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Kinetics of phase formation in the Ln–O–S (Ln=La, Gd, Y) systems during oxide sulfidation in ammonium thiocyanate vapor. / Bakovets, Vladimir V.; Sotnikov, Aleksandr V.; Korolkov, Ilya V.

In: Journal of the American Ceramic Society, Vol. 100, No. 4, 01.04.2017, p. 1320-1329.

Research output: Contribution to journal › Article › peer-review

Harvard

Bakovets, VV, Sotnikov, AV & Korolkov, IV 2017, 'Kinetics of phase formation in the Ln–O–S (Ln=La, Gd, Y) systems during oxide sulfidation in ammonium thiocyanate vapor', Journal of the American Ceramic Society, vol. 100, no. 4, pp. 1320-1329. https://doi.org/10.1111/jace.14692

APA

Bakovets, V. V., Sotnikov, A. V., & Korolkov, I. V. (2017). Kinetics of phase formation in the Ln–O–S (Ln=La, Gd, Y) systems during oxide sulfidation in ammonium thiocyanate vapor. Journal of the American Ceramic Society, 100(4), 1320-1329. https://doi.org/10.1111/jace.14692

Vancouver

Bakovets VV, Sotnikov AV, Korolkov IV. Kinetics of phase formation in the Ln–O–S (Ln=La, Gd, Y) systems during oxide sulfidation in ammonium thiocyanate vapor. Journal of the American Ceramic Society. 2017 Apr 1;100(4):1320-1329. doi: 10.1111/jace.14692

Author

Bakovets, Vladimir V. ; Sotnikov, Aleksandr V. ; Korolkov, Ilya V. / Kinetics of phase formation in the Ln–O–S (Ln=La, Gd, Y) systems during oxide sulfidation in ammonium thiocyanate vapor. In: Journal of the American Ceramic Society. 2017 ; Vol. 100, No. 4. pp. 1320-1329.

BibTeX

@article{f8b1c0adf73749a0abb5a02c4d6ebe7a,
title = "Kinetics of phase formation in the Ln–O–S (Ln=La, Gd, Y) systems during oxide sulfidation in ammonium thiocyanate vapor",
abstract = "Kinetics and mechanism of phase formation in the Ln–O–S (Ln=La, Gd, Y) systems during Ln2O3 sulfidation in ammonium thiocyanate vapor and the identified sequence of transformations of obtained phases in the temperature range 873-1273 K have been studied. The kinetic dependencies for the reactions involved were fitted by the Jander equation for topochemical heterogeneous reactions with a squared correlation coefficient R2=.99. The reaction rate constants, pre-exponential factors, and effective activation energies for the reaction formation of compounds have been calculated, and approximate times and low temperatures for the formation of particular phases have been found.",
keywords = "kinetics, rare earths, sulfides",
author = "Bakovets, {Vladimir V.} and Sotnikov, {Aleksandr V.} and Korolkov, {Ilya V.}",
year = "2017",
month = apr,
day = "1",
doi = "10.1111/jace.14692",
language = "English",
volume = "100",
pages = "1320--1329",
journal = "Journal of the American Ceramic Society",
issn = "0002-7820",
publisher = "Wiley-Blackwell",
number = "4",

}

RIS

TY - JOUR

T1 - Kinetics of phase formation in the Ln–O–S (Ln=La, Gd, Y) systems during oxide sulfidation in ammonium thiocyanate vapor

AU - Bakovets, Vladimir V.

AU - Sotnikov, Aleksandr V.

AU - Korolkov, Ilya V.

PY - 2017/4/1

Y1 - 2017/4/1

N2 - Kinetics and mechanism of phase formation in the Ln–O–S (Ln=La, Gd, Y) systems during Ln2O3 sulfidation in ammonium thiocyanate vapor and the identified sequence of transformations of obtained phases in the temperature range 873-1273 K have been studied. The kinetic dependencies for the reactions involved were fitted by the Jander equation for topochemical heterogeneous reactions with a squared correlation coefficient R2=.99. The reaction rate constants, pre-exponential factors, and effective activation energies for the reaction formation of compounds have been calculated, and approximate times and low temperatures for the formation of particular phases have been found.

AB - Kinetics and mechanism of phase formation in the Ln–O–S (Ln=La, Gd, Y) systems during Ln2O3 sulfidation in ammonium thiocyanate vapor and the identified sequence of transformations of obtained phases in the temperature range 873-1273 K have been studied. The kinetic dependencies for the reactions involved were fitted by the Jander equation for topochemical heterogeneous reactions with a squared correlation coefficient R2=.99. The reaction rate constants, pre-exponential factors, and effective activation energies for the reaction formation of compounds have been calculated, and approximate times and low temperatures for the formation of particular phases have been found.

KW - kinetics

KW - rare earths

KW - sulfides

UR - http://www.scopus.com/inward/record.url?scp=85010822257&partnerID=8YFLogxK

U2 - 10.1111/jace.14692

DO - 10.1111/jace.14692

M3 - Article

AN - SCOPUS:85010822257

VL - 100

SP - 1320

EP - 1329

JO - Journal of the American Ceramic Society

JF - Journal of the American Ceramic Society

SN - 0002-7820

IS - 4

ER -

ID: 10040575