Research output: Contribution to journal › Article › peer-review
Mononuclear Molybdenum Oxohalide Complexes (Bu4N)[MoOCl4(H2O)] and (Bu4N)[MoOBr4(H2O)] : Synthesis and Crystal Structures. / Adonin, S. A.; Udalova, L. I.; Abramov, P. A. et al.
In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 44, No. 11, 01.11.2018, p. 673-677.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Mononuclear Molybdenum Oxohalide Complexes (Bu4N)[MoOCl4(H2O)] and (Bu4N)[MoOBr4(H2O)]
T2 - Synthesis and Crystal Structures
AU - Adonin, S. A.
AU - Udalova, L. I.
AU - Abramov, P. A.
AU - Sokolov, M. N.
AU - Fedin, V. P.
PY - 2018/11/1
Y1 - 2018/11/1
N2 - Abstract: The oxidation of K3[MoCl6] with air oxygen in aqueous solutions of HX (X = Cl, Br) in the presence of n-tetrabutylammonium salts affords mononuclear heteroligand complexes (Bu4N)[MoOCl4(H2O)] (I) and (Bu4N)[MoOBr4(H2O)] (II). The complexes are characterized by X-ray diffraction analysis (СIF files CCDC nos. 1812657 (I) and 1812658 (II).
AB - Abstract: The oxidation of K3[MoCl6] with air oxygen in aqueous solutions of HX (X = Cl, Br) in the presence of n-tetrabutylammonium salts affords mononuclear heteroligand complexes (Bu4N)[MoOCl4(H2O)] (I) and (Bu4N)[MoOBr4(H2O)] (II). The complexes are characterized by X-ray diffraction analysis (СIF files CCDC nos. 1812657 (I) and 1812658 (II).
KW - halide complexes
KW - heteroligand complexes
KW - molybdenum
KW - X-ray diffraction analysis
KW - HALIDES
KW - CORE
KW - LIGANDS
KW - OXOTETRABROMOMOLYBDENUM(V)
KW - PYRIDINE
UR - http://www.scopus.com/inward/record.url?scp=85054909194&partnerID=8YFLogxK
U2 - 10.1134/S1070328418110015
DO - 10.1134/S1070328418110015
M3 - Article
AN - SCOPUS:85054909194
VL - 44
SP - 673
EP - 677
JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
SN - 1070-3284
IS - 11
ER -
ID: 17115374