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High-pressure synthesis and crystal structure of non-centrosymmetric K2Ca3(CO3)4. / Rashchenko, Sergey V.; Shatskiy, Anton F.; Ignatov, Mark A. et al.

In: CrystEngComm, Vol. 23, No. 38, 14.10.2021, p. 6675-6681.

Research output: Contribution to journal › Article › peer-review

Harvard

Rashchenko, SV, Shatskiy, AF, Ignatov, MA, Arefiev, AV & Litasov, KD 2021, 'High-pressure synthesis and crystal structure of non-centrosymmetric K2Ca3(CO3)4', CrystEngComm, vol. 23, no. 38, pp. 6675-6681. https://doi.org/10.1039/d1ce00882j

APA

Rashchenko, S. V., Shatskiy, A. F., Ignatov, M. A., Arefiev, A. V., & Litasov, K. D. (2021). High-pressure synthesis and crystal structure of non-centrosymmetric K2Ca3(CO3)4. CrystEngComm, 23(38), 6675-6681. https://doi.org/10.1039/d1ce00882j

Vancouver

Rashchenko SV, Shatskiy AF, Ignatov MA, Arefiev AV, Litasov KD. High-pressure synthesis and crystal structure of non-centrosymmetric K2Ca3(CO3)4. CrystEngComm. 2021 Oct 14;23(38):6675-6681. doi: 10.1039/d1ce00882j

Author

Rashchenko, Sergey V. ; Shatskiy, Anton F. ; Ignatov, Mark A. et al. / High-pressure synthesis and crystal structure of non-centrosymmetric K2Ca3(CO3)4. In: CrystEngComm. 2021 ; Vol. 23, No. 38. pp. 6675-6681.

BibTeX

@article{f9a49e8fa5304113bfb7b91c8108b822,
title = "High-pressure synthesis and crystal structure of non-centrosymmetric K2Ca3(CO3)4",
abstract = "A new non-centrosymmetric K2Ca3(CO3)4crystal (P212121,a= 7.3905(2) {\AA},b= 8.8156(3) {\AA},c= 16.4817(5) {\AA}) was synthesized in a multi-anvil press at a pressure of 3 GPa and temperature of 975 °C. The compound is homeotypic to A3B2(BO3)4(A = Ca, Sr, Ba; B = REE, Y, Bi) orthoborates with thePnmasymmetry, but is characterized by the non-centrosymmetric arrangement of (CO3) anions within thePnma-pseudosymmetric cation sublattice. K2Ca3(CO3)4represents a pure carbonate member of the extended M5(XO3)4(X = B, C, B/C) structural type, which also includes A3B2(BO3)4orthoborates as well as recently synthesized mixed orthoborate-carbonates of Ba and Sr. Crystallochemical considerations suggest that cation-substituted (REE, Cs, Sr, and Ba) derivatives of K2Ca3(CO3)4can probably be synthesized at significantly lower pressures than 3 GPa, which is required to stabilize the compound itself.",
author = "Rashchenko, {Sergey V.} and Shatskiy, {Anton F.} and Ignatov, {Mark A.} and Arefiev, {Anton V.} and Litasov, {Konstantin D.}",
note = "Funding Information: The reported study was funded by RFBR and FWF according to the research project #21-55-14001. The SEM and EDS studies were performed in the Analytical Center for Multi-element and Isotope Research SB RAS. The XRD study was done using the equipment of Research and Education Centre “Molecular Design and Ecologically Safe Technologies” at Novosibirsk State University. The authors also thank two anonymous reviewers for their constructive criticism. Funding Information: The reported study was funded by RFBR and FWF according to the research project #21-55-14001. The SEM and EDS studies were performed in the Analytical Center for Multi-element and Isotope Research SB RAS. The XRD study was done using the equipment of Research and Education Centre ?Molecular Design and Ecologically Safe Technologies? at Novosibirsk State University. The authors also thank two anonymous reviewers for their constructive criticism. Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2021.",
year = "2021",
month = oct,
day = "14",
doi = "10.1039/d1ce00882j",
language = "English",
volume = "23",
pages = "6675--6681",
journal = "CrystEngComm",
issn = "1466-8033",
publisher = "Royal Society of Chemistry",
number = "38",

}

RIS

TY - JOUR

T1 - High-pressure synthesis and crystal structure of non-centrosymmetric K2Ca3(CO3)4

AU - Rashchenko, Sergey V.

AU - Shatskiy, Anton F.

AU - Ignatov, Mark A.

AU - Arefiev, Anton V.

AU - Litasov, Konstantin D.

N1 - Funding Information: The reported study was funded by RFBR and FWF according to the research project #21-55-14001. The SEM and EDS studies were performed in the Analytical Center for Multi-element and Isotope Research SB RAS. The XRD study was done using the equipment of Research and Education Centre “Molecular Design and Ecologically Safe Technologies” at Novosibirsk State University. The authors also thank two anonymous reviewers for their constructive criticism. Funding Information: The reported study was funded by RFBR and FWF according to the research project #21-55-14001. The SEM and EDS studies were performed in the Analytical Center for Multi-element and Isotope Research SB RAS. The XRD study was done using the equipment of Research and Education Centre ?Molecular Design and Ecologically Safe Technologies? at Novosibirsk State University. The authors also thank two anonymous reviewers for their constructive criticism. Publisher Copyright: © The Royal Society of Chemistry 2021.

PY - 2021/10/14

Y1 - 2021/10/14

N2 - A new non-centrosymmetric K2Ca3(CO3)4crystal (P212121,a= 7.3905(2) Å,b= 8.8156(3) Å,c= 16.4817(5) Å) was synthesized in a multi-anvil press at a pressure of 3 GPa and temperature of 975 °C. The compound is homeotypic to A3B2(BO3)4(A = Ca, Sr, Ba; B = REE, Y, Bi) orthoborates with thePnmasymmetry, but is characterized by the non-centrosymmetric arrangement of (CO3) anions within thePnma-pseudosymmetric cation sublattice. K2Ca3(CO3)4represents a pure carbonate member of the extended M5(XO3)4(X = B, C, B/C) structural type, which also includes A3B2(BO3)4orthoborates as well as recently synthesized mixed orthoborate-carbonates of Ba and Sr. Crystallochemical considerations suggest that cation-substituted (REE, Cs, Sr, and Ba) derivatives of K2Ca3(CO3)4can probably be synthesized at significantly lower pressures than 3 GPa, which is required to stabilize the compound itself.

AB - A new non-centrosymmetric K2Ca3(CO3)4crystal (P212121,a= 7.3905(2) Å,b= 8.8156(3) Å,c= 16.4817(5) Å) was synthesized in a multi-anvil press at a pressure of 3 GPa and temperature of 975 °C. The compound is homeotypic to A3B2(BO3)4(A = Ca, Sr, Ba; B = REE, Y, Bi) orthoborates with thePnmasymmetry, but is characterized by the non-centrosymmetric arrangement of (CO3) anions within thePnma-pseudosymmetric cation sublattice. K2Ca3(CO3)4represents a pure carbonate member of the extended M5(XO3)4(X = B, C, B/C) structural type, which also includes A3B2(BO3)4orthoborates as well as recently synthesized mixed orthoborate-carbonates of Ba and Sr. Crystallochemical considerations suggest that cation-substituted (REE, Cs, Sr, and Ba) derivatives of K2Ca3(CO3)4can probably be synthesized at significantly lower pressures than 3 GPa, which is required to stabilize the compound itself.

UR - http://www.scopus.com/inward/record.url?scp=85116689200&partnerID=8YFLogxK

U2 - 10.1039/d1ce00882j

DO - 10.1039/d1ce00882j

M3 - Article

AN - SCOPUS:85116689200

VL - 23

SP - 6675

EP - 6681

JO - CrystEngComm

JF - CrystEngComm

SN - 1466-8033

IS - 38

ER -

ID: 34409708