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Metal-organic frameworks based on octafluorobiphenyl-4,4′-dicarboxylate : Synthesis, crystal structure, and surface functionality. / Cheplakova, Anastasia M.; Kovalenko, Konstantin A.; Samsonenko, Denis G. et al.

In: Dalton Transactions, Vol. 47, No. 10, 06.03.2018, p. 3283-3297.

Research output: Contribution to journal › Article › peer-review

Harvard

Cheplakova, AM, Kovalenko, KA, Samsonenko, DG, Lazarenko, VA, Khrustalev, VN, Vinogradov, AS, Karpov, VM, Platonov, VE & Fedin, VP 2018, 'Metal-organic frameworks based on octafluorobiphenyl-4,4′-dicarboxylate: Synthesis, crystal structure, and surface functionality', Dalton Transactions, vol. 47, no. 10, pp. 3283-3297. https://doi.org/10.1039/c7dt04566b

APA

Cheplakova, A. M., Kovalenko, K. A., Samsonenko, D. G., Lazarenko, V. A., Khrustalev, V. N., Vinogradov, A. S., Karpov, V. M., Platonov, V. E., & Fedin, V. P. (2018). Metal-organic frameworks based on octafluorobiphenyl-4,4′-dicarboxylate: Synthesis, crystal structure, and surface functionality. Dalton Transactions, 47(10), 3283-3297. https://doi.org/10.1039/c7dt04566b

Vancouver

Cheplakova AM, Kovalenko KA, Samsonenko DG, Lazarenko VA, Khrustalev VN, Vinogradov AS et al. Metal-organic frameworks based on octafluorobiphenyl-4,4′-dicarboxylate: Synthesis, crystal structure, and surface functionality. Dalton Transactions. 2018 Mar 6;47(10):3283-3297. doi: 10.1039/c7dt04566b

Author

Cheplakova, Anastasia M. ; Kovalenko, Konstantin A. ; Samsonenko, Denis G. et al. / Metal-organic frameworks based on octafluorobiphenyl-4,4′-dicarboxylate : Synthesis, crystal structure, and surface functionality. In: Dalton Transactions. 2018 ; Vol. 47, No. 10. pp. 3283-3297.

BibTeX

@article{b8bcc03ebdbf49739dd3994c11f8d6bc,
title = "Metal-organic frameworks based on octafluorobiphenyl-4,4′-dicarboxylate: Synthesis, crystal structure, and surface functionality",
abstract = "In contrast to aromatic carboxylates, the coordination polymers based on their perfluorinated analogues are not numerous. Here we present a series of six Zn(ii) coordination polymers of different dimensionalities (1D, 2D, and 3D) and porosities based on octafluorobiphenyl-4,4′-dicarboxylate (oFBPDC2-) and N-containing co-ligands (ur, dabco, and bpy). These complexes are characterized by single-crystal X-ray diffraction, PXRD, FT-IR, elemental analysis, and TGA. The metal-organic frameworks [Zn2(CH3CONH2)2(oFBPDC)2] (1) and [Zn2(oFBPDC)2(dabco)] (4) are shown to be porous with BET surface areas of 470 m2 g-1 and 441 m2 g-1, respectively. In addition, compound 4 shows selectivity factors of 11.3, 4.9 and more than 6 for the binary gas mixtures CO2/N2, CO2/CH4 and benzene/cyclohexane, respectively. The measurements for pressed powders and water droplet give water contact angles of 136° for 4 and 133° for (H2bpy)[Zn2(bpy)(oFBPDC)3] (5). Low water uptake indicates that both 4 and 5 belong to highly hydrophobic solids.",
keywords = "TETRAFLUOROTEREPHTHALIC ACID, PHOTOLUMINESCENT COMPOUNDS, COORDINATION POLYMER, ADSORPTION, CO2, SORPTION, HYDROPHOBICITY, LUMINESCENCE, SEPARATIONS, STABILITY",
author = "Cheplakova, {Anastasia M.} and Kovalenko, {Konstantin A.} and Samsonenko, {Denis G.} and Lazarenko, {Vladimir A.} and Khrustalev, {Victor N.} and Vinogradov, {Andrey S.} and Karpov, {Victor M.} and Platonov, {Vyacheslav E.} and Fedin, {Vladimir P.}",
year = "2018",
month = mar,
day = "6",
doi = "10.1039/c7dt04566b",
language = "English",
volume = "47",
pages = "3283--3297",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "10",

}

RIS

TY - JOUR

T1 - Metal-organic frameworks based on octafluorobiphenyl-4,4′-dicarboxylate

T2 - Synthesis, crystal structure, and surface functionality

AU - Cheplakova, Anastasia M.

AU - Kovalenko, Konstantin A.

AU - Samsonenko, Denis G.

AU - Lazarenko, Vladimir A.

AU - Khrustalev, Victor N.

AU - Vinogradov, Andrey S.

AU - Karpov, Victor M.

AU - Platonov, Vyacheslav E.

AU - Fedin, Vladimir P.

PY - 2018/3/6

Y1 - 2018/3/6

N2 - In contrast to aromatic carboxylates, the coordination polymers based on their perfluorinated analogues are not numerous. Here we present a series of six Zn(ii) coordination polymers of different dimensionalities (1D, 2D, and 3D) and porosities based on octafluorobiphenyl-4,4′-dicarboxylate (oFBPDC2-) and N-containing co-ligands (ur, dabco, and bpy). These complexes are characterized by single-crystal X-ray diffraction, PXRD, FT-IR, elemental analysis, and TGA. The metal-organic frameworks [Zn2(CH3CONH2)2(oFBPDC)2] (1) and [Zn2(oFBPDC)2(dabco)] (4) are shown to be porous with BET surface areas of 470 m2 g-1 and 441 m2 g-1, respectively. In addition, compound 4 shows selectivity factors of 11.3, 4.9 and more than 6 for the binary gas mixtures CO2/N2, CO2/CH4 and benzene/cyclohexane, respectively. The measurements for pressed powders and water droplet give water contact angles of 136° for 4 and 133° for (H2bpy)[Zn2(bpy)(oFBPDC)3] (5). Low water uptake indicates that both 4 and 5 belong to highly hydrophobic solids.

AB - In contrast to aromatic carboxylates, the coordination polymers based on their perfluorinated analogues are not numerous. Here we present a series of six Zn(ii) coordination polymers of different dimensionalities (1D, 2D, and 3D) and porosities based on octafluorobiphenyl-4,4′-dicarboxylate (oFBPDC2-) and N-containing co-ligands (ur, dabco, and bpy). These complexes are characterized by single-crystal X-ray diffraction, PXRD, FT-IR, elemental analysis, and TGA. The metal-organic frameworks [Zn2(CH3CONH2)2(oFBPDC)2] (1) and [Zn2(oFBPDC)2(dabco)] (4) are shown to be porous with BET surface areas of 470 m2 g-1 and 441 m2 g-1, respectively. In addition, compound 4 shows selectivity factors of 11.3, 4.9 and more than 6 for the binary gas mixtures CO2/N2, CO2/CH4 and benzene/cyclohexane, respectively. The measurements for pressed powders and water droplet give water contact angles of 136° for 4 and 133° for (H2bpy)[Zn2(bpy)(oFBPDC)3] (5). Low water uptake indicates that both 4 and 5 belong to highly hydrophobic solids.

KW - TETRAFLUOROTEREPHTHALIC ACID

KW - PHOTOLUMINESCENT COMPOUNDS

KW - COORDINATION POLYMER

KW - ADSORPTION

KW - CO2

KW - SORPTION

KW - HYDROPHOBICITY

KW - LUMINESCENCE

KW - SEPARATIONS

KW - STABILITY

UR - http://www.scopus.com/inward/record.url?scp=85043323299&partnerID=8YFLogxK

U2 - 10.1039/c7dt04566b

DO - 10.1039/c7dt04566b

M3 - Article

C2 - 29363694

AN - SCOPUS:85043323299

VL - 47

SP - 3283

EP - 3297

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 10

ER -

ID: 10420585