Standard

Hydrogenation of furfural to 2-methylfuran over Ni-Mo2c/γ-Al2O3 catalyst. / Smirnov, Andrey A.; Shilov, Ivan N.; Saraev, Andrey A. et al.

In: WSEAS Transactions on Environment and Development, Vol. 15, 21, 01.01.2019, p. 189-196.

Research output: Contribution to journal › Article › peer-review

Harvard

Smirnov, AA, Shilov, IN, Saraev, AA, Kauchev, VV, Bulavchenko, OA, Zavarukhin, SG & Yakovlev, VA 2019, 'Hydrogenation of furfural to 2-methylfuran over Ni-Mo2c/γ-Al2O3 catalyst', WSEAS Transactions on Environment and Development, vol. 15, 21, pp. 189-196.

APA

Smirnov, A. A., Shilov, I. N., Saraev, A. A., Kauchev, V. V., Bulavchenko, O. A., Zavarukhin, S. G., & Yakovlev, V. A. (2019). Hydrogenation of furfural to 2-methylfuran over Ni-Mo2c/γ-Al2O3 catalyst. WSEAS Transactions on Environment and Development, 15, 189-196. [21].

Vancouver

Smirnov AA, Shilov IN, Saraev AA, Kauchev VV, Bulavchenko OA, Zavarukhin SG et al. Hydrogenation of furfural to 2-methylfuran over Ni-Mo2c/γ-Al2O3 catalyst. WSEAS Transactions on Environment and Development. 2019 Jan 1;15:189-196. 21.

Author

Smirnov, Andrey A. ; Shilov, Ivan N. ; Saraev, Andrey A. et al. / Hydrogenation of furfural to 2-methylfuran over Ni-Mo2c/γ-Al2O3 catalyst. In: WSEAS Transactions on Environment and Development. 2019 ; Vol. 15. pp. 189-196.

BibTeX

@article{157e2226ced74cb19f2b50e425503c17,
title = "Hydrogenation of furfural to 2-methylfuran over Ni-Mo2c/γ-Al2O3 catalyst",
abstract = "The current study focuses on the synthesis of a new supported catalyst by impregnation of the γ-Al2O3 solution of Ni and Mo salts and citric acid as carbon resource with the following temperature programmed treatment. Characterization of catalyst composition was performed using XANES/EXAFS method shown the presence of molybdenum carbide and metallic nickel. The oxide form of Mo and Ni were also detected. The supported catalyst was investigated in the hydrogenation reaction of furfural. The free-solution furfural conversion was carried out at a temperature of 160-260 °C and a hydrogen pressure of 5.0 MPa in a fixed bed reactor. The main hydrogenation products were furfuryl alcohol and 2-methylfuran. It was shown that 2-methylfuran formation increases with the reaction temperature and reaches around 75-80%. High temperature leads to fast catalyst deactivation due to polymer formation on its surface.",
keywords = "2-methylfuran, Biomass, Carbide catalyst, Fuel additive, Furfural, Hydrogenation",
author = "Smirnov, {Andrey A.} and Shilov, {Ivan N.} and Saraev, {Andrey A.} and Kauchev, {Vasily V.} and Bulavchenko, {Olga A.} and Zavarukhin, {Sergei G.} and Yakovlev, {Vadim A.}",
note = "Publisher Copyright: {\textcopyright} 2019, World Scientific and Engineering Academy and Society. All rights reserved.",
year = "2019",
month = jan,
day = "1",
language = "English",
volume = "15",
pages = "189--196",
journal = "WSEAS Transactions on Environment and Development",
issn = "1790-5079",
publisher = "World Scientific and Engineering Academy and Society",

}

RIS

TY - JOUR

T1 - Hydrogenation of furfural to 2-methylfuran over Ni-Mo2c/γ-Al2O3 catalyst

AU - Smirnov, Andrey A.

AU - Shilov, Ivan N.

AU - Saraev, Andrey A.

AU - Kauchev, Vasily V.

AU - Bulavchenko, Olga A.

AU - Zavarukhin, Sergei G.

AU - Yakovlev, Vadim A.

N1 - Publisher Copyright: © 2019, World Scientific and Engineering Academy and Society. All rights reserved.

PY - 2019/1/1

Y1 - 2019/1/1

N2 - The current study focuses on the synthesis of a new supported catalyst by impregnation of the γ-Al2O3 solution of Ni and Mo salts and citric acid as carbon resource with the following temperature programmed treatment. Characterization of catalyst composition was performed using XANES/EXAFS method shown the presence of molybdenum carbide and metallic nickel. The oxide form of Mo and Ni were also detected. The supported catalyst was investigated in the hydrogenation reaction of furfural. The free-solution furfural conversion was carried out at a temperature of 160-260 °C and a hydrogen pressure of 5.0 MPa in a fixed bed reactor. The main hydrogenation products were furfuryl alcohol and 2-methylfuran. It was shown that 2-methylfuran formation increases with the reaction temperature and reaches around 75-80%. High temperature leads to fast catalyst deactivation due to polymer formation on its surface.

AB - The current study focuses on the synthesis of a new supported catalyst by impregnation of the γ-Al2O3 solution of Ni and Mo salts and citric acid as carbon resource with the following temperature programmed treatment. Characterization of catalyst composition was performed using XANES/EXAFS method shown the presence of molybdenum carbide and metallic nickel. The oxide form of Mo and Ni were also detected. The supported catalyst was investigated in the hydrogenation reaction of furfural. The free-solution furfural conversion was carried out at a temperature of 160-260 °C and a hydrogen pressure of 5.0 MPa in a fixed bed reactor. The main hydrogenation products were furfuryl alcohol and 2-methylfuran. It was shown that 2-methylfuran formation increases with the reaction temperature and reaches around 75-80%. High temperature leads to fast catalyst deactivation due to polymer formation on its surface.

KW - 2-methylfuran

KW - Biomass

KW - Carbide catalyst

KW - Fuel additive

KW - Furfural

KW - Hydrogenation

UR - http://www.scopus.com/inward/record.url?scp=85070088831&partnerID=8YFLogxK

UR - https://elibrary.ru/item.asp?id=41622856

M3 - Article

AN - SCOPUS:85070088831

VL - 15

SP - 189

EP - 196

JO - WSEAS Transactions on Environment and Development

JF - WSEAS Transactions on Environment and Development

SN - 1790-5079

M1 - 21

ER -

ID: 21144420