TY - JOUR

T1 - Identification of conjugate electron transitions in X-ray photoelectron spectra

AU - Cholach, A. R.

AU - Asanov, I. P.

AU - Bryliakova, A. A.

PY - 2017/11/1

Y1 - 2017/11/1

N2 - The regularities of the electron energy dissipation found in the subsurface atomic layer are valid in the bulk of a solid, too. On the example of model graphite-based materials it is shown that energy losses in X-ray photoelectron spectra agree with the calculated valence electron excitation spectra in analogous unit cells. The control of conjugate electron transitions opens the way to gain new data on the geometry, character, and order of bonding between atoms in the sample by the conventional electron spectroscopy and quantum chemistry methods.

AB - The regularities of the electron energy dissipation found in the subsurface atomic layer are valid in the bulk of a solid, too. On the example of model graphite-based materials it is shown that energy losses in X-ray photoelectron spectra agree with the calculated valence electron excitation spectra in analogous unit cells. The control of conjugate electron transitions opens the way to gain new data on the geometry, character, and order of bonding between atoms in the sample by the conventional electron spectroscopy and quantum chemistry methods.

KW - conjugate electron transitions

KW - density of states

KW - electron spectroscopy

KW - inelastic electron scattering

UR - http://www.scopus.com/inward/record.url?scp=85036507579&partnerID=8YFLogxK

U2 - 10.1134/S0022476617060130

DO - 10.1134/S0022476617060130

M3 - Article

AN - SCOPUS:85036507579

VL - 58

SP - 1160

EP - 1165

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 6

ER -