Standard

Halogen Contacts-Induced Unusual Coloring in BiIII Bromide Complex : Anion-to-Cation Charge Transfer via Br⋅⋅⋅Br Interactions. / Adonin, Sergey A.; Gorokh, Igor D.; Novikov, Alexander S. et al.

In: Chemistry - A European Journal, Vol. 23, No. 62, 07.11.2017, p. 15612-15616.

Research output: Contribution to journal › Article › peer-review

Harvard

Adonin, SA, Gorokh, ID, Novikov, AS, Abramov, PA, Sokolov, MN & Fedin, VP 2017, 'Halogen Contacts-Induced Unusual Coloring in BiIII Bromide Complex: Anion-to-Cation Charge Transfer via Br⋅⋅⋅Br Interactions', Chemistry - A European Journal, vol. 23, no. 62, pp. 15612-15616. https://doi.org/10.1002/chem.201703747

APA

Adonin, S. A., Gorokh, I. D., Novikov, A. S., Abramov, P. A., Sokolov, M. N., & Fedin, V. P. (2017). Halogen Contacts-Induced Unusual Coloring in BiIII Bromide Complex: Anion-to-Cation Charge Transfer via Br⋅⋅⋅Br Interactions. Chemistry - A European Journal, 23(62), 15612-15616. https://doi.org/10.1002/chem.201703747

Vancouver

Adonin SA, Gorokh ID, Novikov AS, Abramov PA, Sokolov MN, Fedin VP. Halogen Contacts-Induced Unusual Coloring in BiIII Bromide Complex: Anion-to-Cation Charge Transfer via Br⋅⋅⋅Br Interactions. Chemistry - A European Journal. 2017 Nov 7;23(62):15612-15616. doi: 10.1002/chem.201703747

Author

Adonin, Sergey A. ; Gorokh, Igor D. ; Novikov, Alexander S. et al. / Halogen Contacts-Induced Unusual Coloring in BiIII Bromide Complex : Anion-to-Cation Charge Transfer via Br⋅⋅⋅Br Interactions. In: Chemistry - A European Journal. 2017 ; Vol. 23, No. 62. pp. 15612-15616.

BibTeX

@article{64c91556d8074b9191504ecb00ec7752,
title = "Halogen Contacts-Induced Unusual Coloring in BiIII Bromide Complex: Anion-to-Cation Charge Transfer via Br⋅⋅⋅Br Interactions",
abstract = "A yellow bromobismuthate {(2-BrPy)2H}[BiBr4] (1, 2-BrPy=2-bromopyridinium) transforms into the unusually deeply colored cherry-red (2-BrPyH)2[BiBr5] (2). A combination of structural studies and theoretical calculations confirms that the appearance of short non-covalent Br⋅⋅⋅Br interactions (≈3.3 {\AA}) in 2 is responsible for the anion-to-cation charge transfer (LP(Brligand)→σ*(Br-C)), yielding dramatic changes in optical behavior. This effect opens the way towards novel halogen bonding-templated halometalate-based hybrid materials with enhanced optical properties.",
keywords = "charge transfer, DFT calculations, halogen bonding, halometalates, QTAIM, DRIVEN PHOTOCATALYTIC PROPERTIES, RECOGNITION, PHOTOCHROMISM, CRYSTAL-STRUCTURES, HALIDE PEROVSKITES, SUPRAMOLECULAR CHEMISTRY, TEMPERATURE, RECEPTORS, HYBRID, VIOLOGEN",
author = "Adonin, {Sergey A.} and Gorokh, {Igor D.} and Novikov, {Alexander S.} and Abramov, {Pavel A.} and Sokolov, {Maxim N.} and Fedin, {Vladimir P.}",
note = "Publisher Copyright: {\textcopyright} 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",
year = "2017",
month = nov,
day = "7",
doi = "10.1002/chem.201703747",
language = "English",
volume = "23",
pages = "15612--15616",
journal = "Chemistry - A European Journal",
issn = "0947-6539",
publisher = "Wiley-VCH Verlag",
number = "62",

}

RIS

TY - JOUR

T1 - Halogen Contacts-Induced Unusual Coloring in BiIII Bromide Complex

T2 - Anion-to-Cation Charge Transfer via Br⋅⋅⋅Br Interactions

AU - Adonin, Sergey A.

AU - Gorokh, Igor D.

AU - Novikov, Alexander S.

AU - Abramov, Pavel A.

AU - Sokolov, Maxim N.

AU - Fedin, Vladimir P.

N1 - Publisher Copyright: © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

PY - 2017/11/7

Y1 - 2017/11/7

N2 - A yellow bromobismuthate {(2-BrPy)2H}[BiBr4] (1, 2-BrPy=2-bromopyridinium) transforms into the unusually deeply colored cherry-red (2-BrPyH)2[BiBr5] (2). A combination of structural studies and theoretical calculations confirms that the appearance of short non-covalent Br⋅⋅⋅Br interactions (≈3.3 Å) in 2 is responsible for the anion-to-cation charge transfer (LP(Brligand)→σ*(Br-C)), yielding dramatic changes in optical behavior. This effect opens the way towards novel halogen bonding-templated halometalate-based hybrid materials with enhanced optical properties.

AB - A yellow bromobismuthate {(2-BrPy)2H}[BiBr4] (1, 2-BrPy=2-bromopyridinium) transforms into the unusually deeply colored cherry-red (2-BrPyH)2[BiBr5] (2). A combination of structural studies and theoretical calculations confirms that the appearance of short non-covalent Br⋅⋅⋅Br interactions (≈3.3 Å) in 2 is responsible for the anion-to-cation charge transfer (LP(Brligand)→σ*(Br-C)), yielding dramatic changes in optical behavior. This effect opens the way towards novel halogen bonding-templated halometalate-based hybrid materials with enhanced optical properties.

KW - charge transfer

KW - DFT calculations

KW - halogen bonding

KW - halometalates

KW - QTAIM

KW - DRIVEN PHOTOCATALYTIC PROPERTIES

KW - RECOGNITION

KW - PHOTOCHROMISM

KW - CRYSTAL-STRUCTURES

KW - HALIDE PEROVSKITES

KW - SUPRAMOLECULAR CHEMISTRY

KW - TEMPERATURE

KW - RECEPTORS

KW - HYBRID

KW - VIOLOGEN

UR - http://www.scopus.com/inward/record.url?scp=85031320277&partnerID=8YFLogxK

U2 - 10.1002/chem.201703747

DO - 10.1002/chem.201703747

M3 - Article

C2 - 28940361

AN - SCOPUS:85031320277

VL - 23

SP - 15612

EP - 15616

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

IS - 62

ER -

ID: 8968598