Standard

Heterogeneous catalysts for hydrogenation of CO2 and bicarbonates to formic acid and formates. / Bulushev, Dmitri A.; Ross, Julian R.H.

In: Catalysis Reviews - Science and Engineering, Vol. 60, No. 4, 02.10.2018, p. 566-593.

Research output: Contribution to journal › Article › peer-review

Harvard

Bulushev, DA & Ross, JRH 2018, 'Heterogeneous catalysts for hydrogenation of CO2 and bicarbonates to formic acid and formates', Catalysis Reviews - Science and Engineering, vol. 60, no. 4, pp. 566-593. https://doi.org/10.1080/01614940.2018.1476806

APA

Bulushev, D. A., & Ross, J. R. H. (2018). Heterogeneous catalysts for hydrogenation of CO2 and bicarbonates to formic acid and formates. Catalysis Reviews - Science and Engineering, 60(4), 566-593. https://doi.org/10.1080/01614940.2018.1476806

Vancouver

Bulushev DA, Ross JRH. Heterogeneous catalysts for hydrogenation of CO2 and bicarbonates to formic acid and formates. Catalysis Reviews - Science and Engineering. 2018 Oct 2;60(4):566-593. doi: 10.1080/01614940.2018.1476806

Author

Bulushev, Dmitri A. ; Ross, Julian R.H. / Heterogeneous catalysts for hydrogenation of CO2 and bicarbonates to formic acid and formates. In: Catalysis Reviews - Science and Engineering. 2018 ; Vol. 60, No. 4. pp. 566-593.

BibTeX

@article{56face790b8344ec8c34c868e2f272ab,
title = "Heterogeneous catalysts for hydrogenation of CO2 and bicarbonates to formic acid and formates",
abstract = "Formic acid and formates are often produced by hydrogenation of CO2 with hydrogen over homogeneous catalysts. The present review reports recent achievements in utilization of heterogeneous catalysts. It shows that highly dispersed supported metal catalysts are able to carry out this reaction by providing activation of hydrogen on the metal sites and activation of CO2 or bicarbonate on the support sites. Important advances have recently been achieved through utilization of catalysts using CxNy materials as supports. The high activity of these catalysts could be assigned to their ability to stabilize the active metal in a state of single-metal atoms or heterogenized metal complexes, which may demonstrate a higher activity than metal atoms on the surface of metal nanoparticles.",
keywords = "CO hydrogenation, formic acid, heterogeneous catalysts, production, ROOM-TEMPERATURE, N-DOPED CARBON, SODIUM-BICARBONATE, AQUEOUS-SOLUTIONS, WET OXIDATION, PD/C CATALYST, SUPPORTED PALLADIUM NANOPARTICLES, DIOXIDE HYDROGENATION, REACTION-KINETICS, AEROBIC OXIDATION, CO2 hydrogenation",
author = "Bulushev, {Dmitri A.} and Ross, {Julian R.H.}",
year = "2018",
month = oct,
day = "2",
doi = "10.1080/01614940.2018.1476806",
language = "English",
volume = "60",
pages = "566--593",
journal = "Catalysis Reviews - Science and Engineering",
issn = "0161-4940",
publisher = "Taylor and Francis Ltd.",
number = "4",

}

RIS

TY - JOUR

T1 - Heterogeneous catalysts for hydrogenation of CO2 and bicarbonates to formic acid and formates

AU - Bulushev, Dmitri A.

AU - Ross, Julian R.H.

PY - 2018/10/2

Y1 - 2018/10/2

N2 - Formic acid and formates are often produced by hydrogenation of CO2 with hydrogen over homogeneous catalysts. The present review reports recent achievements in utilization of heterogeneous catalysts. It shows that highly dispersed supported metal catalysts are able to carry out this reaction by providing activation of hydrogen on the metal sites and activation of CO2 or bicarbonate on the support sites. Important advances have recently been achieved through utilization of catalysts using CxNy materials as supports. The high activity of these catalysts could be assigned to their ability to stabilize the active metal in a state of single-metal atoms or heterogenized metal complexes, which may demonstrate a higher activity than metal atoms on the surface of metal nanoparticles.

AB - Formic acid and formates are often produced by hydrogenation of CO2 with hydrogen over homogeneous catalysts. The present review reports recent achievements in utilization of heterogeneous catalysts. It shows that highly dispersed supported metal catalysts are able to carry out this reaction by providing activation of hydrogen on the metal sites and activation of CO2 or bicarbonate on the support sites. Important advances have recently been achieved through utilization of catalysts using CxNy materials as supports. The high activity of these catalysts could be assigned to their ability to stabilize the active metal in a state of single-metal atoms or heterogenized metal complexes, which may demonstrate a higher activity than metal atoms on the surface of metal nanoparticles.

KW - CO hydrogenation

KW - formic acid

KW - heterogeneous catalysts

KW - production

KW - ROOM-TEMPERATURE

KW - N-DOPED CARBON

KW - SODIUM-BICARBONATE

KW - AQUEOUS-SOLUTIONS

KW - WET OXIDATION

KW - PD/C CATALYST

KW - SUPPORTED PALLADIUM NANOPARTICLES

KW - DIOXIDE HYDROGENATION

KW - REACTION-KINETICS

KW - AEROBIC OXIDATION

KW - CO2 hydrogenation

UR - http://www.scopus.com/inward/record.url?scp=85047914440&partnerID=8YFLogxK

U2 - 10.1080/01614940.2018.1476806

DO - 10.1080/01614940.2018.1476806

M3 - Article

AN - SCOPUS:85047914440

VL - 60

SP - 566

EP - 593

JO - Catalysis Reviews - Science and Engineering

JF - Catalysis Reviews - Science and Engineering

SN - 0161-4940

IS - 4

ER -

ID: 13754570