Imidazoline and imidazolidine nitroxides as controlling agents in nitroxide-mediated pseudoliving radical polymerization

Standard

Imidazoline and imidazolidine nitroxides as controlling agents in nitroxide-mediated pseudoliving radical polymerization. / Edeleva, Mariya V.; Marque, Sylvain R.A.; Bagryanskaya, Elena G.

In: Russian Chemical Reviews, Vol. 87, No. 4, 01.01.2018, p. 328-349.

Research output: Contribution to journal › Article › peer-review

Author

Edeleva, Mariya V. ; Marque, Sylvain R.A. ; Bagryanskaya, Elena G. / Imidazoline and imidazolidine nitroxides as controlling agents in nitroxide-mediated pseudoliving radical polymerization. In: Russian Chemical Reviews. 2018 ; Vol. 87, No. 4. pp. 328-349.

BibTeX

@article{e95327e9cafd4dda949667c3a9651a11,

title = "Imidazoline and imidazolidine nitroxides as controlling agents in nitroxide-mediated pseudoliving radical polymerization",

abstract = "Controlled, or pseudoliving, radical polymerization provides unique opportunities for the synthesis of structurally diverse polymers with a narrow molecular-weight distribution. These reactions occur under relatively mild conditions with broad tolerance to functional groups in the monomers. The nitroxide-mediated pseudoliving radical polymerization is of particular interest for the synthesis of polymers for biomedical applications. This review briefly describes one of the mechanisms of controlled radical polymerization. The studies dealing with the use of imidazoline and imidazolidine nitroxides as controlling agents for nitroxide-mediated pseudoliving radical polymerization of various monomers are summarized and analyzed. The publications addressing the key steps of the controlled radical polymerization in the presence of imidazoline and imidazolidine nitroxides and new approaches to nitroxide-mediated polymerization based on protonation of both nitroxides and monomers are considered.",

keywords = "C-ON BOND, CARBON-CENTERED RADICALS, FRAGMENTATION CHAIN-TRANSFER, HYDROGEN-TRANSFER REACTION, METHYL-METHACRYLATE, RATE CONSTANTS, ATOM-TRANSFER, INITIATING ALKOXYAMINE, MODEL ALKOXYAMINES, RATE COEFFICIENTS",

author = "Edeleva, {Mariya V.} and Marque, {Sylvain R.A.} and Bagryanskaya, {Elena G.}",

note = "Publisher Copyright: {\textcopyright} 2018 Uspekhi Khimii, Russian Academy of Sciences and Turpion Ltd.",

year = "2018",

month = jan,

day = "1",

doi = "10.1070/RCR4765",

language = "English",

volume = "87",

pages = "328--349",

journal = "Russian Chemical Reviews",

issn = "0036-021X",

publisher = "Turpion Ltd.",

number = "4",

}

RIS

TY - JOUR

T1 - Imidazoline and imidazolidine nitroxides as controlling agents in nitroxide-mediated pseudoliving radical polymerization

AU - Edeleva, Mariya V.

AU - Marque, Sylvain R.A.

AU - Bagryanskaya, Elena G.

PY - 2018/1/1

Y1 - 2018/1/1

N2 - Controlled, or pseudoliving, radical polymerization provides unique opportunities for the synthesis of structurally diverse polymers with a narrow molecular-weight distribution. These reactions occur under relatively mild conditions with broad tolerance to functional groups in the monomers. The nitroxide-mediated pseudoliving radical polymerization is of particular interest for the synthesis of polymers for biomedical applications. This review briefly describes one of the mechanisms of controlled radical polymerization. The studies dealing with the use of imidazoline and imidazolidine nitroxides as controlling agents for nitroxide-mediated pseudoliving radical polymerization of various monomers are summarized and analyzed. The publications addressing the key steps of the controlled radical polymerization in the presence of imidazoline and imidazolidine nitroxides and new approaches to nitroxide-mediated polymerization based on protonation of both nitroxides and monomers are considered.

AB - Controlled, or pseudoliving, radical polymerization provides unique opportunities for the synthesis of structurally diverse polymers with a narrow molecular-weight distribution. These reactions occur under relatively mild conditions with broad tolerance to functional groups in the monomers. The nitroxide-mediated pseudoliving radical polymerization is of particular interest for the synthesis of polymers for biomedical applications. This review briefly describes one of the mechanisms of controlled radical polymerization. The studies dealing with the use of imidazoline and imidazolidine nitroxides as controlling agents for nitroxide-mediated pseudoliving radical polymerization of various monomers are summarized and analyzed. The publications addressing the key steps of the controlled radical polymerization in the presence of imidazoline and imidazolidine nitroxides and new approaches to nitroxide-mediated polymerization based on protonation of both nitroxides and monomers are considered.

KW - C-ON BOND

KW - CARBON-CENTERED RADICALS

KW - FRAGMENTATION CHAIN-TRANSFER

KW - HYDROGEN-TRANSFER REACTION

KW - METHYL-METHACRYLATE

KW - RATE CONSTANTS

KW - ATOM-TRANSFER

KW - INITIATING ALKOXYAMINE

KW - MODEL ALKOXYAMINES

KW - RATE COEFFICIENTS

UR - http://www.scopus.com/inward/record.url?scp=85046547464&partnerID=8YFLogxK

U2 - 10.1070/RCR4765

DO - 10.1070/RCR4765

M3 - Article

AN - SCOPUS:85046547464

VL - 87

SP - 328

EP - 349

JO - Russian Chemical Reviews

JF - Russian Chemical Reviews

SN - 0036-021X

IS - 4

ER -

ID: 13120505