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Nanoscale heterogeneities in ionic liquids : insights from EPR of spin probes. / Ivanov, Mikhail Yu; Fedin, Matvey V.

In: Mendeleev Communications, Vol. 28, No. 6, 01.11.2018, p. 565-573.

Research output: Contribution to journal › Article › peer-review

Harvard

Ivanov, MY & Fedin, MV 2018, 'Nanoscale heterogeneities in ionic liquids: insights from EPR of spin probes', Mendeleev Communications, vol. 28, no. 6, pp. 565-573. https://doi.org/10.1016/j.mencom.2018.11.001

APA

Ivanov, M. Y., & Fedin, M. V. (2018). Nanoscale heterogeneities in ionic liquids: insights from EPR of spin probes. Mendeleev Communications, 28(6), 565-573. https://doi.org/10.1016/j.mencom.2018.11.001

Vancouver

Ivanov MY, Fedin MV. Nanoscale heterogeneities in ionic liquids: insights from EPR of spin probes. Mendeleev Communications. 2018 Nov 1;28(6):565-573. doi: 10.1016/j.mencom.2018.11.001

Author

Ivanov, Mikhail Yu ; Fedin, Matvey V. / Nanoscale heterogeneities in ionic liquids : insights from EPR of spin probes. In: Mendeleev Communications. 2018 ; Vol. 28, No. 6. pp. 565-573.

BibTeX

@article{6a6de25d07914ce981e80ad3b19bafb5,
title = "Nanoscale heterogeneities in ionic liquids: insights from EPR of spin probes",
abstract = "Self-organization is an important property of room-temperature ionic liquids (ILs). In particular, it gives rise to various heterogeneities occurring on the nanometer scale. However, the detection and characterization of such heterogeneities is often challenging, and the development of new experimental approaches for such studies is highly demanded. In this work we review recent progress in applications of electron paramagnetic resonance (EPR) to study heterogeneities in ILs over a broad temperature range. Since ILs are naturally diamagnetic, various spin probes and corresponding techniques have been used. We demonstrate that complex application of continuous wave, pulse and time-resolved EPR allows one to obtain unique information on formation and properties of heterogeneities in ILs, fruitfully complementing the data of other methods.",
keywords = "ELECTRON-PARAMAGNETIC-RESONANCE, TIME-RESOLVED EPR, PHOTOEXCITED TRIPLET-STATE, EXCITED-TRIPLET, ZINC(II) TETRAPHENYLPORPHYRIN, SPATIAL HETEROGENEITY, LIBRATION MOTION, STEADY-STATE, DYNAMICS, WATER",
author = "Ivanov, {Mikhail Yu} and Fedin, {Matvey V.}",
year = "2018",
month = nov,
day = "1",
doi = "10.1016/j.mencom.2018.11.001",
language = "English",
volume = "28",
pages = "565--573",
journal = "Mendeleev Communications",
issn = "0959-9436",
publisher = "Elsevier",
number = "6",

}

RIS

TY - JOUR

T1 - Nanoscale heterogeneities in ionic liquids

T2 - insights from EPR of spin probes

AU - Ivanov, Mikhail Yu

AU - Fedin, Matvey V.

PY - 2018/11/1

Y1 - 2018/11/1

N2 - Self-organization is an important property of room-temperature ionic liquids (ILs). In particular, it gives rise to various heterogeneities occurring on the nanometer scale. However, the detection and characterization of such heterogeneities is often challenging, and the development of new experimental approaches for such studies is highly demanded. In this work we review recent progress in applications of electron paramagnetic resonance (EPR) to study heterogeneities in ILs over a broad temperature range. Since ILs are naturally diamagnetic, various spin probes and corresponding techniques have been used. We demonstrate that complex application of continuous wave, pulse and time-resolved EPR allows one to obtain unique information on formation and properties of heterogeneities in ILs, fruitfully complementing the data of other methods.

AB - Self-organization is an important property of room-temperature ionic liquids (ILs). In particular, it gives rise to various heterogeneities occurring on the nanometer scale. However, the detection and characterization of such heterogeneities is often challenging, and the development of new experimental approaches for such studies is highly demanded. In this work we review recent progress in applications of electron paramagnetic resonance (EPR) to study heterogeneities in ILs over a broad temperature range. Since ILs are naturally diamagnetic, various spin probes and corresponding techniques have been used. We demonstrate that complex application of continuous wave, pulse and time-resolved EPR allows one to obtain unique information on formation and properties of heterogeneities in ILs, fruitfully complementing the data of other methods.

KW - ELECTRON-PARAMAGNETIC-RESONANCE

KW - TIME-RESOLVED EPR

KW - PHOTOEXCITED TRIPLET-STATE

KW - EXCITED-TRIPLET

KW - ZINC(II) TETRAPHENYLPORPHYRIN

KW - SPATIAL HETEROGENEITY

KW - LIBRATION MOTION

KW - STEADY-STATE

KW - DYNAMICS

KW - WATER

UR - http://www.scopus.com/inward/record.url?scp=85057581227&partnerID=8YFLogxK

U2 - 10.1016/j.mencom.2018.11.001

DO - 10.1016/j.mencom.2018.11.001

M3 - Article

AN - SCOPUS:85057581227

VL - 28

SP - 565

EP - 573

JO - Mendeleev Communications

JF - Mendeleev Communications

SN - 0959-9436

IS - 6

ER -

ID: 17686678