Research output: Contribution to journal › Article › peer-review
Metal-Organic Coordination Polymers Formed from γ-Cyclodextrin and Divalent Metal Ions. / Koshevoy, Evgeny I.; Samsonenko, Denis G.; Berezin, Alexey S. et al.
In: European Journal of Inorganic Chemistry, Vol. 2019, No. 39-40, 31.10.2019, p. 4321-4327.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Metal-Organic Coordination Polymers Formed from γ-Cyclodextrin and Divalent Metal Ions
AU - Koshevoy, Evgeny I.
AU - Samsonenko, Denis G.
AU - Berezin, Alexey S.
AU - Fedin, Vladimir P.
N1 - Publisher Copyright: © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
PY - 2019/10/31
Y1 - 2019/10/31
N2 - The chemistry of metal-organic frameworks based on cyclodextrins and alkali metals has been extensively investigated in recent years, but coordination polymers with non-alkali metals have been rarely reported. Here, we describe the synthesis and X-ray crystallographic characterization of a series of coordination polymers, [Ba(H2O)3(γ-CD)]Cl2·6H2O (γ-CD-Ba1), [Ba(H2O)(γ-CD)]Cl2·8H2O (γ-CD-Ba2), [Sr(H2O)(γ-CD)](NO3)2·9H2O (γ-CD-Sr), [Ca(γ-CD)2]Cl2·2CH3OH·16H2O (γ-CD-Ca), and [Pb(H2O)(γ-CD)](NO3)2·11H2O (γ-CD-Pb), which were obtained by reacting γ-cyclodextrin with alkaline earth metal ions and Pb2+. The coordination polymers formed from γ-cyclodextrin and Ca2+ and Ba2+ are obtained for the first time. The only compound in the studied series, γ-CD-Ba1, has a 3D structure. The other compounds have layered structures. In the structure of γ-CD-Ca, the coordination and number of γ-cyclodextrin molecules connected to the Ca2+ are different from those determined for a series of isostructural 2D coordination polymers, namely, γ-CD-Ba2, γ-CD-Sr and γ-CD-Pb. The metal-organic coordination polymer γ-CD-Pb exhibits photoluminescence in the near UV-region (λmax = 345 nm).
AB - The chemistry of metal-organic frameworks based on cyclodextrins and alkali metals has been extensively investigated in recent years, but coordination polymers with non-alkali metals have been rarely reported. Here, we describe the synthesis and X-ray crystallographic characterization of a series of coordination polymers, [Ba(H2O)3(γ-CD)]Cl2·6H2O (γ-CD-Ba1), [Ba(H2O)(γ-CD)]Cl2·8H2O (γ-CD-Ba2), [Sr(H2O)(γ-CD)](NO3)2·9H2O (γ-CD-Sr), [Ca(γ-CD)2]Cl2·2CH3OH·16H2O (γ-CD-Ca), and [Pb(H2O)(γ-CD)](NO3)2·11H2O (γ-CD-Pb), which were obtained by reacting γ-cyclodextrin with alkaline earth metal ions and Pb2+. The coordination polymers formed from γ-cyclodextrin and Ca2+ and Ba2+ are obtained for the first time. The only compound in the studied series, γ-CD-Ba1, has a 3D structure. The other compounds have layered structures. In the structure of γ-CD-Ca, the coordination and number of γ-cyclodextrin molecules connected to the Ca2+ are different from those determined for a series of isostructural 2D coordination polymers, namely, γ-CD-Ba2, γ-CD-Sr and γ-CD-Pb. The metal-organic coordination polymer γ-CD-Pb exhibits photoluminescence in the near UV-region (λmax = 345 nm).
KW - Alkaline earth metals
KW - Coordination polymers
KW - Cyclodextrins
KW - Metal-organic frameworks
KW - Structure elucidation
UR - http://www.scopus.com/inward/record.url?scp=85067573107&partnerID=8YFLogxK
U2 - 10.1002/ejic.201900398
DO - 10.1002/ejic.201900398
M3 - Article
AN - SCOPUS:85067573107
VL - 2019
SP - 4321
EP - 4327
JO - European Journal of Inorganic Chemistry
JF - European Journal of Inorganic Chemistry
SN - 1434-1948
IS - 39-40
ER -
ID: 20640038