Research output: Contribution to journal › Article › peer-review
Isolation of homoleptic platinum oxyanionic complexes with doubly protonated diazacrown cation. / Vasilchenko, Danila; Tkachev, Sergey; Baidina, Iraida et al.
In: Journal of Molecular Structure, Vol. 1130, 15.02.2017, p. 855-859.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Isolation of homoleptic platinum oxyanionic complexes with doubly protonated diazacrown cation
AU - Vasilchenko, Danila
AU - Tkachev, Sergey
AU - Baidina, Iraida
AU - Romanenko, Galina
AU - Korenev, Sergey
N1 - Funding Information: This work was supported by the Russian Foundation for Basic Research grant 16-03-00549 A and 14-03-00411 A . D.V. thanks the Ministry for Education and Science of the Russian Federation for the award of a fellowship of the President of the Russian Federation for young scientists. Publisher Copyright: © 2016 Elsevier B.V.
PY - 2017/2/15
Y1 - 2017/2/15
N2 - Doubly protonated diazacrown ether cation (1,4,10,13-tetraoxa-7,16-diazoniacyclooctadecane DCH2 2+) was used for the efficient isolation of the homoleptic platinum complexes [Pt(NO3)6]2- and [Pt(C2O4)2]2- to crystalline solid phases from solutions containing mixtures of related platinum complexes. DCH2 2+ molecules in nitric acid solution were shown to prevent the condensation of mononuclear [Pt(H2O)n(NO3)6-n]n−2 species.
AB - Doubly protonated diazacrown ether cation (1,4,10,13-tetraoxa-7,16-diazoniacyclooctadecane DCH2 2+) was used for the efficient isolation of the homoleptic platinum complexes [Pt(NO3)6]2- and [Pt(C2O4)2]2- to crystalline solid phases from solutions containing mixtures of related platinum complexes. DCH2 2+ molecules in nitric acid solution were shown to prevent the condensation of mononuclear [Pt(H2O)n(NO3)6-n]n−2 species.
KW - Crystal structure
KW - Diazacrown
KW - NMR
KW - O-ligands
KW - Platinum
KW - OXALATO
KW - CRYSTAL
KW - PRECURSORS
UR - http://www.scopus.com/inward/record.url?scp=85002948559&partnerID=8YFLogxK
U2 - 10.1016/j.molstruc.2016.10.088
DO - 10.1016/j.molstruc.2016.10.088
M3 - Article
AN - SCOPUS:85002948559
VL - 1130
SP - 855
EP - 859
JO - Journal of Molecular Structure
JF - Journal of Molecular Structure
SN - 0022-2860
ER -
ID: 10318657