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Na4Ca(CO3)3 : A novel carbonate analog of borate optical materials. / Rashchenko, Sergey V.; Shatskiy, Anton F.; Arefiev, Anton V. et al.

In: CrystEngComm, Vol. 20, No. 35, 21.09.2018, p. 5228-5232.

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Rashchenko SV, Shatskiy AF, Arefiev AV, Seryotkin YV, Litasov KD. Na4Ca(CO3)3: A novel carbonate analog of borate optical materials. CrystEngComm. 2018 Sept 21;20(35):5228-5232. doi: 10.1039/c8ce00745d

Author

Rashchenko, Sergey V. ; Shatskiy, Anton F. ; Arefiev, Anton V. et al. / Na4Ca(CO3)3 : A novel carbonate analog of borate optical materials. In: CrystEngComm. 2018 ; Vol. 20, No. 35. pp. 5228-5232.

BibTeX

@article{9c47d889f99740d281b08aedbb812998,
title = "Na4Ca(CO3)3: A novel carbonate analog of borate optical materials",
abstract = "Carbonate optical materials currently attract a lot of interest as an unexplored alternative to borate ones. However, these two classes of compounds were believed to have quite different crystal chemistry, so that no systematic attempts were made to reproduce crystal structures of known borate optical materials in carbonates. Here we describe a novel Na4Ca(CO3)3 cubic carbonate (Ia3d, a = 15.5770(5) {\AA}), isostructural to borates of the NaBa4(BO3)3 family known for their phosphor properties, and discuss further perspectives in the investigation of {\textquoteleft}borate-structured' carbonate materials.",
keywords = "LIGHT-EMITTING-DIODES, FLUORIDE CARBONATE, DEGREES-C, 6 GPA, PHOSPHOR, CRYSTAL, ULTRAVIOLET, SYSTEM, EMISSION, SR",
author = "Rashchenko, {Sergey V.} and Shatskiy, {Anton F.} and Arefiev, {Anton V.} and Seryotkin, {Yurii V.} and Litasov, {Konstantin D.}",
note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",
year = "2018",
month = sep,
day = "21",
doi = "10.1039/c8ce00745d",
language = "English",
volume = "20",
pages = "5228--5232",
journal = "CrystEngComm",
issn = "1466-8033",
publisher = "Royal Society of Chemistry",
number = "35",

}

RIS

TY - JOUR

T1 - Na4Ca(CO3)3

T2 - A novel carbonate analog of borate optical materials

AU - Rashchenko, Sergey V.

AU - Shatskiy, Anton F.

AU - Arefiev, Anton V.

AU - Seryotkin, Yurii V.

AU - Litasov, Konstantin D.

N1 - Publisher Copyright: © The Royal Society of Chemistry.

PY - 2018/9/21

Y1 - 2018/9/21

N2 - Carbonate optical materials currently attract a lot of interest as an unexplored alternative to borate ones. However, these two classes of compounds were believed to have quite different crystal chemistry, so that no systematic attempts were made to reproduce crystal structures of known borate optical materials in carbonates. Here we describe a novel Na4Ca(CO3)3 cubic carbonate (Ia3d, a = 15.5770(5) Å), isostructural to borates of the NaBa4(BO3)3 family known for their phosphor properties, and discuss further perspectives in the investigation of ‘borate-structured' carbonate materials.

AB - Carbonate optical materials currently attract a lot of interest as an unexplored alternative to borate ones. However, these two classes of compounds were believed to have quite different crystal chemistry, so that no systematic attempts were made to reproduce crystal structures of known borate optical materials in carbonates. Here we describe a novel Na4Ca(CO3)3 cubic carbonate (Ia3d, a = 15.5770(5) Å), isostructural to borates of the NaBa4(BO3)3 family known for their phosphor properties, and discuss further perspectives in the investigation of ‘borate-structured' carbonate materials.

KW - LIGHT-EMITTING-DIODES

KW - FLUORIDE CARBONATE

KW - DEGREES-C

KW - 6 GPA

KW - PHOSPHOR

KW - CRYSTAL

KW - ULTRAVIOLET

KW - SYSTEM

KW - EMISSION

KW - SR

UR - http://www.scopus.com/inward/record.url?scp=85053417263&partnerID=8YFLogxK

U2 - 10.1039/c8ce00745d

DO - 10.1039/c8ce00745d

M3 - Article

AN - SCOPUS:85053417263

VL - 20

SP - 5228

EP - 5232

JO - CrystEngComm

JF - CrystEngComm

SN - 1466-8033

IS - 35

ER -

ID: 16600777