Research output: Contribution to journal › Article › peer-review
Methyl Methacrylate Copolymer with Pendant Thioxanthenone Groups as Active Layer for Resistive Memory Devices. / Odintsov, Danila S.; Gismatulin, Andrei A.; Shundrina, Inna K. et al.
In: ChemPhysChem, Vol. 25, No. 21, e202400266, 04.11.2024.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Methyl Methacrylate Copolymer with Pendant Thioxanthenone Groups as Active Layer for Resistive Memory Devices
AU - Odintsov, Danila S.
AU - Gismatulin, Andrei A.
AU - Shundrina, Inna K.
AU - Buktoyarova, Alexandra D.
AU - Os'kina, Irina A.
AU - Beckmann, Jens
AU - Azarov, Ivan A.
AU - Dementeva, Ekaterina V.
AU - Shundrin, Leonid A.
AU - Gritsenko, Vladimir A.
N1 - Project 22-13-00108, synthesis, device fabrication, electrophysical measurements) and the Deutsche Forschungsgemeinschaft project BE 3616/6-2, spectroelectrochemistry.
PY - 2024/11/4
Y1 - 2024/11/4
N2 - An electro-active copolymer of methyl methacrylate and 2-((4-acroylpiperazine-1-yl)methyl)-9H-thioxanthene-9-one (poly(MMA-co-ThS)) was synthesized by radical polymerization. The copolymer has good solubility in most organic solvents, thermal stability up to 282 °C and excellent ability to form thin films on silicon wafers. Poly(MMA-co-ThS) films exhibited an electrochemical and electrochromic activity resulting in the formation of long-lived radical anion states of pendant thioxanthone groups inside the film. These states exhibit optical transitions in the visible region as a broad optical absorption band, 500
AB - An electro-active copolymer of methyl methacrylate and 2-((4-acroylpiperazine-1-yl)methyl)-9H-thioxanthene-9-one (poly(MMA-co-ThS)) was synthesized by radical polymerization. The copolymer has good solubility in most organic solvents, thermal stability up to 282 °C and excellent ability to form thin films on silicon wafers. Poly(MMA-co-ThS) films exhibited an electrochemical and electrochromic activity resulting in the formation of long-lived radical anion states of pendant thioxanthone groups inside the film. These states exhibit optical transitions in the visible region as a broad optical absorption band, 500
KW - Charge transport
KW - Memristor
KW - Organic polymers
KW - Pendant groups
KW - Spectroelectrochemistry
UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85202055309&origin=inward&txGid=b299aa57f05d462fac2cc4364f5365eb
UR - https://www.mendeley.com/catalogue/974789f6-ff76-354a-8976-fe3cce40dfe7/
U2 - 10.1002/cphc.202400266
DO - 10.1002/cphc.202400266
M3 - Article
C2 - 38938183
VL - 25
JO - ChemPhysChem
JF - ChemPhysChem
SN - 1439-4235
IS - 21
M1 - e202400266
ER -
ID: 61104933