Standard

Highly active carbon-supported Ni catalyst prepared by nitrate decomposition with a sacrificial agent for the hydrogen oxidation reaction in alkaline medium. / Simonov, Pavel A.; Cherstiouk, Olga V.; Kuznetsov, Aleksey N. et al.

In: Journal of Electroanalytical Chemistry, Vol. 852, 113551, 01.11.2019.

Research output: Contribution to journal › Article › peer-review

Harvard

Simonov, PA, Cherstiouk, OV, Kuznetsov, AN, Zaikovskii, VI, Kardash, TY, Oshchepkov, AG, Bonnefont, A & Savinova, ER 2019, 'Highly active carbon-supported Ni catalyst prepared by nitrate decomposition with a sacrificial agent for the hydrogen oxidation reaction in alkaline medium', Journal of Electroanalytical Chemistry, vol. 852, 113551. https://doi.org/10.1016/j.jelechem.2019.113551

APA

Simonov, P. A., Cherstiouk, O. V., Kuznetsov, A. N., Zaikovskii, V. I., Kardash, T. Y., Oshchepkov, A. G., Bonnefont, A., & Savinova, E. R. (2019). Highly active carbon-supported Ni catalyst prepared by nitrate decomposition with a sacrificial agent for the hydrogen oxidation reaction in alkaline medium. Journal of Electroanalytical Chemistry, 852, [113551]. https://doi.org/10.1016/j.jelechem.2019.113551

Vancouver

Simonov PA, Cherstiouk OV, Kuznetsov AN, Zaikovskii VI, Kardash TY, Oshchepkov AG et al. Highly active carbon-supported Ni catalyst prepared by nitrate decomposition with a sacrificial agent for the hydrogen oxidation reaction in alkaline medium. Journal of Electroanalytical Chemistry. 2019 Nov 1;852:113551. doi: 10.1016/j.jelechem.2019.113551

Author

Simonov, Pavel A. ; Cherstiouk, Olga V. ; Kuznetsov, Aleksey N. et al. / Highly active carbon-supported Ni catalyst prepared by nitrate decomposition with a sacrificial agent for the hydrogen oxidation reaction in alkaline medium. In: Journal of Electroanalytical Chemistry. 2019 ; Vol. 852.

BibTeX

@article{e83ea3625ccb42ea816b2cb89eea7b7c,
title = "Highly active carbon-supported Ni catalyst prepared by nitrate decomposition with a sacrificial agent for the hydrogen oxidation reaction in alkaline medium",
abstract = "Ketjenblack EC-600 JD supported Ni/C electrocatalysts with a nickel content of 50 and 60 wt% were prepared by impregnation with either Ni(OAc)2 or a mixture of Ni(OAc)2 and Ni(NO3)2 precursors, followed by freeze-drying and reduction with H2. XRD, TEM and cyclic voltammetry were applied for characterizing the catalysts. The use of Ni(OAc)2 as a sacrificial agent during decomposition of Ni(NO3)2 allows one to decrease significantly the size of nickel nanoparticles (from 37 to 12 nm) at a very high metal loading. Benefiting from the high dispersion and high specific activity, 60 % Ni/Ketjenblack EC-600 JD possesses remarkable mass activity (7 A∙g−1 Ni) in the hydrogen oxidation reaction in an alkaline electrolyte.",
keywords = "Alkaline solutions, Hydrogen oxidation reaction, Ketjenblack DJ-600, Lyophilization, Nickel, EVOLUTION, PARTICLES, ELECTRODE-REACTIONS, KINETICS, NICKEL NANOPARTICLES, ELECTROCATALYSTS",
author = "Simonov, {Pavel A.} and Cherstiouk, {Olga V.} and Kuznetsov, {Aleksey N.} and Zaikovskii, {Vladimir I.} and Kardash, {Tatyana Yu} and Oshchepkov, {Alexandr G.} and Antoine Bonnefont and Savinova, {Elena R.}",
note = "Publisher Copyright: {\textcopyright} 2019 Elsevier B.V.",
year = "2019",
month = nov,
day = "1",
doi = "10.1016/j.jelechem.2019.113551",
language = "English",
volume = "852",
journal = "Journal of Electroanalytical Chemistry",
issn = "1572-6657",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Highly active carbon-supported Ni catalyst prepared by nitrate decomposition with a sacrificial agent for the hydrogen oxidation reaction in alkaline medium

AU - Simonov, Pavel A.

AU - Cherstiouk, Olga V.

AU - Kuznetsov, Aleksey N.

AU - Zaikovskii, Vladimir I.

AU - Kardash, Tatyana Yu

AU - Oshchepkov, Alexandr G.

AU - Bonnefont, Antoine

AU - Savinova, Elena R.

N1 - Publisher Copyright: © 2019 Elsevier B.V.

PY - 2019/11/1

Y1 - 2019/11/1

N2 - Ketjenblack EC-600 JD supported Ni/C electrocatalysts with a nickel content of 50 and 60 wt% were prepared by impregnation with either Ni(OAc)2 or a mixture of Ni(OAc)2 and Ni(NO3)2 precursors, followed by freeze-drying and reduction with H2. XRD, TEM and cyclic voltammetry were applied for characterizing the catalysts. The use of Ni(OAc)2 as a sacrificial agent during decomposition of Ni(NO3)2 allows one to decrease significantly the size of nickel nanoparticles (from 37 to 12 nm) at a very high metal loading. Benefiting from the high dispersion and high specific activity, 60 % Ni/Ketjenblack EC-600 JD possesses remarkable mass activity (7 A∙g−1 Ni) in the hydrogen oxidation reaction in an alkaline electrolyte.

AB - Ketjenblack EC-600 JD supported Ni/C electrocatalysts with a nickel content of 50 and 60 wt% were prepared by impregnation with either Ni(OAc)2 or a mixture of Ni(OAc)2 and Ni(NO3)2 precursors, followed by freeze-drying and reduction with H2. XRD, TEM and cyclic voltammetry were applied for characterizing the catalysts. The use of Ni(OAc)2 as a sacrificial agent during decomposition of Ni(NO3)2 allows one to decrease significantly the size of nickel nanoparticles (from 37 to 12 nm) at a very high metal loading. Benefiting from the high dispersion and high specific activity, 60 % Ni/Ketjenblack EC-600 JD possesses remarkable mass activity (7 A∙g−1 Ni) in the hydrogen oxidation reaction in an alkaline electrolyte.

KW - Alkaline solutions

KW - Hydrogen oxidation reaction

KW - Ketjenblack DJ-600

KW - Lyophilization

KW - Nickel

KW - EVOLUTION

KW - PARTICLES

KW - ELECTRODE-REACTIONS

KW - KINETICS

KW - NICKEL NANOPARTICLES

KW - ELECTROCATALYSTS

UR - http://www.scopus.com/inward/record.url?scp=85073095203&partnerID=8YFLogxK

U2 - 10.1016/j.jelechem.2019.113551

DO - 10.1016/j.jelechem.2019.113551

M3 - Article

AN - SCOPUS:85073095203

VL - 852

JO - Journal of Electroanalytical Chemistry

JF - Journal of Electroanalytical Chemistry

SN - 1572-6657

M1 - 113551

ER -

ID: 21848196