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Growth and Optical Properties of LixNa1-xBa12(BO3)7F4 Fluoride Borates with “Antizeolite” Structure. / Bekker, Tatyana B.; Rashchenko, Sergey V.; Solntsev, Vladimir P. et al.

In: Inorganic Chemistry, Vol. 56, No. 9, 01.05.2017, p. 5411-5419.

Research output: Contribution to journal › Article › peer-review

Harvard

Bekker, TB, Rashchenko, SV, Solntsev, VP, Yelisseyev, AP, Kragzhda, AA, Bakakin, VV, Seryotkin, YV, Kokh, AE, Kokh, KA & Kuznetsov, AB 2017, 'Growth and Optical Properties of LixNa1-xBa12(BO3)7F4 Fluoride Borates with “Antizeolite” Structure', Inorganic Chemistry, vol. 56, no. 9, pp. 5411-5419. https://doi.org/10.1021/acs.inorgchem.7b00520

APA

Bekker, T. B., Rashchenko, S. V., Solntsev, V. P., Yelisseyev, A. P., Kragzhda, A. A., Bakakin, V. V., Seryotkin, Y. V., Kokh, A. E., Kokh, K. A., & Kuznetsov, A. B. (2017). Growth and Optical Properties of LixNa1-xBa12(BO3)7F4 Fluoride Borates with “Antizeolite” Structure. Inorganic Chemistry, 56(9), 5411-5419. https://doi.org/10.1021/acs.inorgchem.7b00520

Vancouver

Bekker TB, Rashchenko SV, Solntsev VP, Yelisseyev AP, Kragzhda AA, Bakakin VV et al. Growth and Optical Properties of LixNa1-xBa12(BO3)7F4 Fluoride Borates with “Antizeolite” Structure. Inorganic Chemistry. 2017 May 1;56(9):5411-5419. doi: 10.1021/acs.inorgchem.7b00520

Author

Bekker, Tatyana B. ; Rashchenko, Sergey V. ; Solntsev, Vladimir P. et al. / Growth and Optical Properties of LixNa1-xBa12(BO3)7F4 Fluoride Borates with “Antizeolite” Structure. In: Inorganic Chemistry. 2017 ; Vol. 56, No. 9. pp. 5411-5419.

BibTeX

@article{082cadb59f7f43efb52ef7f1c5a3226c,
title = "Growth and Optical Properties of LixNa1-xBa12(BO3)7F4 Fluoride Borates with “Antizeolite” Structure",
abstract = "Studied LixNa1-xBa12(BO3)7F4 (P42bc) solid solution belongs to the new class of “antizeolite” borates with [Ba12(BO3)6]6+ cation pattern, which contains channels filled by anionic clusters. Optical-quality crystals were grown from the compositions with different sodium-lithium ratio. The results of Rietveld refinement based on powder data demonstrate linear increase of parameter a and unit cell volume with Na/(Na + Li) ratio in cation site. Parameter c is less sensitive to the changes in stoichiometry, which is consistent with channel topology of LixNa1-xBa12(BO3)7F4 structure. Distinctive feature of LixNa1-xBa12(BO3)7F4 crystals is their deep purple color, which is due to both hole-type and electron-type centers. Crystals are characterized by linear dichroism effect.",
keywords = "CRYSTAL, MAYENITE, ELECTRIDE",
author = "Bekker, {Tatyana B.} and Rashchenko, {Sergey V.} and Solntsev, {Vladimir P.} and Yelisseyev, {Alexander P.} and Kragzhda, {Alexander A.} and Bakakin, {Vladimir V.} and Seryotkin, {Yuriy V.} and Kokh, {Alexander E.} and Kokh, {Konstantin A.} and Kuznetsov, {Artem B.}",
year = "2017",
month = may,
day = "1",
doi = "10.1021/acs.inorgchem.7b00520",
language = "English",
volume = "56",
pages = "5411--5419",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "9",

}

RIS

TY - JOUR

T1 - Growth and Optical Properties of LixNa1-xBa12(BO3)7F4 Fluoride Borates with “Antizeolite” Structure

AU - Bekker, Tatyana B.

AU - Rashchenko, Sergey V.

AU - Solntsev, Vladimir P.

AU - Yelisseyev, Alexander P.

AU - Kragzhda, Alexander A.

AU - Bakakin, Vladimir V.

AU - Seryotkin, Yuriy V.

AU - Kokh, Alexander E.

AU - Kokh, Konstantin A.

AU - Kuznetsov, Artem B.

PY - 2017/5/1

Y1 - 2017/5/1

N2 - Studied LixNa1-xBa12(BO3)7F4 (P42bc) solid solution belongs to the new class of “antizeolite” borates with [Ba12(BO3)6]6+ cation pattern, which contains channels filled by anionic clusters. Optical-quality crystals were grown from the compositions with different sodium-lithium ratio. The results of Rietveld refinement based on powder data demonstrate linear increase of parameter a and unit cell volume with Na/(Na + Li) ratio in cation site. Parameter c is less sensitive to the changes in stoichiometry, which is consistent with channel topology of LixNa1-xBa12(BO3)7F4 structure. Distinctive feature of LixNa1-xBa12(BO3)7F4 crystals is their deep purple color, which is due to both hole-type and electron-type centers. Crystals are characterized by linear dichroism effect.

AB - Studied LixNa1-xBa12(BO3)7F4 (P42bc) solid solution belongs to the new class of “antizeolite” borates with [Ba12(BO3)6]6+ cation pattern, which contains channels filled by anionic clusters. Optical-quality crystals were grown from the compositions with different sodium-lithium ratio. The results of Rietveld refinement based on powder data demonstrate linear increase of parameter a and unit cell volume with Na/(Na + Li) ratio in cation site. Parameter c is less sensitive to the changes in stoichiometry, which is consistent with channel topology of LixNa1-xBa12(BO3)7F4 structure. Distinctive feature of LixNa1-xBa12(BO3)7F4 crystals is their deep purple color, which is due to both hole-type and electron-type centers. Crystals are characterized by linear dichroism effect.

KW - CRYSTAL

KW - MAYENITE

KW - ELECTRIDE

UR - http://www.scopus.com/inward/record.url?scp=85018939122&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.7b00520

DO - 10.1021/acs.inorgchem.7b00520

M3 - Article

AN - SCOPUS:85018939122

VL - 56

SP - 5411

EP - 5419

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 9

ER -

ID: 10193915