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Mixed-Ligand Iridium(III) Nitro Complexes with Phenantroline. / Topchiyan, P. A.; Vasilchenko, D. B.; Tkachev, S. V. et al.

In: Journal of Structural Chemistry, Vol. 60, No. 4, 01.04.2019, p. 640-646.

Research output: Contribution to journal › Article › peer-review

Harvard

Topchiyan, PA, Vasilchenko, DB, Tkachev, SV, Baydina, IA, Korolkov, IV, Sheven, DG & Korenev, SV 2019, 'Mixed-Ligand Iridium(III) Nitro Complexes with Phenantroline', Journal of Structural Chemistry, vol. 60, no. 4, pp. 640-646. https://doi.org/10.1134/S0022476619040152

APA

Topchiyan, P. A., Vasilchenko, D. B., Tkachev, S. V., Baydina, I. A., Korolkov, I. V., Sheven, D. G., & Korenev, S. V. (2019). Mixed-Ligand Iridium(III) Nitro Complexes with Phenantroline. Journal of Structural Chemistry, 60(4), 640-646. https://doi.org/10.1134/S0022476619040152

Vancouver

Topchiyan PA, Vasilchenko DB, Tkachev SV, Baydina IA, Korolkov IV, Sheven DG et al. Mixed-Ligand Iridium(III) Nitro Complexes with Phenantroline. Journal of Structural Chemistry. 2019 Apr 1;60(4):640-646. doi: 10.1134/S0022476619040152

Author

Topchiyan, P. A. ; Vasilchenko, D. B. ; Tkachev, S. V. et al. / Mixed-Ligand Iridium(III) Nitro Complexes with Phenantroline. In: Journal of Structural Chemistry. 2019 ; Vol. 60, No. 4. pp. 640-646.

BibTeX

@article{98786a0c9ed34c0094dd65a8db172b8d,
title = "Mixed-Ligand Iridium(III) Nitro Complexes with Phenantroline",
abstract = " Interaction of iridium(III) nitro-aqua complexes with 1,10-phenanthroline is studied. Complex anions [Ir(phen)(NO 2 ) 4 ] − and [Ir(phen)(OH)(NO 2 ) 3 ] − are isolated in the solid phase. The complex Na[Ir(phen)(NO 2 ) 4 ](phen)(H 2 O) is structurally characterized for the first time. Crystallographic data: a= 8.0752 (5) Ǻ, b= 11.690 (7) Ǻ, c= 14.012 (7) α, α = 105.55(2)°, β = 91,99(2)°, γ = 103,71(2)° space group P-1, Z = 2, ρ calc = 1,936 g/cm 3 . The coordination sphere of the iridium atom has a distorted octahedral geometry. The obtained structure contains an island motif consisting of the pairs of complex anions [Ir(phen)(NO 2 ) 4 ] − linked to each other by sodium cations. ",
keywords = "aquacomplexes, iridium, mass spectrometry, nitro complexes, NMR, phenanthroline, X-ray diffraction, CRYSTAL-STRUCTURE, RH, CARBONYL-COMPOUNDS",
author = "Topchiyan, {P. A.} and Vasilchenko, {D. B.} and Tkachev, {S. V.} and Baydina, {I. A.} and Korolkov, {I. V.} and Sheven, {D. G.} and Korenev, {S. V.}",
year = "2019",
month = apr,
day = "1",
doi = "10.1134/S0022476619040152",
language = "English",
volume = "60",
pages = "640--646",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "4",

}

RIS

TY - JOUR

T1 - Mixed-Ligand Iridium(III) Nitro Complexes with Phenantroline

AU - Topchiyan, P. A.

AU - Vasilchenko, D. B.

AU - Tkachev, S. V.

AU - Baydina, I. A.

AU - Korolkov, I. V.

AU - Sheven, D. G.

AU - Korenev, S. V.

PY - 2019/4/1

Y1 - 2019/4/1

N2 - Interaction of iridium(III) nitro-aqua complexes with 1,10-phenanthroline is studied. Complex anions [Ir(phen)(NO 2 ) 4 ] − and [Ir(phen)(OH)(NO 2 ) 3 ] − are isolated in the solid phase. The complex Na[Ir(phen)(NO 2 ) 4 ](phen)(H 2 O) is structurally characterized for the first time. Crystallographic data: a= 8.0752 (5) Ǻ, b= 11.690 (7) Ǻ, c= 14.012 (7) α, α = 105.55(2)°, β = 91,99(2)°, γ = 103,71(2)° space group P-1, Z = 2, ρ calc = 1,936 g/cm 3 . The coordination sphere of the iridium atom has a distorted octahedral geometry. The obtained structure contains an island motif consisting of the pairs of complex anions [Ir(phen)(NO 2 ) 4 ] − linked to each other by sodium cations.

AB - Interaction of iridium(III) nitro-aqua complexes with 1,10-phenanthroline is studied. Complex anions [Ir(phen)(NO 2 ) 4 ] − and [Ir(phen)(OH)(NO 2 ) 3 ] − are isolated in the solid phase. The complex Na[Ir(phen)(NO 2 ) 4 ](phen)(H 2 O) is structurally characterized for the first time. Crystallographic data: a= 8.0752 (5) Ǻ, b= 11.690 (7) Ǻ, c= 14.012 (7) α, α = 105.55(2)°, β = 91,99(2)°, γ = 103,71(2)° space group P-1, Z = 2, ρ calc = 1,936 g/cm 3 . The coordination sphere of the iridium atom has a distorted octahedral geometry. The obtained structure contains an island motif consisting of the pairs of complex anions [Ir(phen)(NO 2 ) 4 ] − linked to each other by sodium cations.

KW - aquacomplexes

KW - iridium

KW - mass spectrometry

KW - nitro complexes

KW - NMR

KW - phenanthroline

KW - X-ray diffraction

KW - CRYSTAL-STRUCTURE

KW - RH

KW - CARBONYL-COMPOUNDS

UR - http://www.scopus.com/inward/record.url?scp=85065414072&partnerID=8YFLogxK

U2 - 10.1134/S0022476619040152

DO - 10.1134/S0022476619040152

M3 - Article

AN - SCOPUS:85065414072

VL - 60

SP - 640

EP - 646

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 4

ER -

ID: 20051393