-123.

BibTeX

@article{737d6464d4044ca9b88b122ec9d6c5a7,
title = "New Method for the Synthesis of Octahedral Rhenium Chalcocyanide Cluster Complexes [{Re 6 (μ 3 -Q) 8 }(CN) 6 ] 4– (Q = S, Se, Te)",
abstract = "A new method is proposed for the synthesis of the octahedral rhenium chalcocyanide cluster complexes [{Re 6 (μ 3 -Q) 8 }(CN) 6 ] 4– (Q = S, Se, Te) using rhenium(IV) oxide as the starting compound. Among the synthesized compounds, the anhydrous cluster salt K 4 [{Re 6 Se 8 }(CN) 6 ] is characterized by X-ray diffraction analysis for the first time. The crystals are orthorhombic, space group Pbcn; a = 13.1386(13), b = 11.4941(8), c = 17.2990(16) {\AA}, Z = 4, V = 2612.4(4) {\AA} 3 (CIF file IСSD no. 434320). The crystal structure of K 4 [{Re 6 Se 8 }(CN) 6 ] represents a framework type packing based on the K + cations coordinated by the cyanide groups of the cluster anions [{Re 6 Se 8 }(CN) 6 ] 4– . ",
keywords = "chalcogens, crystal structure, octahedral cluster complex, rhenium",
author = "Pronin, {A. S.} and Yarovoy, {S. S.} and Smolentsev, {A. I.} and Mironov, {Yu V.}",
year = "2019",
month = feb,
day = "1",
doi = "10.1134/S1070328419020052",
language = "English",
volume = "45",
pages = "119--123",
journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",
issn = "1070-3284",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "2",

}

RIS

TY - JOUR

T1 - New Method for the Synthesis of Octahedral Rhenium Chalcocyanide Cluster Complexes [{Re 6 (μ 3 -Q) 8 }(CN) 6 ] 4– (Q = S, Se, Te)

AU - Pronin, A. S.

AU - Yarovoy, S. S.

AU - Smolentsev, A. I.

AU - Mironov, Yu V.

PY - 2019/2/1

Y1 - 2019/2/1

N2 - A new method is proposed for the synthesis of the octahedral rhenium chalcocyanide cluster complexes [{Re 6 (μ 3 -Q) 8 }(CN) 6 ] 4– (Q = S, Se, Te) using rhenium(IV) oxide as the starting compound. Among the synthesized compounds, the anhydrous cluster salt K 4 [{Re 6 Se 8 }(CN) 6 ] is characterized by X-ray diffraction analysis for the first time. The crystals are orthorhombic, space group Pbcn; a = 13.1386(13), b = 11.4941(8), c = 17.2990(16) Å, Z = 4, V = 2612.4(4) Å 3 (CIF file IСSD no. 434320). The crystal structure of K 4 [{Re 6 Se 8 }(CN) 6 ] represents a framework type packing based on the K + cations coordinated by the cyanide groups of the cluster anions [{Re 6 Se 8 }(CN) 6 ] 4– .

AB - A new method is proposed for the synthesis of the octahedral rhenium chalcocyanide cluster complexes [{Re 6 (μ 3 -Q) 8 }(CN) 6 ] 4– (Q = S, Se, Te) using rhenium(IV) oxide as the starting compound. Among the synthesized compounds, the anhydrous cluster salt K 4 [{Re 6 Se 8 }(CN) 6 ] is characterized by X-ray diffraction analysis for the first time. The crystals are orthorhombic, space group Pbcn; a = 13.1386(13), b = 11.4941(8), c = 17.2990(16) Å, Z = 4, V = 2612.4(4) Å 3 (CIF file IСSD no. 434320). The crystal structure of K 4 [{Re 6 Se 8 }(CN) 6 ] represents a framework type packing based on the K + cations coordinated by the cyanide groups of the cluster anions [{Re 6 Se 8 }(CN) 6 ] 4– .

KW - chalcogens

KW - crystal structure

KW - octahedral cluster complex

KW - rhenium

UR - http://www.scopus.com/inward/record.url?scp=85064811771&partnerID=8YFLogxK

U2 - 10.1134/S1070328419020052

DO - 10.1134/S1070328419020052

M3 - Article

AN - SCOPUS:85064811771

VL - 45

SP - 119

EP - 123

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 2

ER -

ID: 19647064