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Luminescent Metal-Organic Framework with 2,1,3-Benzothiadiazole Units for Highly Sensitive Gossypol Sensing. / Павлов, Дмитрий Игоревич; Юй, Сяолинь ; Рядун, Алексей Андреевич et al.

In: Chemosensors, Vol. 11, No. 1, 52, 2023.

Research output: Contribution to journal › Article › peer-review

Harvard

Павлов, ДИ, Юй, С, Рядун, АА, Федин, ВП & Потапов, АС 2023, 'Luminescent Metal-Organic Framework with 2,1,3-Benzothiadiazole Units for Highly Sensitive Gossypol Sensing', Chemosensors, vol. 11, no. 1, 52. https://doi.org/10.3390/chemosensors11010052

APA

Павлов, Д. И., Юй, С., Рядун, А. А., Федин, В. П., & Потапов, А. С. (2023). Luminescent Metal-Organic Framework with 2,1,3-Benzothiadiazole Units for Highly Sensitive Gossypol Sensing. Chemosensors, 11(1), [52]. https://doi.org/10.3390/chemosensors11010052

Vancouver

Павлов ДИ, Юй С, Рядун АА, Федин ВП, Потапов АС. Luminescent Metal-Organic Framework with 2,1,3-Benzothiadiazole Units for Highly Sensitive Gossypol Sensing. Chemosensors. 2023;11(1):52. doi: 10.3390/chemosensors11010052

Author

Павлов, Дмитрий Игоревич ; Юй, Сяолинь ; Рядун, Алексей Андреевич et al. / Luminescent Metal-Organic Framework with 2,1,3-Benzothiadiazole Units for Highly Sensitive Gossypol Sensing. In: Chemosensors. 2023 ; Vol. 11, No. 1.

BibTeX

@article{7ec21e5c13164e129c08749c29be7304,
title = "Luminescent Metal-Organic Framework with 2,1,3-Benzothiadiazole Units for Highly Sensitive Gossypol Sensing",
abstract = "A new metal–organic framework based on cadmium(II) cations, di(p-carboxyphenyl)sulphone and 4,7-di(imidazol-1-yl)-2,1,3-benzothiadiazole was prepared, and its crystal structure was determined using single-crystal XRD analysis. MOF demonstrated bright luminescence with a maximum near 500 nm and quantum yield reaching 20%. In addition, this MOF demonstrated sensing properties towards antibiotics and a toxic natural polyphenol gossypol through effective luminescence quenching in an ethanol suspension. The determined detection limit for gossypol was among the lowest reported so far (0.65 µM), and did not significantly change in the interference experiments with cottonseed oil as background, indicating the possibility of using this MOF as a sensor for the detection and determination of gossypol in real-life samples.",
author = "Павлов, {Дмитрий Игоревич} and Сяолинь Юй and Рядун, {Алексей Андреевич} and Федин, {Владимир Петрович} and Потапов, {Андрей Сергеевич}",
note = "This work was supported by the Ministry of Science and Higher Education of the Russian Federation (Agreement No. 075-15-2022-263). The experiments were performed using large-scale research facilities “EXAFS spectroscopy beamline”.",
year = "2023",
doi = "10.3390/chemosensors11010052",
language = "English",
volume = "11",
journal = "Chemosensors",
issn = "2227-9040",
publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",
number = "1",

}

RIS

TY - JOUR

T1 - Luminescent Metal-Organic Framework with 2,1,3-Benzothiadiazole Units for Highly Sensitive Gossypol Sensing

AU - Павлов, Дмитрий Игоревич

AU - Юй, Сяолинь

AU - Рядун, Алексей Андреевич

AU - Федин, Владимир Петрович

AU - Потапов, Андрей Сергеевич

N1 - This work was supported by the Ministry of Science and Higher Education of the Russian Federation (Agreement No. 075-15-2022-263). The experiments were performed using large-scale research facilities “EXAFS spectroscopy beamline”.

PY - 2023

Y1 - 2023

N2 - A new metal–organic framework based on cadmium(II) cations, di(p-carboxyphenyl)sulphone and 4,7-di(imidazol-1-yl)-2,1,3-benzothiadiazole was prepared, and its crystal structure was determined using single-crystal XRD analysis. MOF demonstrated bright luminescence with a maximum near 500 nm and quantum yield reaching 20%. In addition, this MOF demonstrated sensing properties towards antibiotics and a toxic natural polyphenol gossypol through effective luminescence quenching in an ethanol suspension. The determined detection limit for gossypol was among the lowest reported so far (0.65 µM), and did not significantly change in the interference experiments with cottonseed oil as background, indicating the possibility of using this MOF as a sensor for the detection and determination of gossypol in real-life samples.

AB - A new metal–organic framework based on cadmium(II) cations, di(p-carboxyphenyl)sulphone and 4,7-di(imidazol-1-yl)-2,1,3-benzothiadiazole was prepared, and its crystal structure was determined using single-crystal XRD analysis. MOF demonstrated bright luminescence with a maximum near 500 nm and quantum yield reaching 20%. In addition, this MOF demonstrated sensing properties towards antibiotics and a toxic natural polyphenol gossypol through effective luminescence quenching in an ethanol suspension. The determined detection limit for gossypol was among the lowest reported so far (0.65 µM), and did not significantly change in the interference experiments with cottonseed oil as background, indicating the possibility of using this MOF as a sensor for the detection and determination of gossypol in real-life samples.

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85146819203&origin=inward&txGid=7989b1014e79d55d354a6f988ecf6ce5

U2 - 10.3390/chemosensors11010052

DO - 10.3390/chemosensors11010052

M3 - Article

VL - 11

JO - Chemosensors

JF - Chemosensors

SN - 2227-9040

IS - 1

M1 - 52

ER -

ID: 56389823