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Heterometallic molecular complex [Co2Gd(NO3)(piv)6(py)2] and coordination polymer [{CoGd(dma)2}2(bdc)5]·4DMA : the synthesis, structure, and properties. / Sapianik, A. A.; Lutsenko, I. A.; Kiskin, M. A. et al.

In: Russian Chemical Bulletin, Vol. 65, No. 11, 01.11.2016, p. 2601-2606.

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Sapianik AA, Lutsenko IA, Kiskin MA, Sidorov AA, Eremenko IL, Samsonenko DG et al. Heterometallic molecular complex [Co2Gd(NO3)(piv)6(py)2] and coordination polymer [{CoGd(dma)2}2(bdc)5]·4DMA: the synthesis, structure, and properties. Russian Chemical Bulletin. 2016 Nov 1;65(11):2601-2606. doi: 10.1007/s11172-016-1624-4

Author

Sapianik, A. A. ; Lutsenko, I. A. ; Kiskin, M. A. et al. / Heterometallic molecular complex [Co2Gd(NO3)(piv)6(py)2] and coordination polymer [{CoGd(dma)2}2(bdc)5]·4DMA : the synthesis, structure, and properties. In: Russian Chemical Bulletin. 2016 ; Vol. 65, No. 11. pp. 2601-2606.

BibTeX

@article{f4df5a5e86ce40de910400649c79f1c5,
title = "Heterometallic molecular complex [Co2Gd(NO3)(piv)6(py)2] and coordination polymer [{CoGd(dma)2}2(bdc)5]·4DMA: the synthesis, structure, and properties",
abstract = "A new heterometallic molecular complex [Co2Gd(NO3)(piv)6(py)2] (1, piv = –O2CBut, py = pyridine) was synthesized. Its reaction with terephthalic acid (H2bdc) in N,N-dimethylacetamide (DMA) results in metal-organic coordination polymer [{CoGd(dma)2}2(bdc)5]·4DMA (2). The crystal structures of 1 and 2 were determined by single-crystal X-ray diffraction analysis. The structure of 2 has two types of channels (4×8 {\AA} and 5×16 {\AA}) that are occupied by coordinated and guest DMA molecules.",
keywords = "carboxylate complexes, cobalt, coordination polymers, gadolinium, metal-organic frameworks, polynuclear complexes, pyridine, single-crystal X-ray diffraction analysis, terephthalic acid",
author = "Sapianik, {A. A.} and Lutsenko, {I. A.} and Kiskin, {M. A.} and Sidorov, {A. A.} and Eremenko, {I. L.} and Samsonenko, {D. G.} and Dybtsev, {D. N.} and Fedin, {V. P.}",
year = "2016",
month = nov,
day = "1",
doi = "10.1007/s11172-016-1624-4",
language = "English",
volume = "65",
pages = "2601--2606",
journal = "Russian Chemical Bulletin",
issn = "1066-5285",
publisher = "Springer Nature",
number = "11",

}

RIS

TY - JOUR

T1 - Heterometallic molecular complex [Co2Gd(NO3)(piv)6(py)2] and coordination polymer [{CoGd(dma)2}2(bdc)5]·4DMA

T2 - the synthesis, structure, and properties

AU - Sapianik, A. A.

AU - Lutsenko, I. A.

AU - Kiskin, M. A.

AU - Sidorov, A. A.

AU - Eremenko, I. L.

AU - Samsonenko, D. G.

AU - Dybtsev, D. N.

AU - Fedin, V. P.

PY - 2016/11/1

Y1 - 2016/11/1

N2 - A new heterometallic molecular complex [Co2Gd(NO3)(piv)6(py)2] (1, piv = –O2CBut, py = pyridine) was synthesized. Its reaction with terephthalic acid (H2bdc) in N,N-dimethylacetamide (DMA) results in metal-organic coordination polymer [{CoGd(dma)2}2(bdc)5]·4DMA (2). The crystal structures of 1 and 2 were determined by single-crystal X-ray diffraction analysis. The structure of 2 has two types of channels (4×8 Å and 5×16 Å) that are occupied by coordinated and guest DMA molecules.

AB - A new heterometallic molecular complex [Co2Gd(NO3)(piv)6(py)2] (1, piv = –O2CBut, py = pyridine) was synthesized. Its reaction with terephthalic acid (H2bdc) in N,N-dimethylacetamide (DMA) results in metal-organic coordination polymer [{CoGd(dma)2}2(bdc)5]·4DMA (2). The crystal structures of 1 and 2 were determined by single-crystal X-ray diffraction analysis. The structure of 2 has two types of channels (4×8 Å and 5×16 Å) that are occupied by coordinated and guest DMA molecules.

KW - carboxylate complexes

KW - cobalt

KW - coordination polymers

KW - gadolinium

KW - metal-organic frameworks

KW - polynuclear complexes

KW - pyridine

KW - single-crystal X-ray diffraction analysis

KW - terephthalic acid

UR - http://www.scopus.com/inward/record.url?scp=85019184266&partnerID=8YFLogxK

U2 - 10.1007/s11172-016-1624-4

DO - 10.1007/s11172-016-1624-4

M3 - Article

AN - SCOPUS:85019184266

VL - 65

SP - 2601

EP - 2606

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

IS - 11

ER -

ID: 25417824