Standard

Hyphenated techniques in speciation analysis of polyoxometalates : identification of individual [PMo12−xVxO40]−3−x (x = 1-3) in the reaction mixtures by high performance liquid chromatography and atomic emission spectrometry with inductively coupled plasma. / Shuvaeva, O. V.; Zhdanov, A. A.; Romanova, T. E. et al.

In: Dalton Transactions, Vol. 46, No. 11, 14.03.2017, p. 3541-3546.

Research output: Contribution to journal › Article › peer-review

Harvard

Shuvaeva, OV, Zhdanov, AA, Romanova, TE, Abramov, PA & Sokolov, MN 2017, 'Hyphenated techniques in speciation analysis of polyoxometalates: identification of individual [PMo12−xVxO40]−3−x (x = 1-3) in the reaction mixtures by high performance liquid chromatography and atomic emission spectrometry with inductively coupled plasma', Dalton Transactions, vol. 46, no. 11, pp. 3541-3546. https://doi.org/10.1039/c6dt04843a

APA

Shuvaeva, O. V., Zhdanov, A. A., Romanova, T. E., Abramov, P. A., & Sokolov, M. N. (2017). Hyphenated techniques in speciation analysis of polyoxometalates: identification of individual [PMo12−xVxO40]−3−x (x = 1-3) in the reaction mixtures by high performance liquid chromatography and atomic emission spectrometry with inductively coupled plasma. Dalton Transactions, 46(11), 3541-3546. https://doi.org/10.1039/c6dt04843a

Vancouver

Shuvaeva OV, Zhdanov AA, Romanova TE, Abramov PA, Sokolov MN. Hyphenated techniques in speciation analysis of polyoxometalates: identification of individual [PMo12−xVxO40]−3−x (x = 1-3) in the reaction mixtures by high performance liquid chromatography and atomic emission spectrometry with inductively coupled plasma. Dalton Transactions. 2017 Mar 14;46(11):3541-3546. doi: 10.1039/c6dt04843a

Author

Shuvaeva, O. V. ; Zhdanov, A. A. ; Romanova, T. E. et al. / Hyphenated techniques in speciation analysis of polyoxometalates : identification of individual [PMo12−xVxO40]−3−x (x = 1-3) in the reaction mixtures by high performance liquid chromatography and atomic emission spectrometry with inductively coupled plasma. In: Dalton Transactions. 2017 ; Vol. 46, No. 11. pp. 3541-3546.

BibTeX

@article{70963cbe2dab4bdd887728a8fdf2a459,
title = "Hyphenated techniques in speciation analysis of polyoxometalates: identification of individual [PMo12−xVxO40]−3−x (x = 1-3) in the reaction mixtures by high performance liquid chromatography and atomic emission spectrometry with inductively coupled plasma",
abstract = "Unambiguous identification of polyoxometalate (POM) species generated in self-assembly reactions in solution is rather problematic due to close similarity of their properties such as solubility and spectral characteristics. The situation is made more complex by protonation equilibria (which can change their analytical signals) and the lack of individual compounds to serve as standards for individual members of these mixtures. In the present work a new approach to the study of such POMs has been suggested, taking molybdovanadates [PMo12−xVxO40]−3−x as a model. The key feature of this approach consists of generation of so-called “conditional model systems” that include most of the expected components of a mixture formed by self-assembly, tracked down by reliable detection techniques, e.g., 51V NMR-spectroscopy in this particular case. Then the proposed composition of the mixture is verified and corrected by means of high-performance liquid chromatography coupled with inductively coupled plasma atomic emission spectrometry (HPLC-ICP-AES).",
keywords = "METAL-OXIDE ANALOGS, MASS-SPECTROMETRY, TRISUBSTITUTED HETEROPOLYTUNGSTATES, CAPILLARY-ELECTROPHORESIS, KEGGIN-TYPE, ICP-OES, COMPLEXES, POLYOXOANIONS, PHOSPHORUS, SEPARATION",
author = "Shuvaeva, {O. V.} and Zhdanov, {A. A.} and Romanova, {T. E.} and Abramov, {P. A.} and Sokolov, {M. N.}",
year = "2017",
month = mar,
day = "14",
doi = "10.1039/c6dt04843a",
language = "English",
volume = "46",
pages = "3541--3546",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "11",

}

RIS

TY - JOUR

T1 - Hyphenated techniques in speciation analysis of polyoxometalates

T2 - identification of individual [PMo12−xVxO40]−3−x (x = 1-3) in the reaction mixtures by high performance liquid chromatography and atomic emission spectrometry with inductively coupled plasma

AU - Shuvaeva, O. V.

AU - Zhdanov, A. A.

AU - Romanova, T. E.

AU - Abramov, P. A.

AU - Sokolov, M. N.

PY - 2017/3/14

Y1 - 2017/3/14

N2 - Unambiguous identification of polyoxometalate (POM) species generated in self-assembly reactions in solution is rather problematic due to close similarity of their properties such as solubility and spectral characteristics. The situation is made more complex by protonation equilibria (which can change their analytical signals) and the lack of individual compounds to serve as standards for individual members of these mixtures. In the present work a new approach to the study of such POMs has been suggested, taking molybdovanadates [PMo12−xVxO40]−3−x as a model. The key feature of this approach consists of generation of so-called “conditional model systems” that include most of the expected components of a mixture formed by self-assembly, tracked down by reliable detection techniques, e.g., 51V NMR-spectroscopy in this particular case. Then the proposed composition of the mixture is verified and corrected by means of high-performance liquid chromatography coupled with inductively coupled plasma atomic emission spectrometry (HPLC-ICP-AES).

AB - Unambiguous identification of polyoxometalate (POM) species generated in self-assembly reactions in solution is rather problematic due to close similarity of their properties such as solubility and spectral characteristics. The situation is made more complex by protonation equilibria (which can change their analytical signals) and the lack of individual compounds to serve as standards for individual members of these mixtures. In the present work a new approach to the study of such POMs has been suggested, taking molybdovanadates [PMo12−xVxO40]−3−x as a model. The key feature of this approach consists of generation of so-called “conditional model systems” that include most of the expected components of a mixture formed by self-assembly, tracked down by reliable detection techniques, e.g., 51V NMR-spectroscopy in this particular case. Then the proposed composition of the mixture is verified and corrected by means of high-performance liquid chromatography coupled with inductively coupled plasma atomic emission spectrometry (HPLC-ICP-AES).

KW - METAL-OXIDE ANALOGS

KW - MASS-SPECTROMETRY

KW - TRISUBSTITUTED HETEROPOLYTUNGSTATES

KW - CAPILLARY-ELECTROPHORESIS

KW - KEGGIN-TYPE

KW - ICP-OES

KW - COMPLEXES

KW - POLYOXOANIONS

KW - PHOSPHORUS

KW - SEPARATION

UR - http://www.scopus.com/inward/record.url?scp=85015634580&partnerID=8YFLogxK

U2 - 10.1039/c6dt04843a

DO - 10.1039/c6dt04843a

M3 - Article

C2 - 28240339

AN - SCOPUS:85015634580

VL - 46

SP - 3541

EP - 3546

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 11

ER -

ID: 10274111