Research output: Contribution to journal › Article › peer-review
Heterometallic molecular complex [Co2Gd(NO3)(piv)6(py)2] and coordination polymer [{CoGd(dma)2}2(bdc)5]·4DMA : the synthesis, structure, and properties. / Sapianik, A. A.; Lutsenko, I. A.; Kiskin, M. A. et al.
In: Russian Chemical Bulletin, Vol. 65, No. 11, 01.11.2016, p. 2601-2606.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Heterometallic molecular complex [Co2Gd(NO3)(piv)6(py)2] and coordination polymer [{CoGd(dma)2}2(bdc)5]·4DMA
T2 - the synthesis, structure, and properties
AU - Sapianik, A. A.
AU - Lutsenko, I. A.
AU - Kiskin, M. A.
AU - Sidorov, A. A.
AU - Eremenko, I. L.
AU - Samsonenko, D. G.
AU - Dybtsev, D. N.
AU - Fedin, V. P.
PY - 2016/11/1
Y1 - 2016/11/1
N2 - A new heterometallic molecular complex [Co2Gd(NO3)(piv)6(py)2] (1, piv = –O2CBut, py = pyridine) was synthesized. Its reaction with terephthalic acid (H2bdc) in N,N-dimethylacetamide (DMA) results in metal-organic coordination polymer [{CoGd(dma)2}2(bdc)5]·4DMA (2). The crystal structures of 1 and 2 were determined by single-crystal X-ray diffraction analysis. The structure of 2 has two types of channels (4×8 Å and 5×16 Å) that are occupied by coordinated and guest DMA molecules.
AB - A new heterometallic molecular complex [Co2Gd(NO3)(piv)6(py)2] (1, piv = –O2CBut, py = pyridine) was synthesized. Its reaction with terephthalic acid (H2bdc) in N,N-dimethylacetamide (DMA) results in metal-organic coordination polymer [{CoGd(dma)2}2(bdc)5]·4DMA (2). The crystal structures of 1 and 2 were determined by single-crystal X-ray diffraction analysis. The structure of 2 has two types of channels (4×8 Å and 5×16 Å) that are occupied by coordinated and guest DMA molecules.
KW - carboxylate complexes
KW - cobalt
KW - coordination polymers
KW - gadolinium
KW - metal-organic frameworks
KW - polynuclear complexes
KW - pyridine
KW - single-crystal X-ray diffraction analysis
KW - terephthalic acid
UR - http://www.scopus.com/inward/record.url?scp=85019184266&partnerID=8YFLogxK
U2 - 10.1007/s11172-016-1624-4
DO - 10.1007/s11172-016-1624-4
M3 - Article
AN - SCOPUS:85019184266
VL - 65
SP - 2601
EP - 2606
JO - Russian Chemical Bulletin
JF - Russian Chemical Bulletin
SN - 1066-5285
IS - 11
ER -
ID: 25417824