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Mono- and Dinuclear Rare-Earth Chlorides Ligated by a Mesityl-Substituted β-Diketiminate. / Klementyeva, Svetlana V.; Afonin, Mikhail Yu; Bogomyakov, Artem S. et al.

In: European Journal of Inorganic Chemistry, Vol. 2016, No. 22, 2016, p. 3666-3672.

Research output: Contribution to journal › Article › peer-review

Harvard

Klementyeva, SV, Afonin, MY, Bogomyakov, AS, Gamer, MT, Roesky, PW & Konchenko, SN 2016, 'Mono- and Dinuclear Rare-Earth Chlorides Ligated by a Mesityl-Substituted β-Diketiminate', European Journal of Inorganic Chemistry, vol. 2016, no. 22, pp. 3666-3672. https://doi.org/10.1002/ejic.201600488

APA

Klementyeva, S. V., Afonin, M. Y., Bogomyakov, A. S., Gamer, M. T., Roesky, P. W., & Konchenko, S. N. (2016). Mono- and Dinuclear Rare-Earth Chlorides Ligated by a Mesityl-Substituted β-Diketiminate. European Journal of Inorganic Chemistry, 2016(22), 3666-3672. https://doi.org/10.1002/ejic.201600488

Vancouver

Klementyeva SV, Afonin MY, Bogomyakov AS, Gamer MT, Roesky PW, Konchenko SN. Mono- and Dinuclear Rare-Earth Chlorides Ligated by a Mesityl-Substituted β-Diketiminate. European Journal of Inorganic Chemistry. 2016;2016(22):3666-3672. doi: 10.1002/ejic.201600488

Author

Klementyeva, Svetlana V. ; Afonin, Mikhail Yu ; Bogomyakov, Artem S. et al. / Mono- and Dinuclear Rare-Earth Chlorides Ligated by a Mesityl-Substituted β-Diketiminate. In: European Journal of Inorganic Chemistry. 2016 ; Vol. 2016, No. 22. pp. 3666-3672.

BibTeX

@article{355b4852bdc84c85b02180af0d2fefac,
title = "Mono- and Dinuclear Rare-Earth Chlorides Ligated by a Mesityl-Substituted β-Diketiminate",
abstract = "The metathesis reaction of anhydrous LnCl3(Ln = Y, Dy, Er, Sm, Yb) with the potassium salt KL [L = 2,4,6-Me3C6H2-NC(Me)CHC(Me)N-2,4,6-Me3C6H2], a mesityl-substituted β-diketiminate, is described. Dinuclear complexes with an unusual triple chlorido bridge in the molecule [LClLn(µ-Cl)3LnL(THF)] [Ln = Y (1a) and Dy (1b)] were obtained by recrystallization from a mixture of non-polar solvents (toluene/n-pentane) in low yield. In contrast, the crystallization in the presence of THF led to the isolation of mononuclear complexes [LLnCl2(THF)2] [Ln = Y (2a), Dy (2b), Er (2c), Sm (2d), Yb (2e)] in good yields. Compounds 1b and 2a–e were fully characterized, and the solid-state structures of 1a,b and 2a–c were determined by single-crystal X-ray diffraction. The magnetic properties of 2b were studied in detail.",
keywords = "Lanthanides, Magnetic properties, Rare earths, Synthetic methods, β-Diketiminato ligands",
author = "Klementyeva, {Svetlana V.} and Afonin, {Mikhail Yu} and Bogomyakov, {Artem S.} and Gamer, {Michael T.} and Roesky, {Peter W.} and Konchenko, {Sergey N.}",
year = "2016",
doi = "10.1002/ejic.201600488",
language = "English",
volume = "2016",
pages = "3666--3672",
journal = "European Journal of Inorganic Chemistry",
issn = "1434-1948",
publisher = "Wiley-VCH Verlag",
number = "22",

}

RIS

TY - JOUR

T1 - Mono- and Dinuclear Rare-Earth Chlorides Ligated by a Mesityl-Substituted β-Diketiminate

AU - Klementyeva, Svetlana V.

AU - Afonin, Mikhail Yu

AU - Bogomyakov, Artem S.

AU - Gamer, Michael T.

AU - Roesky, Peter W.

AU - Konchenko, Sergey N.

PY - 2016

Y1 - 2016

N2 - The metathesis reaction of anhydrous LnCl3(Ln = Y, Dy, Er, Sm, Yb) with the potassium salt KL [L = 2,4,6-Me3C6H2-NC(Me)CHC(Me)N-2,4,6-Me3C6H2], a mesityl-substituted β-diketiminate, is described. Dinuclear complexes with an unusual triple chlorido bridge in the molecule [LClLn(µ-Cl)3LnL(THF)] [Ln = Y (1a) and Dy (1b)] were obtained by recrystallization from a mixture of non-polar solvents (toluene/n-pentane) in low yield. In contrast, the crystallization in the presence of THF led to the isolation of mononuclear complexes [LLnCl2(THF)2] [Ln = Y (2a), Dy (2b), Er (2c), Sm (2d), Yb (2e)] in good yields. Compounds 1b and 2a–e were fully characterized, and the solid-state structures of 1a,b and 2a–c were determined by single-crystal X-ray diffraction. The magnetic properties of 2b were studied in detail.

AB - The metathesis reaction of anhydrous LnCl3(Ln = Y, Dy, Er, Sm, Yb) with the potassium salt KL [L = 2,4,6-Me3C6H2-NC(Me)CHC(Me)N-2,4,6-Me3C6H2], a mesityl-substituted β-diketiminate, is described. Dinuclear complexes with an unusual triple chlorido bridge in the molecule [LClLn(µ-Cl)3LnL(THF)] [Ln = Y (1a) and Dy (1b)] were obtained by recrystallization from a mixture of non-polar solvents (toluene/n-pentane) in low yield. In contrast, the crystallization in the presence of THF led to the isolation of mononuclear complexes [LLnCl2(THF)2] [Ln = Y (2a), Dy (2b), Er (2c), Sm (2d), Yb (2e)] in good yields. Compounds 1b and 2a–e were fully characterized, and the solid-state structures of 1a,b and 2a–c were determined by single-crystal X-ray diffraction. The magnetic properties of 2b were studied in detail.

KW - Lanthanides

KW - Magnetic properties

KW - Rare earths

KW - Synthetic methods

KW - β-Diketiminato ligands

UR - http://www.scopus.com/inward/record.url?scp=84978039237&partnerID=8YFLogxK

U2 - 10.1002/ejic.201600488

DO - 10.1002/ejic.201600488

M3 - Article

AN - SCOPUS:84978039237

VL - 2016

SP - 3666

EP - 3672

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

SN - 1434-1948

IS - 22

ER -

ID: 25413877