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Metal-organic coordination polymers of lanthanides(III) with thienothiophendicarboxylate ligands. / Yudina, Yu A.; Samsonova, A. M.; Bolotov, V. A. et al.

In: Journal of Structural Chemistry, Vol. 62, No. 10, 10.2021, p. 1599-1606.

Research output: Contribution to journal › Article › peer-review

Harvard

Yudina, YA, Samsonova, AM, Bolotov, VA, Demakov, PA, Samsonenko, DG, Fedin, VP & Dybtsev, DN 2021, 'Metal-organic coordination polymers of lanthanides(III) with thienothiophendicarboxylate ligands', Journal of Structural Chemistry, vol. 62, no. 10, pp. 1599-1606. https://doi.org/10.1134/S0022476621100152

APA

Yudina, Y. A., Samsonova, A. M., Bolotov, V. A., Demakov, P. A., Samsonenko, D. G., Fedin, V. P., & Dybtsev, D. N. (2021). Metal-organic coordination polymers of lanthanides(III) with thienothiophendicarboxylate ligands. Journal of Structural Chemistry, 62(10), 1599-1606. https://doi.org/10.1134/S0022476621100152

Vancouver

Yudina YA, Samsonova AM, Bolotov VA, Demakov PA, Samsonenko DG, Fedin VP et al. Metal-organic coordination polymers of lanthanides(III) with thienothiophendicarboxylate ligands. Journal of Structural Chemistry. 2021 Oct;62(10):1599-1606. doi: 10.1134/S0022476621100152

Author

Yudina, Yu A. ; Samsonova, A. M. ; Bolotov, V. A. et al. / Metal-organic coordination polymers of lanthanides(III) with thienothiophendicarboxylate ligands. In: Journal of Structural Chemistry. 2021 ; Vol. 62, No. 10. pp. 1599-1606.

BibTeX

@article{bef4c866ede444c8b5e1deb4b2ae5bfd,
title = "Metal-organic coordination polymers of lanthanides(III) with thienothiophendicarboxylate ligands",
abstract = "Three novel metal-organic coordination polymers based on sulfur-containing thieno[3,2-b]thiophene-2,5-dicarboxylic (trans-H2ttdc) and thieno[2,3-b]thiophene-2,5-dicarboxylic (cis-H2ttdc) acids are obtained: [Ce2(DMF)4(trans-ttdc)3]·2DMF (1), [Dy2(DMF)4(trans-ttdc)3]·4DMF (2), and [Tb2(DMF)4(cis-ttdc)3]·2.5DMF (3). Structures of the products are determined by single crystal X-ray diffraction. The compositions and nature of compounds 2 and 3 are confirmed by IR spectroscopy, elemental and thermogravimetric analyses. All three compounds are based on binuclear {Ln2(DMF)4(RCOO)6} units organized into 3D frameworks with primitive cubic topology pcu by linear organic linkers. The specific void volume in the structures of 1-3 ranges from 29% to 37%.",
keywords = "carboxylates, lanthanides, metal-organic coordination polymers, sulfur-containing heterocycles, thiophene, X-ray crystallographic analysis",
author = "Yudina, {Yu A.} and Samsonova, {A. M.} and Bolotov, {V. A.} and Demakov, {P. A.} and Samsonenko, {D. G.} and Fedin, {V. P.} and Dybtsev, {D. N.}",
note = "Funding Information: The work was also supported by the Ministry of Science and Higher Education of the Russian Federation (project No. 121031700321-3). Funding Information: The work was supported by the Russian Science Foundation (project No. 18-13-00203). Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd.",
year = "2021",
month = oct,
doi = "10.1134/S0022476621100152",
language = "English",
volume = "62",
pages = "1599--1606",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "10",

}

RIS

TY - JOUR

T1 - Metal-organic coordination polymers of lanthanides(III) with thienothiophendicarboxylate ligands

AU - Yudina, Yu A.

AU - Samsonova, A. M.

AU - Bolotov, V. A.

AU - Demakov, P. A.

AU - Samsonenko, D. G.

AU - Fedin, V. P.

AU - Dybtsev, D. N.

N1 - Funding Information: The work was also supported by the Ministry of Science and Higher Education of the Russian Federation (project No. 121031700321-3). Funding Information: The work was supported by the Russian Science Foundation (project No. 18-13-00203). Publisher Copyright: © 2021, Pleiades Publishing, Ltd.

PY - 2021/10

Y1 - 2021/10

N2 - Three novel metal-organic coordination polymers based on sulfur-containing thieno[3,2-b]thiophene-2,5-dicarboxylic (trans-H2ttdc) and thieno[2,3-b]thiophene-2,5-dicarboxylic (cis-H2ttdc) acids are obtained: [Ce2(DMF)4(trans-ttdc)3]·2DMF (1), [Dy2(DMF)4(trans-ttdc)3]·4DMF (2), and [Tb2(DMF)4(cis-ttdc)3]·2.5DMF (3). Structures of the products are determined by single crystal X-ray diffraction. The compositions and nature of compounds 2 and 3 are confirmed by IR spectroscopy, elemental and thermogravimetric analyses. All three compounds are based on binuclear {Ln2(DMF)4(RCOO)6} units organized into 3D frameworks with primitive cubic topology pcu by linear organic linkers. The specific void volume in the structures of 1-3 ranges from 29% to 37%.

AB - Three novel metal-organic coordination polymers based on sulfur-containing thieno[3,2-b]thiophene-2,5-dicarboxylic (trans-H2ttdc) and thieno[2,3-b]thiophene-2,5-dicarboxylic (cis-H2ttdc) acids are obtained: [Ce2(DMF)4(trans-ttdc)3]·2DMF (1), [Dy2(DMF)4(trans-ttdc)3]·4DMF (2), and [Tb2(DMF)4(cis-ttdc)3]·2.5DMF (3). Structures of the products are determined by single crystal X-ray diffraction. The compositions and nature of compounds 2 and 3 are confirmed by IR spectroscopy, elemental and thermogravimetric analyses. All three compounds are based on binuclear {Ln2(DMF)4(RCOO)6} units organized into 3D frameworks with primitive cubic topology pcu by linear organic linkers. The specific void volume in the structures of 1-3 ranges from 29% to 37%.

KW - carboxylates

KW - lanthanides

KW - metal-organic coordination polymers

KW - sulfur-containing heterocycles

KW - thiophene

KW - X-ray crystallographic analysis

UR - http://www.scopus.com/inward/record.url?scp=85119130156&partnerID=8YFLogxK

U2 - 10.1134/S0022476621100152

DO - 10.1134/S0022476621100152

M3 - Article

AN - SCOPUS:85119130156

VL - 62

SP - 1599

EP - 1606

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 10

ER -

ID: 34679498