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Influence of synthetic conditions on the formation of thermally and hydrolytically stable Sc-based metal–organic frameworks. / Barsukova, Marina O.; Samsonenko, Denis G.; Sapianik, Aleksandr A. et al.

In: Polyhedron, Vol. 144, 01.04.2018, p. 219-224.

Research output: Contribution to journal › Article › peer-review

Harvard

Barsukova, MO, Samsonenko, DG, Sapianik, AA, Sapchenko, SA & Fedin, VP 2018, 'Influence of synthetic conditions on the formation of thermally and hydrolytically stable Sc-based metal–organic frameworks', Polyhedron, vol. 144, pp. 219-224. https://doi.org/10.1016/j.poly.2018.01.031

APA

Barsukova, M. O., Samsonenko, D. G., Sapianik, A. A., Sapchenko, S. A., & Fedin, V. P. (2018). Influence of synthetic conditions on the formation of thermally and hydrolytically stable Sc-based metal–organic frameworks. Polyhedron, 144, 219-224. https://doi.org/10.1016/j.poly.2018.01.031

Vancouver

Barsukova MO, Samsonenko DG, Sapianik AA, Sapchenko SA, Fedin VP. Influence of synthetic conditions on the formation of thermally and hydrolytically stable Sc-based metal–organic frameworks. Polyhedron. 2018 Apr 1;144:219-224. doi: 10.1016/j.poly.2018.01.031

Author

Barsukova, Marina O. ; Samsonenko, Denis G. ; Sapianik, Aleksandr A. et al. / Influence of synthetic conditions on the formation of thermally and hydrolytically stable Sc-based metal–organic frameworks. In: Polyhedron. 2018 ; Vol. 144. pp. 219-224.

BibTeX

@article{928848616b4847f6b53aea369e0a8f0f,
title = "Influence of synthetic conditions on the formation of thermally and hydrolytically stable Sc-based metal–organic frameworks",
abstract = "Three new coordination polymers ((CH3)2NH2)[Sc(H2O)2(fdc)2]·1,5CH3CN (1), ((CH3)2NH2)2[Sc(fdc)2(HCOO)] (2), [Sc2(H2O)2(fdc)3] (3) based on scandium cations and 2,5-furandicarboxylate ligand (fdc2−) have been synthesized and characterized by single crystal and powder X-ray diffraction crystallography, TG, elemental analyses and IR-spectroscopy. Compound 1 is formed from layers bind by hydrogen bonds. Calculated accessible for solvent volume is 41%. Compound 2 is a structure of negatively charged layers connected with interlayer dimethylammonium cations. Layered compound 3 appeared to be thermally stable (up to 300 °C) and retain its structure in wide range of pH from 1 to 13. Additionally, the solid-state luminescence properties of compounds 2 and 3 we investigated.",
keywords = "2,5-furandicarboxylic acid, Coordination polymers, Luminescence, Metal–organic framework, Scandium complexes, CATALYSIS, ADSORPTION PROPERTIES, HYDROGEN STORAGE, CH4, CO2 CAPTURE, MIL-100(SC), C-C, Metal-organic framework, ACIDITY",
author = "Barsukova, {Marina O.} and Samsonenko, {Denis G.} and Sapianik, {Aleksandr A.} and Sapchenko, {Sergey A.} and Fedin, {Vladimir P.}",
note = "Funding Information: The reported study was funded by RFBR and Government of the Novosibirsk region according to the research project № 17-43-543116. Publisher Copyright: {\textcopyright} 2018 Elsevier Ltd",
year = "2018",
month = apr,
day = "1",
doi = "10.1016/j.poly.2018.01.031",
language = "English",
volume = "144",
pages = "219--224",
journal = "Polyhedron",
issn = "0277-5387",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Influence of synthetic conditions on the formation of thermally and hydrolytically stable Sc-based metal–organic frameworks

AU - Barsukova, Marina O.

AU - Samsonenko, Denis G.

AU - Sapianik, Aleksandr A.

AU - Sapchenko, Sergey A.

AU - Fedin, Vladimir P.

N1 - Funding Information: The reported study was funded by RFBR and Government of the Novosibirsk region according to the research project № 17-43-543116. Publisher Copyright: © 2018 Elsevier Ltd

PY - 2018/4/1

Y1 - 2018/4/1

N2 - Three new coordination polymers ((CH3)2NH2)[Sc(H2O)2(fdc)2]·1,5CH3CN (1), ((CH3)2NH2)2[Sc(fdc)2(HCOO)] (2), [Sc2(H2O)2(fdc)3] (3) based on scandium cations and 2,5-furandicarboxylate ligand (fdc2−) have been synthesized and characterized by single crystal and powder X-ray diffraction crystallography, TG, elemental analyses and IR-spectroscopy. Compound 1 is formed from layers bind by hydrogen bonds. Calculated accessible for solvent volume is 41%. Compound 2 is a structure of negatively charged layers connected with interlayer dimethylammonium cations. Layered compound 3 appeared to be thermally stable (up to 300 °C) and retain its structure in wide range of pH from 1 to 13. Additionally, the solid-state luminescence properties of compounds 2 and 3 we investigated.

AB - Three new coordination polymers ((CH3)2NH2)[Sc(H2O)2(fdc)2]·1,5CH3CN (1), ((CH3)2NH2)2[Sc(fdc)2(HCOO)] (2), [Sc2(H2O)2(fdc)3] (3) based on scandium cations and 2,5-furandicarboxylate ligand (fdc2−) have been synthesized and characterized by single crystal and powder X-ray diffraction crystallography, TG, elemental analyses and IR-spectroscopy. Compound 1 is formed from layers bind by hydrogen bonds. Calculated accessible for solvent volume is 41%. Compound 2 is a structure of negatively charged layers connected with interlayer dimethylammonium cations. Layered compound 3 appeared to be thermally stable (up to 300 °C) and retain its structure in wide range of pH from 1 to 13. Additionally, the solid-state luminescence properties of compounds 2 and 3 we investigated.

KW - 2,5-furandicarboxylic acid

KW - Coordination polymers

KW - Luminescence

KW - Metal–organic framework

KW - Scandium complexes

KW - CATALYSIS

KW - ADSORPTION PROPERTIES

KW - HYDROGEN STORAGE

KW - CH4

KW - CO2 CAPTURE

KW - MIL-100(SC)

KW - C-C

KW - Metal-organic framework

KW - ACIDITY

UR - http://www.scopus.com/inward/record.url?scp=85042312639&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2018.01.031

DO - 10.1016/j.poly.2018.01.031

M3 - Article

AN - SCOPUS:85042312639

VL - 144

SP - 219

EP - 224

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

ER -

ID: 10428245