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Mapping Magnetic Properties and Relaxation in Vanadium(IV) Complexes with Lanthanides by Electron Paramagnetic Resonance. / Kurganskii, Ivan V.; Bazhina, Evgeniya S.; Korlyukov, Alexander A. et al.

In: Molecules (Basel, Switzerland), Vol. 24, No. 24, 4582, 14.12.2019.

Research output: Contribution to journal › Article › peer-review

Harvard

Kurganskii, IV, Bazhina, ES, Korlyukov, AA, Babeshkin, KA, Efimov, NN, Kiskin, MA, Veber, SL, Sidorov, AA, Eremenko, IL & Fedin, MV 2019, 'Mapping Magnetic Properties and Relaxation in Vanadium(IV) Complexes with Lanthanides by Electron Paramagnetic Resonance', Molecules (Basel, Switzerland), vol. 24, no. 24, 4582. https://doi.org/10.3390/molecules24244582

APA

Kurganskii, I. V., Bazhina, E. S., Korlyukov, A. A., Babeshkin, K. A., Efimov, N. N., Kiskin, M. A., Veber, S. L., Sidorov, A. A., Eremenko, I. L., & Fedin, M. V. (2019). Mapping Magnetic Properties and Relaxation in Vanadium(IV) Complexes with Lanthanides by Electron Paramagnetic Resonance. Molecules (Basel, Switzerland), 24(24), [4582]. https://doi.org/10.3390/molecules24244582

Vancouver

Kurganskii IV, Bazhina ES, Korlyukov AA, Babeshkin KA, Efimov NN, Kiskin MA et al. Mapping Magnetic Properties and Relaxation in Vanadium(IV) Complexes with Lanthanides by Electron Paramagnetic Resonance. Molecules (Basel, Switzerland). 2019 Dec 14;24(24):4582. doi: 10.3390/molecules24244582

Author

Kurganskii, Ivan V. ; Bazhina, Evgeniya S. ; Korlyukov, Alexander A. et al. / Mapping Magnetic Properties and Relaxation in Vanadium(IV) Complexes with Lanthanides by Electron Paramagnetic Resonance. In: Molecules (Basel, Switzerland). 2019 ; Vol. 24, No. 24.

BibTeX

@article{3e65f984c6b74e42a0a101cd2ad10ea0,
title = "Mapping Magnetic Properties and Relaxation in Vanadium(IV) Complexes with Lanthanides by Electron Paramagnetic Resonance",
abstract = "Vanadium(IV) complexes are actively studied as potential candidates for molecular spin qubits operating at room temperatures. They have longer electron spin decoherence times than many other transition ions, being the key property for applications in quantum information processing. In most cases reported to date, the molecular complexes were optimized through the design for this purpose. In this work, we investigate the relaxation properties of vanadium(IV) ions incorporated in complexes with lanthanides using electron paramagnetic resonance (EPR). In all cases, the VO6 moieties with no nuclear spins in the first coordination sphere are addressed. We develop and implement the approaches for facile diagnostics of relaxation characteristics in individual VO6 moieties of such compounds. Remarkably, the estimated relaxation times are found to be close to those of other vanadium-based qubits obtained previously. In the future, a synergistic combination of qubit-friendly properties of vanadium ions with single-molecule magnetism and luminescence of lanthanides can be pursued to realize new functionalities of such materials.",
keywords = "EPR, relaxation times, vanadium(IV) ions, SPIN DYNAMICS, TIMES, SPECTRA, QUANTUM COHERENCE",
author = "Kurganskii, {Ivan V.} and Bazhina, {Evgeniya S.} and Korlyukov, {Alexander A.} and Babeshkin, {Konstantin A.} and Efimov, {Nikolay N.} and Kiskin, {Mikhail A.} and Veber, {Sergey L.} and Sidorov, {Alexey A.} and Eremenko, {Igor L.} and Fedin, {Matvey V.}",
year = "2019",
month = dec,
day = "14",
doi = "10.3390/molecules24244582",
language = "English",
volume = "24",
journal = "Molecules",
issn = "1420-3049",
publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",
number = "24",

}

RIS

TY - JOUR

T1 - Mapping Magnetic Properties and Relaxation in Vanadium(IV) Complexes with Lanthanides by Electron Paramagnetic Resonance

AU - Kurganskii, Ivan V.

AU - Bazhina, Evgeniya S.

AU - Korlyukov, Alexander A.

AU - Babeshkin, Konstantin A.

AU - Efimov, Nikolay N.

AU - Kiskin, Mikhail A.

AU - Veber, Sergey L.

AU - Sidorov, Alexey A.

AU - Eremenko, Igor L.

AU - Fedin, Matvey V.

PY - 2019/12/14

Y1 - 2019/12/14

N2 - Vanadium(IV) complexes are actively studied as potential candidates for molecular spin qubits operating at room temperatures. They have longer electron spin decoherence times than many other transition ions, being the key property for applications in quantum information processing. In most cases reported to date, the molecular complexes were optimized through the design for this purpose. In this work, we investigate the relaxation properties of vanadium(IV) ions incorporated in complexes with lanthanides using electron paramagnetic resonance (EPR). In all cases, the VO6 moieties with no nuclear spins in the first coordination sphere are addressed. We develop and implement the approaches for facile diagnostics of relaxation characteristics in individual VO6 moieties of such compounds. Remarkably, the estimated relaxation times are found to be close to those of other vanadium-based qubits obtained previously. In the future, a synergistic combination of qubit-friendly properties of vanadium ions with single-molecule magnetism and luminescence of lanthanides can be pursued to realize new functionalities of such materials.

AB - Vanadium(IV) complexes are actively studied as potential candidates for molecular spin qubits operating at room temperatures. They have longer electron spin decoherence times than many other transition ions, being the key property for applications in quantum information processing. In most cases reported to date, the molecular complexes were optimized through the design for this purpose. In this work, we investigate the relaxation properties of vanadium(IV) ions incorporated in complexes with lanthanides using electron paramagnetic resonance (EPR). In all cases, the VO6 moieties with no nuclear spins in the first coordination sphere are addressed. We develop and implement the approaches for facile diagnostics of relaxation characteristics in individual VO6 moieties of such compounds. Remarkably, the estimated relaxation times are found to be close to those of other vanadium-based qubits obtained previously. In the future, a synergistic combination of qubit-friendly properties of vanadium ions with single-molecule magnetism and luminescence of lanthanides can be pursued to realize new functionalities of such materials.

KW - EPR

KW - relaxation times

KW - vanadium(IV) ions

KW - SPIN DYNAMICS

KW - TIMES

KW - SPECTRA

KW - QUANTUM COHERENCE

UR - http://www.scopus.com/inward/record.url?scp=85076864257&partnerID=8YFLogxK

U2 - 10.3390/molecules24244582

DO - 10.3390/molecules24244582

M3 - Article

C2 - 31847326

AN - SCOPUS:85076864257

VL - 24

JO - Molecules

JF - Molecules

SN - 1420-3049

IS - 24

M1 - 4582

ER -

ID: 22849152