Research output: Contribution to journal › Article › peer-review
Halloysite Nanoclay Based CdS Formulations with High Catalytic Activity in Hydrogen Evolution Reaction under Visible Light Irradiation. / Vinokurov, Vladimir A.; Stavitskaya, Anna V.; Ivanov, Evgenii V. et al.
In: ACS Sustainable Chemistry and Engineering, Vol. 5, No. 12, 04.12.2017, p. 11316-11323.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Halloysite Nanoclay Based CdS Formulations with High Catalytic Activity in Hydrogen Evolution Reaction under Visible Light Irradiation
AU - Vinokurov, Vladimir A.
AU - Stavitskaya, Anna V.
AU - Ivanov, Evgenii V.
AU - Gushchin, Pavel A.
AU - Kozlov, Denis V.
AU - Kurenkova, Anna Yu
AU - Kolinko, Pavel A.
AU - Kozlova, Ekaterina A.
AU - Lvov, Yuri M.
N1 - Publisher Copyright: © 2017 American Chemical Society.
PY - 2017/12/4
Y1 - 2017/12/4
N2 - An efficient and an easily scalable photocatalyst with CdS nanoparticles placed on the outer surface and inside halloysite clay nanotubes with cadmium sulfide content of ca. 3 wt % was developed. The CdS/halloysite core-shell tubule nanocomposites showed a superior catalytic activity and a high stability in the release of hydrogen under visible radiation without cocatalysts or noble metal doping. The specific activity was of 20 mmol of hydrogen per hour per gram of CdS. The suggested approach opens the way to an inexpensive production of highly efficient mesoporous catalyst based on a natural, abundantly available clay support.
AB - An efficient and an easily scalable photocatalyst with CdS nanoparticles placed on the outer surface and inside halloysite clay nanotubes with cadmium sulfide content of ca. 3 wt % was developed. The CdS/halloysite core-shell tubule nanocomposites showed a superior catalytic activity and a high stability in the release of hydrogen under visible radiation without cocatalysts or noble metal doping. The specific activity was of 20 mmol of hydrogen per hour per gram of CdS. The suggested approach opens the way to an inexpensive production of highly efficient mesoporous catalyst based on a natural, abundantly available clay support.
KW - Cadmium sulfide
KW - Clay
KW - Halloysite nanotubes
KW - Hydrogen
KW - Photocatalysis
KW - OXIDATION
KW - GRAPHENE OXIDE
KW - AQUEOUS-SOLUTIONS
KW - MICROSPHERES
KW - CADMIUM-SULFIDE
KW - HETEROSTRUCTURES
KW - COMPOSITES
KW - PHOTOCATALYTIC H-2 EVOLUTION
KW - NANOTUBES
KW - WATER
UR - http://www.scopus.com/inward/record.url?scp=85041090513&partnerID=8YFLogxK
U2 - 10.1021/acssuschemeng.7b02272
DO - 10.1021/acssuschemeng.7b02272
M3 - Article
AN - SCOPUS:85041090513
VL - 5
SP - 11316
EP - 11323
JO - ACS Sustainable Chemistry and Engineering
JF - ACS Sustainable Chemistry and Engineering
SN - 2168-0485
IS - 12
ER -
ID: 9976677