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Heteroleptic Dithiocarbamato–Chlorido Gold(III) Complexes [Au(S2CNR2)Cl2] (R = CH3, iso-C3H7; R2 = (CH2)6) : Synthesis, Supramolecular Structures, and Thermal Behavior. / Loseva, O. V.; Rodina, T. A.; Ivanov, A. V. et al.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 44, No. 10, 01.10.2018, p. 604-612.

Research output: Contribution to journal › Article › peer-review

Harvard

Loseva, OV, Rodina, TA, Ivanov, AV, Lutsenko, IA, Korneeva, EV, Gerasimenko, AV & Smolentsev, AI 2018, 'Heteroleptic Dithiocarbamato–Chlorido Gold(III) Complexes [Au(S2CNR2)Cl2] (R = CH3, iso-C3H7; R2 = (CH2)6): Synthesis, Supramolecular Structures, and Thermal Behavior', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 44, no. 10, pp. 604-612. https://doi.org/10.1134/S107032841810007X

APA

Loseva, O. V., Rodina, T. A., Ivanov, A. V., Lutsenko, I. A., Korneeva, E. V., Gerasimenko, A. V., & Smolentsev, A. I. (2018). Heteroleptic Dithiocarbamato–Chlorido Gold(III) Complexes [Au(S2CNR2)Cl2] (R = CH3, iso-C3H7; R2 = (CH2)6): Synthesis, Supramolecular Structures, and Thermal Behavior. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 44(10), 604-612. https://doi.org/10.1134/S107032841810007X

Vancouver

Loseva OV, Rodina TA, Ivanov AV, Lutsenko IA, Korneeva EV, Gerasimenko AV et al. Heteroleptic Dithiocarbamato–Chlorido Gold(III) Complexes [Au(S2CNR2)Cl2] (R = CH3, iso-C3H7; R2 = (CH2)6): Synthesis, Supramolecular Structures, and Thermal Behavior. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2018 Oct 1;44(10):604-612. doi: 10.1134/S107032841810007X

Author

Loseva, O. V. ; Rodina, T. A. ; Ivanov, A. V. et al. / Heteroleptic Dithiocarbamato–Chlorido Gold(III) Complexes [Au(S2CNR2)Cl2] (R = CH3, iso-C3H7; R2 = (CH2)6) : Synthesis, Supramolecular Structures, and Thermal Behavior. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2018 ; Vol. 44, No. 10. pp. 604-612.

BibTeX

@article{1c461869d618450680144a2d6be117d9,
title = "Heteroleptic Dithiocarbamato–Chlorido Gold(III) Complexes [Au(S2CNR2)Cl2] (R = CH3, iso-C3H7; R2 = (CH2)6): Synthesis, Supramolecular Structures, and Thermal Behavior",
abstract = "Abstract: The chemisorption binding of gold(III) by freshly precipitated binuclear zinc dithiocarbamates [Zn2(S2CNR2)4] from solutions in 2 M HCl makes it possible to obtain heteroligand complexes [Au(S2CNR2)Cl2]: R = CH3 (I), iso-C3H7 (II); R2 = (CH2)6 (III). The structural organization of complexes I, II, and III is determined by X-ray diffraction analysis (CIF files CCDC no. 1813107, 1813369, and 1813108, respectively). The distorted square–planar structure of the cis-[AuS2Cl2] chromophores shows the low-spin dsp2-hybrid state of the central gold atom. Pairwise secondary interactions Au⋅⋅⋅S between the adjacent molecules in complexes I and III result in the building of zigzag polymer chains (⋅⋅⋅[Au{S2CN(CH3)2}Cl2]⋅⋅⋅)n and binuclear aggregates [Au{S2CN(CH2)6}Cl2]2 at the supramolecular level. Complex II is presented by discrete molecules [Au{S2CN(iso-C3H7)2}Cl2]. According to the simultaneous thermal analysis data, the single final product of the thermolysis of compounds I–III is reduced elemental gold.",
keywords = "complex-chemisorbents, forms of gold binding from solutions, heteroleptic dithiocarbamato–chlorido gold(III) complexes, secondary interactions Au⋅⋅⋅S, simultaneous thermal analysis, supramolecular self-organization, secondary interactions Au center dot center dot center dot S, ANTICANCER AGENTS, CRYSTAL-STRUCTURE, ELECTRON-PARAMAGNETIC-RES, GOLD COMPLEXES, heteroleptic dithiocarbamato-chlorido gold(III) complexes, ZINC, PROTEASOME, POLYNUCLEAR, CYTOTOXICITY, BINDING, DERIVATIVES",
author = "Loseva, {O. V.} and Rodina, {T. A.} and Ivanov, {A. V.} and Lutsenko, {I. A.} and Korneeva, {E. V.} and Gerasimenko, {A. V.} and Smolentsev, {A. I.}",
note = "Publisher Copyright: {\textcopyright} 2018, Pleiades Publishing, Ltd.",
year = "2018",
month = oct,
day = "1",
doi = "10.1134/S107032841810007X",
language = "English",
volume = "44",
pages = "604--612",
journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",
issn = "1070-3284",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "10",

}

RIS

TY - JOUR

T1 - Heteroleptic Dithiocarbamato–Chlorido Gold(III) Complexes [Au(S2CNR2)Cl2] (R = CH3, iso-C3H7; R2 = (CH2)6)

T2 - Synthesis, Supramolecular Structures, and Thermal Behavior

AU - Loseva, O. V.

AU - Rodina, T. A.

AU - Ivanov, A. V.

AU - Lutsenko, I. A.

AU - Korneeva, E. V.

AU - Gerasimenko, A. V.

AU - Smolentsev, A. I.

N1 - Publisher Copyright: © 2018, Pleiades Publishing, Ltd.

PY - 2018/10/1

Y1 - 2018/10/1

N2 - Abstract: The chemisorption binding of gold(III) by freshly precipitated binuclear zinc dithiocarbamates [Zn2(S2CNR2)4] from solutions in 2 M HCl makes it possible to obtain heteroligand complexes [Au(S2CNR2)Cl2]: R = CH3 (I), iso-C3H7 (II); R2 = (CH2)6 (III). The structural organization of complexes I, II, and III is determined by X-ray diffraction analysis (CIF files CCDC no. 1813107, 1813369, and 1813108, respectively). The distorted square–planar structure of the cis-[AuS2Cl2] chromophores shows the low-spin dsp2-hybrid state of the central gold atom. Pairwise secondary interactions Au⋅⋅⋅S between the adjacent molecules in complexes I and III result in the building of zigzag polymer chains (⋅⋅⋅[Au{S2CN(CH3)2}Cl2]⋅⋅⋅)n and binuclear aggregates [Au{S2CN(CH2)6}Cl2]2 at the supramolecular level. Complex II is presented by discrete molecules [Au{S2CN(iso-C3H7)2}Cl2]. According to the simultaneous thermal analysis data, the single final product of the thermolysis of compounds I–III is reduced elemental gold.

AB - Abstract: The chemisorption binding of gold(III) by freshly precipitated binuclear zinc dithiocarbamates [Zn2(S2CNR2)4] from solutions in 2 M HCl makes it possible to obtain heteroligand complexes [Au(S2CNR2)Cl2]: R = CH3 (I), iso-C3H7 (II); R2 = (CH2)6 (III). The structural organization of complexes I, II, and III is determined by X-ray diffraction analysis (CIF files CCDC no. 1813107, 1813369, and 1813108, respectively). The distorted square–planar structure of the cis-[AuS2Cl2] chromophores shows the low-spin dsp2-hybrid state of the central gold atom. Pairwise secondary interactions Au⋅⋅⋅S between the adjacent molecules in complexes I and III result in the building of zigzag polymer chains (⋅⋅⋅[Au{S2CN(CH3)2}Cl2]⋅⋅⋅)n and binuclear aggregates [Au{S2CN(CH2)6}Cl2]2 at the supramolecular level. Complex II is presented by discrete molecules [Au{S2CN(iso-C3H7)2}Cl2]. According to the simultaneous thermal analysis data, the single final product of the thermolysis of compounds I–III is reduced elemental gold.

KW - complex-chemisorbents

KW - forms of gold binding from solutions

KW - heteroleptic dithiocarbamato–chlorido gold(III) complexes

KW - secondary interactions Au⋅⋅⋅S

KW - simultaneous thermal analysis

KW - supramolecular self-organization

KW - secondary interactions Au center dot center dot center dot S

KW - ANTICANCER AGENTS

KW - CRYSTAL-STRUCTURE

KW - ELECTRON-PARAMAGNETIC-RES

KW - GOLD COMPLEXES

KW - heteroleptic dithiocarbamato-chlorido gold(III) complexes

KW - ZINC

KW - PROTEASOME

KW - POLYNUCLEAR

KW - CYTOTOXICITY

KW - BINDING

KW - DERIVATIVES

UR - http://www.scopus.com/inward/record.url?scp=85054516702&partnerID=8YFLogxK

U2 - 10.1134/S107032841810007X

DO - 10.1134/S107032841810007X

M3 - Article

AN - SCOPUS:85054516702

VL - 44

SP - 604

EP - 612

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 10

ER -

ID: 17038447