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New double complex salt [PdEn2]3[Rh(NO2)6]2 · 2.67H2O : Synthesis, crystal structure, and thermal properties. / Kirilovich, A. K.; Plyusnin, P. E.; Piryazev, D. A. et al.

In: Russian Journal of Inorganic Chemistry, Vol. 62, No. 7, 01.07.2017, p. 886-892.

Research output: Contribution to journal › Article › peer-review

Harvard

Kirilovich, AK, Plyusnin, PE, Piryazev, DA, Gromilov, SA & Korenev, SV 2017, 'New double complex salt [PdEn2]3[Rh(NO2)6]2 · 2.67H2O: Synthesis, crystal structure, and thermal properties', Russian Journal of Inorganic Chemistry, vol. 62, no. 7, pp. 886-892. https://doi.org/10.1134/S0036023617070099

APA

Kirilovich, A. K., Plyusnin, P. E., Piryazev, D. A., Gromilov, S. A., & Korenev, S. V. (2017). New double complex salt [PdEn2]3[Rh(NO2)6]2 · 2.67H2O: Synthesis, crystal structure, and thermal properties. Russian Journal of Inorganic Chemistry, 62(7), 886-892. https://doi.org/10.1134/S0036023617070099

Vancouver

Kirilovich AK, Plyusnin PE, Piryazev DA, Gromilov SA, Korenev SV. New double complex salt [PdEn2]3[Rh(NO2)6]2 · 2.67H2O: Synthesis, crystal structure, and thermal properties. Russian Journal of Inorganic Chemistry. 2017 Jul 1;62(7):886-892. doi: 10.1134/S0036023617070099

Author

Kirilovich, A. K. ; Plyusnin, P. E. ; Piryazev, D. A. et al. / New double complex salt [PdEn2]3[Rh(NO2)6]2 · 2.67H2O : Synthesis, crystal structure, and thermal properties. In: Russian Journal of Inorganic Chemistry. 2017 ; Vol. 62, No. 7. pp. 886-892.

BibTeX

@article{b1810ca9065a46c795dc5f331cc7dbf4,
title = "New double complex salt [PdEn2]3[Rh(NO2)6]2 · 2.67H2O: Synthesis, crystal structure, and thermal properties",
abstract = "The crystal structure of the double complex salt (DCS) [PdEn2]3[Rh(NO2)6]2 • 2.67H2O (I) has been determined by X-ray diffraction. Crystals are triclinic, space group P1 ¯ , Z = 4, a = 9.2331(3) {\AA}, b = 9.9136(4) {\AA}, c = 13.7824(5) {\AA}, α = 84.3230(14)°, β = 89.9655(14)°, γ = 66.7272(13)°, V = 1152.19(7) {\AA}3, ρcalcd = 2.141 g/cm3, R = 0.0279. The thermal behavior of complex salt I has been studied in various gas atmospheres. The end product of thermolysis in reductive atmosphere is a mixture of Pd0.45Rh0.55 and Pd0.95Rh0.05 solid solutions. The end product of thermolysis in an inert atmosphere is a homogeneous Pd0.6Rh0.4 solid solution.",
keywords = "CATALYSTS, SUPPORT, RH",
author = "Kirilovich, {A. K.} and Plyusnin, {P. E.} and Piryazev, {D. A.} and Gromilov, {S. A.} and Korenev, {S. V.}",
year = "2017",
month = jul,
day = "1",
doi = "10.1134/S0036023617070099",
language = "English",
volume = "62",
pages = "886--892",
journal = "Russian Journal of Inorganic Chemistry",
issn = "0036-0236",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "7",

}

RIS

TY - JOUR

T1 - New double complex salt [PdEn2]3[Rh(NO2)6]2 · 2.67H2O

T2 - Synthesis, crystal structure, and thermal properties

AU - Kirilovich, A. K.

AU - Plyusnin, P. E.

AU - Piryazev, D. A.

AU - Gromilov, S. A.

AU - Korenev, S. V.

PY - 2017/7/1

Y1 - 2017/7/1

N2 - The crystal structure of the double complex salt (DCS) [PdEn2]3[Rh(NO2)6]2 • 2.67H2O (I) has been determined by X-ray diffraction. Crystals are triclinic, space group P1 ¯ , Z = 4, a = 9.2331(3) Å, b = 9.9136(4) Å, c = 13.7824(5) Å, α = 84.3230(14)°, β = 89.9655(14)°, γ = 66.7272(13)°, V = 1152.19(7) Å3, ρcalcd = 2.141 g/cm3, R = 0.0279. The thermal behavior of complex salt I has been studied in various gas atmospheres. The end product of thermolysis in reductive atmosphere is a mixture of Pd0.45Rh0.55 and Pd0.95Rh0.05 solid solutions. The end product of thermolysis in an inert atmosphere is a homogeneous Pd0.6Rh0.4 solid solution.

AB - The crystal structure of the double complex salt (DCS) [PdEn2]3[Rh(NO2)6]2 • 2.67H2O (I) has been determined by X-ray diffraction. Crystals are triclinic, space group P1 ¯ , Z = 4, a = 9.2331(3) Å, b = 9.9136(4) Å, c = 13.7824(5) Å, α = 84.3230(14)°, β = 89.9655(14)°, γ = 66.7272(13)°, V = 1152.19(7) Å3, ρcalcd = 2.141 g/cm3, R = 0.0279. The thermal behavior of complex salt I has been studied in various gas atmospheres. The end product of thermolysis in reductive atmosphere is a mixture of Pd0.45Rh0.55 and Pd0.95Rh0.05 solid solutions. The end product of thermolysis in an inert atmosphere is a homogeneous Pd0.6Rh0.4 solid solution.

KW - CATALYSTS

KW - SUPPORT

KW - RH

UR - http://www.scopus.com/inward/record.url?scp=85026830720&partnerID=8YFLogxK

U2 - 10.1134/S0036023617070099

DO - 10.1134/S0036023617070099

M3 - Article

AN - SCOPUS:85026830720

VL - 62

SP - 886

EP - 892

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

SN - 0036-0236

IS - 7

ER -

ID: 9067496