Luminescence properties of rare-earth-doped fluoride borate crystals

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Luminescence properties of rare-earth-doped fluoride borate crystals. / Bekker, Tatyana B.; Ryadun, Alexey A.; Davydov, Alexey V. et al.

In: Journal of Alloys and Compounds, Vol. 900, 163343, 15.04.2022.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{aaf5efbde53645af8db7beba4ec887cf,

title = "Luminescence properties of rare-earth-doped fluoride borate crystals",

abstract = "Single crystals of undoped and Ce3+, Tb3+, and Eu3+/Tb3+/Ce3+ co-doped Ba12(BO3)6[BO3][LiF4] crystals were grown from high-temperature solutions. The Ba12(BO3)6[BO3][LiF4] compound crystallizes in the structural type of barium orthoborate Ba3(BO3)2 with porous Ba12(BO3)66+ cationic framework filled with disordered anionic groups. The PL and PLE spectra of undoped and rare-earth-doped crystals were studied. The photoluminescence temperature dependences in the range of 77–300 K were recorded. The shape and position of lines in the spectra are typical of cerium, terbium, and europium ions. Luminescence lifetime constants were measured in the range of 77–300 К. It was shown that at the excitation wavelength of 300 nm and 370 nm at 300 K, Ba12(BO3)6[BO3][LiF4]:Eu3+, Tb3+, Ce3+ crystals have luminescence close to daylight with CIE chromaticity coordinates and correlated color temperature of (0.335; 0.309), 5352 K and (0.295; 0.362), 7121 K, respectively. Our results indicate that rare-earth-doped Ba12(BO3)6[BO3][LiF4] crystals can be considered a candidate for the conversion of LED emission into white light.",

keywords = "Crystal growth, Inorganic materials, Luminescence, Optical spectroscopy, Rare earth alloys and compounds",

author = "Bekker, {Tatyana B.} and Ryadun, {Alexey A.} and Davydov, {Alexey V.} and Solntsev, {Vladimir P.} and Grigorieva, {Veronika D.}",

note = "Funding Information: We thank the three anonymous Reviewers for their valuable suggestions which improved the quality of the manuscript. The authors are thankful to V. Danilovskaya (IGM SB RAS) for the wavelength-dispersive spectroscopy measurements. This work was supported by the Russian Science Foundation, grant No. 21-19-00097. Publisher Copyright: {\textcopyright} 2021 Elsevier B.V.",

year = "2022",

month = apr,

day = "15",

doi = "10.1016/j.jallcom.2021.163343",

language = "English",

volume = "900",

journal = "Journal of Alloys and Compounds",

issn = "0925-8388",

publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Luminescence properties of rare-earth-doped fluoride borate crystals

AU - Bekker, Tatyana B.

AU - Ryadun, Alexey A.

AU - Davydov, Alexey V.

AU - Solntsev, Vladimir P.

AU - Grigorieva, Veronika D.

N1 - Funding Information: We thank the three anonymous Reviewers for their valuable suggestions which improved the quality of the manuscript. The authors are thankful to V. Danilovskaya (IGM SB RAS) for the wavelength-dispersive spectroscopy measurements. This work was supported by the Russian Science Foundation, grant No. 21-19-00097. Publisher Copyright: © 2021 Elsevier B.V.

PY - 2022/4/15

Y1 - 2022/4/15

N2 - Single crystals of undoped and Ce3+, Tb3+, and Eu3+/Tb3+/Ce3+ co-doped Ba12(BO3)6[BO3][LiF4] crystals were grown from high-temperature solutions. The Ba12(BO3)6[BO3][LiF4] compound crystallizes in the structural type of barium orthoborate Ba3(BO3)2 with porous Ba12(BO3)66+ cationic framework filled with disordered anionic groups. The PL and PLE spectra of undoped and rare-earth-doped crystals were studied. The photoluminescence temperature dependences in the range of 77–300 K were recorded. The shape and position of lines in the spectra are typical of cerium, terbium, and europium ions. Luminescence lifetime constants were measured in the range of 77–300 К. It was shown that at the excitation wavelength of 300 nm and 370 nm at 300 K, Ba12(BO3)6[BO3][LiF4]:Eu3+, Tb3+, Ce3+ crystals have luminescence close to daylight with CIE chromaticity coordinates and correlated color temperature of (0.335; 0.309), 5352 K and (0.295; 0.362), 7121 K, respectively. Our results indicate that rare-earth-doped Ba12(BO3)6[BO3][LiF4] crystals can be considered a candidate for the conversion of LED emission into white light.

AB - Single crystals of undoped and Ce3+, Tb3+, and Eu3+/Tb3+/Ce3+ co-doped Ba12(BO3)6[BO3][LiF4] crystals were grown from high-temperature solutions. The Ba12(BO3)6[BO3][LiF4] compound crystallizes in the structural type of barium orthoborate Ba3(BO3)2 with porous Ba12(BO3)66+ cationic framework filled with disordered anionic groups. The PL and PLE spectra of undoped and rare-earth-doped crystals were studied. The photoluminescence temperature dependences in the range of 77–300 K were recorded. The shape and position of lines in the spectra are typical of cerium, terbium, and europium ions. Luminescence lifetime constants were measured in the range of 77–300 К. It was shown that at the excitation wavelength of 300 nm and 370 nm at 300 K, Ba12(BO3)6[BO3][LiF4]:Eu3+, Tb3+, Ce3+ crystals have luminescence close to daylight with CIE chromaticity coordinates and correlated color temperature of (0.335; 0.309), 5352 K and (0.295; 0.362), 7121 K, respectively. Our results indicate that rare-earth-doped Ba12(BO3)6[BO3][LiF4] crystals can be considered a candidate for the conversion of LED emission into white light.

KW - Crystal growth

KW - Inorganic materials

KW - Luminescence

KW - Optical spectroscopy

KW - Rare earth alloys and compounds

UR - http://www.scopus.com/inward/record.url?scp=85121857193&partnerID=8YFLogxK

UR - https://www.elibrary.ru/item.asp?id=47549870

U2 - 10.1016/j.jallcom.2021.163343

DO - 10.1016/j.jallcom.2021.163343

M3 - Article

AN - SCOPUS:85121857193

VL - 900

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

SN - 0925-8388

M1 - 163343

ER -

ID: 35196272