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Nature of the Color of Borates with "anti-Zeolite" Structure. / Bekker, Tatyana B.; Solntsev, Vladimir P.; Rashchenko, Sergey V. et al.

In: Inorganic Chemistry, Vol. 57, No. 5, 05.03.2018, p. 2744-2751.

Research output: Contribution to journal › Article › peer-review

Harvard

Bekker, TB, Solntsev, VP, Rashchenko, SV, Yelisseyev, AP, Davydov, AV, Kragzhda, AA, Kokh, AE, Kuznetsov, AB & Park, S 2018, 'Nature of the Color of Borates with "anti-Zeolite" Structure', Inorganic Chemistry, vol. 57, no. 5, pp. 2744-2751. https://doi.org/10.1021/acs.inorgchem.7b03134

APA

Bekker, T. B., Solntsev, V. P., Rashchenko, S. V., Yelisseyev, A. P., Davydov, A. V., Kragzhda, A. A., Kokh, A. E., Kuznetsov, A. B., & Park, S. (2018). Nature of the Color of Borates with "anti-Zeolite" Structure. Inorganic Chemistry, 57(5), 2744-2751. https://doi.org/10.1021/acs.inorgchem.7b03134

Vancouver

Bekker TB, Solntsev VP, Rashchenko SV, Yelisseyev AP, Davydov AV, Kragzhda AA et al. Nature of the Color of Borates with "anti-Zeolite" Structure. Inorganic Chemistry. 2018 Mar 5;57(5):2744-2751. doi: 10.1021/acs.inorgchem.7b03134

Author

Bekker, Tatyana B. ; Solntsev, Vladimir P. ; Rashchenko, Sergey V. et al. / Nature of the Color of Borates with "anti-Zeolite" Structure. In: Inorganic Chemistry. 2018 ; Vol. 57, No. 5. pp. 2744-2751.

BibTeX

@article{49625150870b40dd9d12e5055c78b3a9,
title = "Nature of the Color of Borates with {"}anti-Zeolite{"} Structure",
abstract = "Crystals of the MnxBa12(BO3)8-2xF8x phase were grown from a high-temperature solution. This new fluoride borate is built of positively charged [Ba12(BO3)6]6+ blocks, the so-called {"}anti-zeolite{"} pattern. Using X-ray single-crystal diffraction, the bulk atomic arrangement in the centrosymmetric tetragonal unit cell in I4/mcm could be elucidated. Crystals of the (MnF6)4- group-containing solid solution MnxBa12(BO3)8-2xF8x are dark brown in color in contrast to the differently colored crystals of (LiF4)3- group-containing {"}anti-zeolite{"} LiBa12(BO3)7F4 (P42bc). According to the electron spin resonance and optical spectroscopic investigation, the absorption spectrum of LiBa12(BO3)7F4 crystals results from the absorption of light by both exciton and free charge carriers and can be tuned by varying the initial composition of the high-temperature solution.",
author = "Bekker, {Tatyana B.} and Solntsev, {Vladimir P.} and Rashchenko, {Sergey V.} and Yelisseyev, {Alexander P.} and Davydov, {Alexey V.} and Kragzhda, {Alexander A.} and Kokh, {Alexander E.} and Kuznetsov, {Artem B.} and Sohyun Park",
year = "2018",
month = mar,
day = "5",
doi = "10.1021/acs.inorgchem.7b03134",
language = "English",
volume = "57",
pages = "2744--2751",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "5",

}

RIS

TY - JOUR

T1 - Nature of the Color of Borates with "anti-Zeolite" Structure

AU - Bekker, Tatyana B.

AU - Solntsev, Vladimir P.

AU - Rashchenko, Sergey V.

AU - Yelisseyev, Alexander P.

AU - Davydov, Alexey V.

AU - Kragzhda, Alexander A.

AU - Kokh, Alexander E.

AU - Kuznetsov, Artem B.

AU - Park, Sohyun

PY - 2018/3/5

Y1 - 2018/3/5

N2 - Crystals of the MnxBa12(BO3)8-2xF8x phase were grown from a high-temperature solution. This new fluoride borate is built of positively charged [Ba12(BO3)6]6+ blocks, the so-called "anti-zeolite" pattern. Using X-ray single-crystal diffraction, the bulk atomic arrangement in the centrosymmetric tetragonal unit cell in I4/mcm could be elucidated. Crystals of the (MnF6)4- group-containing solid solution MnxBa12(BO3)8-2xF8x are dark brown in color in contrast to the differently colored crystals of (LiF4)3- group-containing "anti-zeolite" LiBa12(BO3)7F4 (P42bc). According to the electron spin resonance and optical spectroscopic investigation, the absorption spectrum of LiBa12(BO3)7F4 crystals results from the absorption of light by both exciton and free charge carriers and can be tuned by varying the initial composition of the high-temperature solution.

AB - Crystals of the MnxBa12(BO3)8-2xF8x phase were grown from a high-temperature solution. This new fluoride borate is built of positively charged [Ba12(BO3)6]6+ blocks, the so-called "anti-zeolite" pattern. Using X-ray single-crystal diffraction, the bulk atomic arrangement in the centrosymmetric tetragonal unit cell in I4/mcm could be elucidated. Crystals of the (MnF6)4- group-containing solid solution MnxBa12(BO3)8-2xF8x are dark brown in color in contrast to the differently colored crystals of (LiF4)3- group-containing "anti-zeolite" LiBa12(BO3)7F4 (P42bc). According to the electron spin resonance and optical spectroscopic investigation, the absorption spectrum of LiBa12(BO3)7F4 crystals results from the absorption of light by both exciton and free charge carriers and can be tuned by varying the initial composition of the high-temperature solution.

UR - http://www.scopus.com/inward/record.url?scp=85042925257&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.7b03134

DO - 10.1021/acs.inorgchem.7b03134

M3 - Article

C2 - 29457896

AN - SCOPUS:85042925257

VL - 57

SP - 2744

EP - 2751

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 5

ER -

ID: 10353179