Mineralogical diversity of ca2 sio4-bearing combustion metamorphic rocks in the hatrurim basin

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Mineralogical diversity of ca₂ sio₄-bearing combustion metamorphic rocks in the hatrurim basin : Implications for storage and partitioning of elements in oil shale clinkering. / Sokol, Ella V.; Kokh, Svetlana N.; Sharygin, Victor V. et al.

In: Minerals, Vol. 9, No. 8, 465, 01.08.2019.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{3f9625020dde410db2679cfb867959ea,

title = "Mineralogical diversity of ca2 sio4-bearing combustion metamorphic rocks in the hatrurim basin: Implications for storage and partitioning of elements in oil shale clinkering",

abstract = "This is the first attempt to provide a general mineralogical and geochemical survey of natural Ca2 SiO4-bearing combustion metamorphic (CM) rocks produced by annealing and decarbonation of bioproductive Maastrichtian oil shales in the Hatrurim Basin (Negev Desert, Israel). We present a synthesis of data collected for fifteen years on thirty nine minerals existing as fairly large grains suitable for analytical examination. The Hatrurim Ca2 SiO4-bearing CM rocks, which are natural analogs of industrial cement clinker, have been studied comprehensively, with a focus on several key issues: major-and trace-element compositions of the rocks and their sedimentary precursors; mineral chemistry of rock-forming phases; accessory mineralogy; incorporation of heavy metals and other trace elements into different phases of clinker-like natural assemblages; role of trace elements in stabilization/destabilization of Ca2 SiO4 polymorphic modifications; mineralogical diversity of Ca2 SiO4-bearing CM rocks and trace element partitioning during high-temperature–low-pressure anhydrous sintering. The reported results have implications for mineral formation and element partitioning during high-temperature–low-pressure combustion metamorphism of trace element-loaded bituminous marine chalky sediments (“oil shales”) as well as for the joint effect of multiple elements on the properties and hydration behavior of crystalline phases in industrial cement clinkers.",

keywords = "Ca SiO modifications, Cement clinker, Combustion metamorphism, Flamite, Hatrurim Formation, Larnite, Mayenite, Threshold limits, Trace element partitioning, Ye{\textquoteright}elimite, NEGEV DESERT, PALESTINIAN AUTONOMY, NATURAL ANALOG, PYROMETAMORPHIC ROCKS, threshold limits, LARNITE ROCKS, SOLID-SOLUTION, mayenite, Ca2SiO4 modifications, MOTTLED ZONE COMPLEX, DEAD-SEA, JABEL HARMUN, combustion metamorphism, trace element partitioning, CRYSTAL-STRUCTURE, larnite, ye'elimite, cement clinker, flamite",

author = "Sokol, {Ella V.} and Kokh, {Svetlana N.} and Sharygin, {Victor V.} and Danilovsky, {Victoria A.} and Seryotkin, {Yurii V.} and Ruslan Liferovich and Deviatiiarova, {Anna S.} and Nigmatulina, {Elena N.} and Karmanov, {Nikolay S.}",

note = "Publisher Copyright: {\textcopyright} 2019 by the authors. Licensee MDPI, Basel, Switzerland.",

year = "2019",

month = aug,

day = "1",

doi = "10.3390/min9080465",

language = "English",

volume = "9",

journal = "Minerals",

issn = "2075-163X",

publisher = "MDPI AG",

number = "8",

}

RIS

TY - JOUR

T1 - Mineralogical diversity of ca2 sio4-bearing combustion metamorphic rocks in the hatrurim basin

T2 - Implications for storage and partitioning of elements in oil shale clinkering

AU - Sokol, Ella V.

AU - Kokh, Svetlana N.

AU - Sharygin, Victor V.

AU - Danilovsky, Victoria A.

AU - Seryotkin, Yurii V.

AU - Liferovich, Ruslan

AU - Deviatiiarova, Anna S.

AU - Nigmatulina, Elena N.

AU - Karmanov, Nikolay S.

PY - 2019/8/1

Y1 - 2019/8/1

N2 - This is the first attempt to provide a general mineralogical and geochemical survey of natural Ca2 SiO4-bearing combustion metamorphic (CM) rocks produced by annealing and decarbonation of bioproductive Maastrichtian oil shales in the Hatrurim Basin (Negev Desert, Israel). We present a synthesis of data collected for fifteen years on thirty nine minerals existing as fairly large grains suitable for analytical examination. The Hatrurim Ca2 SiO4-bearing CM rocks, which are natural analogs of industrial cement clinker, have been studied comprehensively, with a focus on several key issues: major-and trace-element compositions of the rocks and their sedimentary precursors; mineral chemistry of rock-forming phases; accessory mineralogy; incorporation of heavy metals and other trace elements into different phases of clinker-like natural assemblages; role of trace elements in stabilization/destabilization of Ca2 SiO4 polymorphic modifications; mineralogical diversity of Ca2 SiO4-bearing CM rocks and trace element partitioning during high-temperature–low-pressure anhydrous sintering. The reported results have implications for mineral formation and element partitioning during high-temperature–low-pressure combustion metamorphism of trace element-loaded bituminous marine chalky sediments (“oil shales”) as well as for the joint effect of multiple elements on the properties and hydration behavior of crystalline phases in industrial cement clinkers.

AB - This is the first attempt to provide a general mineralogical and geochemical survey of natural Ca2 SiO4-bearing combustion metamorphic (CM) rocks produced by annealing and decarbonation of bioproductive Maastrichtian oil shales in the Hatrurim Basin (Negev Desert, Israel). We present a synthesis of data collected for fifteen years on thirty nine minerals existing as fairly large grains suitable for analytical examination. The Hatrurim Ca2 SiO4-bearing CM rocks, which are natural analogs of industrial cement clinker, have been studied comprehensively, with a focus on several key issues: major-and trace-element compositions of the rocks and their sedimentary precursors; mineral chemistry of rock-forming phases; accessory mineralogy; incorporation of heavy metals and other trace elements into different phases of clinker-like natural assemblages; role of trace elements in stabilization/destabilization of Ca2 SiO4 polymorphic modifications; mineralogical diversity of Ca2 SiO4-bearing CM rocks and trace element partitioning during high-temperature–low-pressure anhydrous sintering. The reported results have implications for mineral formation and element partitioning during high-temperature–low-pressure combustion metamorphism of trace element-loaded bituminous marine chalky sediments (“oil shales”) as well as for the joint effect of multiple elements on the properties and hydration behavior of crystalline phases in industrial cement clinkers.

KW - Ca SiO modifications

KW - Cement clinker

KW - Combustion metamorphism

KW - Flamite

KW - Hatrurim Formation

KW - Larnite

KW - Mayenite

KW - Threshold limits

KW - Trace element partitioning

KW - Ye’elimite

KW - NEGEV DESERT

KW - PALESTINIAN AUTONOMY

KW - NATURAL ANALOG

KW - PYROMETAMORPHIC ROCKS

KW - threshold limits

KW - LARNITE ROCKS

KW - SOLID-SOLUTION

KW - mayenite

KW - Ca2SiO4 modifications

KW - MOTTLED ZONE COMPLEX

KW - DEAD-SEA

KW - JABEL HARMUN

KW - combustion metamorphism

KW - trace element partitioning

KW - CRYSTAL-STRUCTURE

KW - larnite

KW - ye'elimite

KW - cement clinker

KW - flamite

UR - http://www.scopus.com/inward/record.url?scp=85070480144&partnerID=8YFLogxK

U2 - 10.3390/min9080465

DO - 10.3390/min9080465

M3 - Article

AN - SCOPUS:85070480144

VL - 9

JO - Minerals

JF - Minerals

SN - 2075-163X

IS - 8

M1 - 465

ER -

ID: 21256000

Mineralogical diversity of ca2 sio4-bearing combustion metamorphic rocks in the hatrurim basin: Implications for storage and partitioning of elements in oil shale clinkering

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Mineralogical diversity of ca₂ sio₄-bearing combustion metamorphic rocks in the hatrurim basin: Implications for storage and partitioning of elements in oil shale clinkering