Research output: Contribution to journal › Article › peer-review
Highly Proton-Conductive Zinc Metal-Organic Framework Based On Nickel(II) Porphyrinylphosphonate. / Enakieva, Yulia Y.; Sinelshchikova, Anna A.; Grigoriev, Mikhail S. et al.
In: Chemistry - A European Journal, Vol. 25, No. 45, 09.08.2019, p. 10552-10556.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Highly Proton-Conductive Zinc Metal-Organic Framework Based On Nickel(II) Porphyrinylphosphonate
AU - Enakieva, Yulia Y.
AU - Sinelshchikova, Anna A.
AU - Grigoriev, Mikhail S.
AU - Chernyshev, Vladimir V.
AU - Kovalenko, Konstantin A.
AU - Stenina, Irina A.
AU - Yaroslavtsev, Andrey B.
AU - Gorbunova, Yulia G.
AU - Tsivadze, Aslan Y.
N1 - © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
PY - 2019/8/9
Y1 - 2019/8/9
N2 - The design of new solid-state proton-conducting materials is a great challenge for chemistry and materials science. Herein, a new anionic porphyrinylphosphonate-based MOF (IPCE-1Ni), which involves dimethylammonium (DMA) cations for charge compensation, is reported. As a result of its unique structure, IPCE-1Ni exhibits one of the highest value of the proton conductivity among reported proton-conducting MOF materials based on porphyrins (1.55×10−3 S cm−1 at 75 °C and 80 % relative humidity).
AB - The design of new solid-state proton-conducting materials is a great challenge for chemistry and materials science. Herein, a new anionic porphyrinylphosphonate-based MOF (IPCE-1Ni), which involves dimethylammonium (DMA) cations for charge compensation, is reported. As a result of its unique structure, IPCE-1Ni exhibits one of the highest value of the proton conductivity among reported proton-conducting MOF materials based on porphyrins (1.55×10−3 S cm−1 at 75 °C and 80 % relative humidity).
KW - conducting materials
KW - metal-organic frameworks
KW - porous materials
KW - porphyrinylphosphonates
KW - proton conductivity
KW - ACID
KW - PHOSPHONATES
KW - LUMINESCENT
KW - SUPERPROTONIC CONDUCTIVITY
KW - CRYSTALLINE
KW - TOOL
UR - http://www.scopus.com/inward/record.url?scp=85068404274&partnerID=8YFLogxK
U2 - 10.1002/chem.201902212
DO - 10.1002/chem.201902212
M3 - Article
C2 - 31095805
AN - SCOPUS:85068404274
VL - 25
SP - 10552
EP - 10556
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
SN - 0947-6539
IS - 45
ER -
ID: 20780175