Research output: Contribution to journal › Article › peer-review
New approaches for enhancement of oxygen fluxes on hollow fiber membranes. / Popov, Mikhail P.; Gainutdinov, Igor I.; Bychkov, Sergey F. et al.
In: Materials Today: Proceedings, Vol. 4, No. 11, 01.01.2017, p. 11381-11384.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - New approaches for enhancement of oxygen fluxes on hollow fiber membranes
AU - Popov, Mikhail P.
AU - Gainutdinov, Igor I.
AU - Bychkov, Sergey F.
AU - Nemudry, Alexander P.
PY - 2017/1/1
Y1 - 2017/1/1
N2 - Hollow fiber (HF) membranes composed of Ba0.5Sr0.5Co0.78W0.02Fe0.2O3- δ (BSCFW2) were prepared by the phase inversion technique. The maximum measured oxygens flux through BSCFW2 HF membranes was 10.4 ml/(min∗cm2) at T=900°C and pO2,1=0.7 atm. Study of the dependence of oxygen fluxes through BSCFW2 HF on temperature (T=800-900°C) and oxygen partial pressure on the feed side (pO2,1=0.1-0.7 atm) was performed. It was shown that the rate-determining step of oxygen permeability is the kinetics of surface reactions with activation energy of 135±10 kJ/mol for furnace heating and 90±5 kJ/mol for current heating.
AB - Hollow fiber (HF) membranes composed of Ba0.5Sr0.5Co0.78W0.02Fe0.2O3- δ (BSCFW2) were prepared by the phase inversion technique. The maximum measured oxygens flux through BSCFW2 HF membranes was 10.4 ml/(min∗cm2) at T=900°C and pO2,1=0.7 atm. Study of the dependence of oxygen fluxes through BSCFW2 HF on temperature (T=800-900°C) and oxygen partial pressure on the feed side (pO2,1=0.1-0.7 atm) was performed. It was shown that the rate-determining step of oxygen permeability is the kinetics of surface reactions with activation energy of 135±10 kJ/mol for furnace heating and 90±5 kJ/mol for current heating.
KW - BSCF
KW - Current heating
KW - Hollow fibers
KW - Nonstoichiometricperovskites
KW - Oxygen flux
KW - Oxygen permeable membranes
KW - current heating
KW - hollow fibers
KW - nonstoichiometricperovskites
KW - oxygen flux
KW - BA0.5SR0.5CO0.8FE0.2O3-DELTA
KW - SEPARATION
KW - PEROVSKITES
KW - SYNGAS
KW - PERMEATION
UR - http://www.scopus.com/inward/record.url?scp=85032034833&partnerID=8YFLogxK
U2 - 10.1016/j.matpr.2017.09.013
DO - 10.1016/j.matpr.2017.09.013
M3 - Article
AN - SCOPUS:85032034833
VL - 4
SP - 11381
EP - 11384
JO - Materials Today: Proceedings
JF - Materials Today: Proceedings
SN - 2214-7853
IS - 11
ER -
ID: 12078677