Standard

Highly active CuFeAl-containing catalysts for selective hydrogenation of furfural to furfuryl alcohol. / Selishcheva, Svetlana A.; Smirnov, Andrey A.; Fedorov, Alexander V. et al.

In: Catalysts, Vol. 9, No. 10, 816, 01.10.2019.

Research output: Contribution to journal › Article › peer-review

Harvard

Selishcheva, SA, Smirnov, AA, Fedorov, AV, Bulavchenko, OA, Saraev, AA, Lebedev, MY & Yakovlev, VA 2019, 'Highly active CuFeAl-containing catalysts for selective hydrogenation of furfural to furfuryl alcohol', Catalysts, vol. 9, no. 10, 816. https://doi.org/10.3390/catal9100816

APA

Selishcheva, S. A., Smirnov, A. A., Fedorov, A. V., Bulavchenko, O. A., Saraev, A. A., Lebedev, M. Y., & Yakovlev, V. A. (2019). Highly active CuFeAl-containing catalysts for selective hydrogenation of furfural to furfuryl alcohol. Catalysts, 9(10), [816]. https://doi.org/10.3390/catal9100816

Vancouver

Selishcheva SA, Smirnov AA, Fedorov AV, Bulavchenko OA, Saraev AA, Lebedev MY et al. Highly active CuFeAl-containing catalysts for selective hydrogenation of furfural to furfuryl alcohol. Catalysts. 2019 Oct 1;9(10):816. doi: 10.3390/catal9100816

Author

Selishcheva, Svetlana A. ; Smirnov, Andrey A. ; Fedorov, Alexander V. et al. / Highly active CuFeAl-containing catalysts for selective hydrogenation of furfural to furfuryl alcohol. In: Catalysts. 2019 ; Vol. 9, No. 10.

BibTeX

@article{b3e1b49b06c34aa084af858ee528ee83,
title = "Highly active CuFeAl-containing catalysts for selective hydrogenation of furfural to furfuryl alcohol",
abstract = "CuFe-containing catalysts with different copper oxide content were prepared by fusion of metal salts. The obtained catalyst showed high activity in the hydrogenation of furfural to furfuryl alcohol (FA) in the batch reactor in the presence of isopropanol as a solvent at a temperature of 100 °C and a hydrogen pressure of 6.0 MPa. The yield of FA and furfural conversion are 97% and 98%, respectively. In the solvent-free reaction in the flow-type reactor; the most active catalyst Cu20Fe66Al14 leads to the 96% formation of FA with 100% conversion of furfural at liquid hourly space velocity (LHSV) = 1 h-1; 160 °C and a hydrogen pressure of 5.0 MPa during 30 h. According to the X-ray diffraction (XRD) method, the active component of the spent and fresh Cu20Fe66Al14 catalyst is the same and is represented by metallic copper and Fe3O4-type spinel. Using different methods, the formation of active sites was investigated.",
keywords = "CuFe-containing catalyst, Furfural, Furfuryl alcohol, Hydrogenation, furfuryl alcohol, CU/SIO2 CATALYSTS, CONVERSION, furfural, PHASE HYDROGENATION, KINETICS, hydrogenation, FE",
author = "Selishcheva, {Svetlana A.} and Smirnov, {Andrey A.} and Fedorov, {Alexander V.} and Bulavchenko, {Olga A.} and Saraev, {Andrey A.} and Lebedev, {Maksim Yu} and Yakovlev, {Vadim A.}",
year = "2019",
month = oct,
day = "1",
doi = "10.3390/catal9100816",
language = "English",
volume = "9",
journal = "Catalysts",
issn = "2073-4344",
publisher = "MDPI AG",
number = "10",

}

RIS

TY - JOUR

T1 - Highly active CuFeAl-containing catalysts for selective hydrogenation of furfural to furfuryl alcohol

AU - Selishcheva, Svetlana A.

AU - Smirnov, Andrey A.

AU - Fedorov, Alexander V.

AU - Bulavchenko, Olga A.

AU - Saraev, Andrey A.

AU - Lebedev, Maksim Yu

AU - Yakovlev, Vadim A.

PY - 2019/10/1

Y1 - 2019/10/1

N2 - CuFe-containing catalysts with different copper oxide content were prepared by fusion of metal salts. The obtained catalyst showed high activity in the hydrogenation of furfural to furfuryl alcohol (FA) in the batch reactor in the presence of isopropanol as a solvent at a temperature of 100 °C and a hydrogen pressure of 6.0 MPa. The yield of FA and furfural conversion are 97% and 98%, respectively. In the solvent-free reaction in the flow-type reactor; the most active catalyst Cu20Fe66Al14 leads to the 96% formation of FA with 100% conversion of furfural at liquid hourly space velocity (LHSV) = 1 h-1; 160 °C and a hydrogen pressure of 5.0 MPa during 30 h. According to the X-ray diffraction (XRD) method, the active component of the spent and fresh Cu20Fe66Al14 catalyst is the same and is represented by metallic copper and Fe3O4-type spinel. Using different methods, the formation of active sites was investigated.

AB - CuFe-containing catalysts with different copper oxide content were prepared by fusion of metal salts. The obtained catalyst showed high activity in the hydrogenation of furfural to furfuryl alcohol (FA) in the batch reactor in the presence of isopropanol as a solvent at a temperature of 100 °C and a hydrogen pressure of 6.0 MPa. The yield of FA and furfural conversion are 97% and 98%, respectively. In the solvent-free reaction in the flow-type reactor; the most active catalyst Cu20Fe66Al14 leads to the 96% formation of FA with 100% conversion of furfural at liquid hourly space velocity (LHSV) = 1 h-1; 160 °C and a hydrogen pressure of 5.0 MPa during 30 h. According to the X-ray diffraction (XRD) method, the active component of the spent and fresh Cu20Fe66Al14 catalyst is the same and is represented by metallic copper and Fe3O4-type spinel. Using different methods, the formation of active sites was investigated.

KW - CuFe-containing catalyst

KW - Furfural

KW - Furfuryl alcohol

KW - Hydrogenation

KW - furfuryl alcohol

KW - CU/SIO2 CATALYSTS

KW - CONVERSION

KW - furfural

KW - PHASE HYDROGENATION

KW - KINETICS

KW - hydrogenation

KW - FE

UR - http://www.scopus.com/inward/record.url?scp=85073593795&partnerID=8YFLogxK

U2 - 10.3390/catal9100816

DO - 10.3390/catal9100816

M3 - Article

AN - SCOPUS:85073593795

VL - 9

JO - Catalysts

JF - Catalysts

SN - 2073-4344

IS - 10

M1 - 816

ER -

ID: 21938300