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Hydrothermal Synthesis and Structure Solution of Na2Ca(CO3)2 : "synthetic Analogue" of Mineral Nyerereite. / Gavryushkin, Pavel N.; Thomas, Victor G.; Bolotina, Nadezhda B. et al.

In: Crystal Growth and Design, Vol. 16, No. 4, 06.04.2016, p. 1893-1902.

Research output: Contribution to journal › Article › peer-review

Harvard

Gavryushkin, PN, Thomas, VG, Bolotina, NB, Bakakin, VV, Golovin, AV, Seryotkin, YV, Fursenko, DA & Litasov, KD 2016, 'Hydrothermal Synthesis and Structure Solution of Na2Ca(CO3)2: "synthetic Analogue" of Mineral Nyerereite', Crystal Growth and Design, vol. 16, no. 4, pp. 1893-1902. https://doi.org/10.1021/acs.cgd.5b01398

APA

Gavryushkin, P. N., Thomas, V. G., Bolotina, N. B., Bakakin, V. V., Golovin, A. V., Seryotkin, Y. V., Fursenko, D. A., & Litasov, K. D. (2016). Hydrothermal Synthesis and Structure Solution of Na2Ca(CO3)2: "synthetic Analogue" of Mineral Nyerereite. Crystal Growth and Design, 16(4), 1893-1902. https://doi.org/10.1021/acs.cgd.5b01398

Vancouver

Gavryushkin PN, Thomas VG, Bolotina NB, Bakakin VV, Golovin AV, Seryotkin YV et al. Hydrothermal Synthesis and Structure Solution of Na2Ca(CO3)2: "synthetic Analogue" of Mineral Nyerereite. Crystal Growth and Design. 2016 Apr 6;16(4):1893-1902. doi: 10.1021/acs.cgd.5b01398

Author

Gavryushkin, Pavel N. ; Thomas, Victor G. ; Bolotina, Nadezhda B. et al. / Hydrothermal Synthesis and Structure Solution of Na2Ca(CO3)2 : "synthetic Analogue" of Mineral Nyerereite. In: Crystal Growth and Design. 2016 ; Vol. 16, No. 4. pp. 1893-1902.

BibTeX

@article{9f6e3927755844cd89e2c8c262aa1b08,
title = "Hydrothermal Synthesis and Structure Solution of Na2Ca(CO3)2: {"}synthetic Analogue{"} of Mineral Nyerereite",
abstract = "Crystals of Na2Ca(CO3)2, the structural analogues of mineral nyerereite, were synthesized using hydrothermal technique at 1 kbar and 450°C. The crystals are transformational twins formed at the transition from the high-temperature hexagonal modification to the low-temperature orthorhombic modification. The structure was solved and refined to R = 0.059 in P21ca (No. 29) space group with a = 10.0713(5) {\AA}, b = 8.7220(2) {\AA}, and c = 12.2460(4) {\AA}. The only structural analogue of the synthesized crystal is the high-temperature modification of K2Ca(CO3)2, which can be considered as a disordered analogue of Na2Ca(CO3)2. Structural analogues among borates and other classes of compounds have not been found. Based on group-subgroup analysis, we propose the structures of high- and intermediate-temperature modifications of Na2Ca(CO3)2. The relations of the determined structure with other polymorphs of Na2Ca(CO3)2 have also been considered.",
author = "Gavryushkin, {Pavel N.} and Thomas, {Victor G.} and Bolotina, {Nadezhda B.} and Bakakin, {Vladimir V.} and Golovin, {Alexander V.} and Seryotkin, {Yurii V.} and Fursenko, {Dmitry A.} and Litasov, {Konstantin D.}",
year = "2016",
month = apr,
day = "6",
doi = "10.1021/acs.cgd.5b01398",
language = "English",
volume = "16",
pages = "1893--1902",
journal = "Crystal Growth and Design",
issn = "1528-7483",
publisher = "American Chemical Society",
number = "4",

}

RIS

TY - JOUR

T1 - Hydrothermal Synthesis and Structure Solution of Na2Ca(CO3)2

T2 - "synthetic Analogue" of Mineral Nyerereite

AU - Gavryushkin, Pavel N.

AU - Thomas, Victor G.

AU - Bolotina, Nadezhda B.

AU - Bakakin, Vladimir V.

AU - Golovin, Alexander V.

AU - Seryotkin, Yurii V.

AU - Fursenko, Dmitry A.

AU - Litasov, Konstantin D.

PY - 2016/4/6

Y1 - 2016/4/6

N2 - Crystals of Na2Ca(CO3)2, the structural analogues of mineral nyerereite, were synthesized using hydrothermal technique at 1 kbar and 450°C. The crystals are transformational twins formed at the transition from the high-temperature hexagonal modification to the low-temperature orthorhombic modification. The structure was solved and refined to R = 0.059 in P21ca (No. 29) space group with a = 10.0713(5) Å, b = 8.7220(2) Å, and c = 12.2460(4) Å. The only structural analogue of the synthesized crystal is the high-temperature modification of K2Ca(CO3)2, which can be considered as a disordered analogue of Na2Ca(CO3)2. Structural analogues among borates and other classes of compounds have not been found. Based on group-subgroup analysis, we propose the structures of high- and intermediate-temperature modifications of Na2Ca(CO3)2. The relations of the determined structure with other polymorphs of Na2Ca(CO3)2 have also been considered.

AB - Crystals of Na2Ca(CO3)2, the structural analogues of mineral nyerereite, were synthesized using hydrothermal technique at 1 kbar and 450°C. The crystals are transformational twins formed at the transition from the high-temperature hexagonal modification to the low-temperature orthorhombic modification. The structure was solved and refined to R = 0.059 in P21ca (No. 29) space group with a = 10.0713(5) Å, b = 8.7220(2) Å, and c = 12.2460(4) Å. The only structural analogue of the synthesized crystal is the high-temperature modification of K2Ca(CO3)2, which can be considered as a disordered analogue of Na2Ca(CO3)2. Structural analogues among borates and other classes of compounds have not been found. Based on group-subgroup analysis, we propose the structures of high- and intermediate-temperature modifications of Na2Ca(CO3)2. The relations of the determined structure with other polymorphs of Na2Ca(CO3)2 have also been considered.

UR - http://www.scopus.com/inward/record.url?scp=84964601638&partnerID=8YFLogxK

U2 - 10.1021/acs.cgd.5b01398

DO - 10.1021/acs.cgd.5b01398

M3 - Article

AN - SCOPUS:84964601638

VL - 16

SP - 1893

EP - 1902

JO - Crystal Growth and Design

JF - Crystal Growth and Design

SN - 1528-7483

IS - 4

ER -

ID: 25761017