Standard

Immobilization of Platinum(II) and Platinum(IV) Complexes on Oxidized Nanoporous Carbon Material and Evaluation of the Enthalpy of Adsorption. / Levchenko, M.; Matskevich, N. I.; Kerzhentseva, V. E. et al.

In: Russian Journal of Inorganic Chemistry, Vol. 63, No. 7, 01.07.2018, p. 923-929.

Research output: Contribution to journal › Article › peer-review

Harvard

Levchenko, M, Matskevich, NI, Kerzhentseva, VE, Pishchur, DP, Mikheev, AN, Gel’fond, NV & Korol’kov, IV 2018, 'Immobilization of Platinum(II) and Platinum(IV) Complexes on Oxidized Nanoporous Carbon Material and Evaluation of the Enthalpy of Adsorption', Russian Journal of Inorganic Chemistry, vol. 63, no. 7, pp. 923-929. https://doi.org/10.1134/S0036023618070136

APA

Levchenko, M., Matskevich, N. I., Kerzhentseva, V. E., Pishchur, D. P., Mikheev, A. N., Gel’fond, N. V., & Korol’kov, I. V. (2018). Immobilization of Platinum(II) and Platinum(IV) Complexes on Oxidized Nanoporous Carbon Material and Evaluation of the Enthalpy of Adsorption. Russian Journal of Inorganic Chemistry, 63(7), 923-929. https://doi.org/10.1134/S0036023618070136

Vancouver

Levchenko M, Matskevich NI, Kerzhentseva VE, Pishchur DP, Mikheev AN, Gel’fond NV et al. Immobilization of Platinum(II) and Platinum(IV) Complexes on Oxidized Nanoporous Carbon Material and Evaluation of the Enthalpy of Adsorption. Russian Journal of Inorganic Chemistry. 2018 Jul 1;63(7):923-929. doi: 10.1134/S0036023618070136

Author

Levchenko, M. ; Matskevich, N. I. ; Kerzhentseva, V. E. et al. / Immobilization of Platinum(II) and Platinum(IV) Complexes on Oxidized Nanoporous Carbon Material and Evaluation of the Enthalpy of Adsorption. In: Russian Journal of Inorganic Chemistry. 2018 ; Vol. 63, No. 7. pp. 923-929.

BibTeX

@article{90f1cf24b4184e13ac4f86ace859fcc2,
title = "Immobilization of Platinum(II) and Platinum(IV) Complexes on Oxidized Nanoporous Carbon Material and Evaluation of the Enthalpy of Adsorption",
abstract = "Physicochemical study of cis-[Pt(NH3)2Cl2] and cis-[Pt(NH3)2Cl2(OH)2] is carried out, and immobilization of platinum complexes on the nanoporous carbon substrate is investigated. The solubility of cis-[Pt(NH3)2Cl2] in 1 M HCl solution is determined, and the average enthalpy of dissolution is calculated: ΔsolH° = 27.3 ± 0.9 kJ/mol. The batch capacity is determined experimentally for cis-[Pt(NH3)2Cl2] and cis- [Pt(NH3)2Cl2(OH)2] to be 32.9 mg/g (0.17 mg-equiv/g) and 47.6 mg/g (0.24 mg-equiv/g), respectively. Immobilization of platinum complexes on the oxidized carbon surface is found to take place due to interaction between carboxy groups and ammine groups of platinum complexes. The resulting heat capacity curves are used to calculate the enthalpies of adsorption for cis-[Pt(NH3)2Cl2] and cis-[Pt(NH3)2Cl2(OH)2] on the oxidized carbon surface, equal to 24.46 and 27.46 kJ/mol, respectively.",
author = "M. Levchenko and Matskevich, {N. I.} and Kerzhentseva, {V. E.} and Pishchur, {D. P.} and Mikheev, {A. N.} and Gel{\textquoteright}fond, {N. V.} and Korol{\textquoteright}kov, {I. V.}",
year = "2018",
month = jul,
day = "1",
doi = "10.1134/S0036023618070136",
language = "English",
volume = "63",
pages = "923--929",
journal = "Russian Journal of Inorganic Chemistry",
issn = "0036-0236",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "7",

}

RIS

TY - JOUR

T1 - Immobilization of Platinum(II) and Platinum(IV) Complexes on Oxidized Nanoporous Carbon Material and Evaluation of the Enthalpy of Adsorption

AU - Levchenko, M.

AU - Matskevich, N. I.

AU - Kerzhentseva, V. E.

AU - Pishchur, D. P.

AU - Mikheev, A. N.

AU - Gel’fond, N. V.

AU - Korol’kov, I. V.

PY - 2018/7/1

Y1 - 2018/7/1

N2 - Physicochemical study of cis-[Pt(NH3)2Cl2] and cis-[Pt(NH3)2Cl2(OH)2] is carried out, and immobilization of platinum complexes on the nanoporous carbon substrate is investigated. The solubility of cis-[Pt(NH3)2Cl2] in 1 M HCl solution is determined, and the average enthalpy of dissolution is calculated: ΔsolH° = 27.3 ± 0.9 kJ/mol. The batch capacity is determined experimentally for cis-[Pt(NH3)2Cl2] and cis- [Pt(NH3)2Cl2(OH)2] to be 32.9 mg/g (0.17 mg-equiv/g) and 47.6 mg/g (0.24 mg-equiv/g), respectively. Immobilization of platinum complexes on the oxidized carbon surface is found to take place due to interaction between carboxy groups and ammine groups of platinum complexes. The resulting heat capacity curves are used to calculate the enthalpies of adsorption for cis-[Pt(NH3)2Cl2] and cis-[Pt(NH3)2Cl2(OH)2] on the oxidized carbon surface, equal to 24.46 and 27.46 kJ/mol, respectively.

AB - Physicochemical study of cis-[Pt(NH3)2Cl2] and cis-[Pt(NH3)2Cl2(OH)2] is carried out, and immobilization of platinum complexes on the nanoporous carbon substrate is investigated. The solubility of cis-[Pt(NH3)2Cl2] in 1 M HCl solution is determined, and the average enthalpy of dissolution is calculated: ΔsolH° = 27.3 ± 0.9 kJ/mol. The batch capacity is determined experimentally for cis-[Pt(NH3)2Cl2] and cis- [Pt(NH3)2Cl2(OH)2] to be 32.9 mg/g (0.17 mg-equiv/g) and 47.6 mg/g (0.24 mg-equiv/g), respectively. Immobilization of platinum complexes on the oxidized carbon surface is found to take place due to interaction between carboxy groups and ammine groups of platinum complexes. The resulting heat capacity curves are used to calculate the enthalpies of adsorption for cis-[Pt(NH3)2Cl2] and cis-[Pt(NH3)2Cl2(OH)2] on the oxidized carbon surface, equal to 24.46 and 27.46 kJ/mol, respectively.

UR - http://www.scopus.com/inward/record.url?scp=85051127738&partnerID=8YFLogxK

U2 - 10.1134/S0036023618070136

DO - 10.1134/S0036023618070136

M3 - Article

AN - SCOPUS:85051127738

VL - 63

SP - 923

EP - 929

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

SN - 0036-0236

IS - 7

ER -

ID: 16075725