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Nature of Bonding in Donor–Acceptor Interactions Exemplified by Complexes of N-Heterocyclic Carbenes with 1,2,5-Telluradiazoles. / Pushkarevsky, Nikolay A.; Petrov, Pavel A.; Grigoriev, Denis S. et al.

In: Chemistry - A European Journal, Vol. 23, No. 46, 16.08.2017, p. 10987-10991.

Research output: Contribution to journal › Article › peer-review

Harvard

Pushkarevsky, NA, Petrov, PA, Grigoriev, DS, Smolentsev, AI, Lee, LM, Kleemiss, F, Salnikov, GE, Konchenko, SN, Vargas-Baca, I, Grabowsky, S, Beckmann, J & Zibarev, AV 2017, 'Nature of Bonding in Donor–Acceptor Interactions Exemplified by Complexes of N-Heterocyclic Carbenes with 1,2,5-Telluradiazoles', Chemistry - A European Journal, vol. 23, no. 46, pp. 10987-10991. https://doi.org/10.1002/chem.201703018

APA

Pushkarevsky, N. A., Petrov, P. A., Grigoriev, D. S., Smolentsev, A. I., Lee, L. M., Kleemiss, F., Salnikov, G. E., Konchenko, S. N., Vargas-Baca, I., Grabowsky, S., Beckmann, J., & Zibarev, A. V. (2017). Nature of Bonding in Donor–Acceptor Interactions Exemplified by Complexes of N-Heterocyclic Carbenes with 1,2,5-Telluradiazoles. Chemistry - A European Journal, 23(46), 10987-10991. https://doi.org/10.1002/chem.201703018

Vancouver

Pushkarevsky NA, Petrov PA, Grigoriev DS, Smolentsev AI, Lee LM, Kleemiss F et al. Nature of Bonding in Donor–Acceptor Interactions Exemplified by Complexes of N-Heterocyclic Carbenes with 1,2,5-Telluradiazoles. Chemistry - A European Journal. 2017 Aug 16;23(46):10987-10991. doi: 10.1002/chem.201703018

Author

Pushkarevsky, Nikolay A. ; Petrov, Pavel A. ; Grigoriev, Denis S. et al. / Nature of Bonding in Donor–Acceptor Interactions Exemplified by Complexes of N-Heterocyclic Carbenes with 1,2,5-Telluradiazoles. In: Chemistry - A European Journal. 2017 ; Vol. 23, No. 46. pp. 10987-10991.

BibTeX

@article{80ecafb59add4241969976a25ce32db0,
title = "Nature of Bonding in Donor–Acceptor Interactions Exemplified by Complexes of N-Heterocyclic Carbenes with 1,2,5-Telluradiazoles",
abstract = "Comprehensive structural, spectroscopic, and quantum chemical analyses of new donor–acceptor complexes between N-heterocyclic carbenes and 1,2,5-telluradiazoles and a comparison with previously known complexes involving tellurenyl cations showed that the dative C−Te bonds cannot be solitarily described with only one Lewis formula. Canonical Lewis formulas that denote covalency and arrows emphasizing ionicity complement each other in varying extents. Evaluation of the relative weights of these resonance forms requires proper bonding description with a well-balanced toolbox of analytical methods. If for conciseness only, one resonance form is used, it must be the most significant one according to the analytical evaluation. If unclear, all significant resonance forms should be displayed.",
keywords = "bond analysis, carbenes, dative bonds, main-group compounds, tellurium",
author = "Pushkarevsky, {Nikolay A.} and Petrov, {Pavel A.} and Grigoriev, {Denis S.} and Smolentsev, {Anton I.} and Lee, {Lucia M.} and Florian Kleemiss and Salnikov, {Georgy E.} and Konchenko, {Sergey N.} and Ignacio Vargas-Baca and Simon Grabowsky and Jens Beckmann and Zibarev, {Andrey V.}",
note = "{\textcopyright} 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.",
year = "2017",
month = aug,
day = "16",
doi = "10.1002/chem.201703018",
language = "English",
volume = "23",
pages = "10987--10991",
journal = "Chemistry - A European Journal",
issn = "0947-6539",
publisher = "Wiley-VCH Verlag",
number = "46",

}

RIS

TY - JOUR

T1 - Nature of Bonding in Donor–Acceptor Interactions Exemplified by Complexes of N-Heterocyclic Carbenes with 1,2,5-Telluradiazoles

AU - Pushkarevsky, Nikolay A.

AU - Petrov, Pavel A.

AU - Grigoriev, Denis S.

AU - Smolentsev, Anton I.

AU - Lee, Lucia M.

AU - Kleemiss, Florian

AU - Salnikov, Georgy E.

AU - Konchenko, Sergey N.

AU - Vargas-Baca, Ignacio

AU - Grabowsky, Simon

AU - Beckmann, Jens

AU - Zibarev, Andrey V.

N1 - © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

PY - 2017/8/16

Y1 - 2017/8/16

N2 - Comprehensive structural, spectroscopic, and quantum chemical analyses of new donor–acceptor complexes between N-heterocyclic carbenes and 1,2,5-telluradiazoles and a comparison with previously known complexes involving tellurenyl cations showed that the dative C−Te bonds cannot be solitarily described with only one Lewis formula. Canonical Lewis formulas that denote covalency and arrows emphasizing ionicity complement each other in varying extents. Evaluation of the relative weights of these resonance forms requires proper bonding description with a well-balanced toolbox of analytical methods. If for conciseness only, one resonance form is used, it must be the most significant one according to the analytical evaluation. If unclear, all significant resonance forms should be displayed.

AB - Comprehensive structural, spectroscopic, and quantum chemical analyses of new donor–acceptor complexes between N-heterocyclic carbenes and 1,2,5-telluradiazoles and a comparison with previously known complexes involving tellurenyl cations showed that the dative C−Te bonds cannot be solitarily described with only one Lewis formula. Canonical Lewis formulas that denote covalency and arrows emphasizing ionicity complement each other in varying extents. Evaluation of the relative weights of these resonance forms requires proper bonding description with a well-balanced toolbox of analytical methods. If for conciseness only, one resonance form is used, it must be the most significant one according to the analytical evaluation. If unclear, all significant resonance forms should be displayed.

KW - bond analysis

KW - carbenes

KW - dative bonds

KW - main-group compounds

KW - tellurium

UR - http://www.scopus.com/inward/record.url?scp=85026457294&partnerID=8YFLogxK

U2 - 10.1002/chem.201703018

DO - 10.1002/chem.201703018

M3 - Article

C2 - 28675774

AN - SCOPUS:85026457294

VL - 23

SP - 10987

EP - 10991

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

IS - 46

ER -

ID: 9053790