Research output: Contribution to journal › Article › peer-review
Gold(III) phthalocyanine chloride : Optical and structural characterization of thin films. / Basova, Tamara V.; Parkhomenko, Roman G.; Krasnov, Pavel O. et al.
In: Dyes and Pigments, Vol. 122, 4780, 27.07.2015, p. 280-285.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Gold(III) phthalocyanine chloride
T2 - Optical and structural characterization of thin films
AU - Basova, Tamara V.
AU - Parkhomenko, Roman G.
AU - Krasnov, Pavel O.
AU - Igumenov, Igor K.
AU - Kadem, Burak
AU - Hassan, Aseel K.
PY - 2015/7/27
Y1 - 2015/7/27
N2 - In the present work, the investigation of gold(III) phthalocyanine chloride (AuClPc) which received very little attention before is progressed further using a range of optical spectroscopic techniques. Thin films of gold(III) phthalocyanine chloride were produced by organic molecular beam deposition deposition and their structure was investigated by UV-visible spectroscopy, polarization dependent Raman spectroscopy and atomic force microscopy. Experimental observations were confirmed by theoretical analysis using quantum chemical calculations; the latter were used for the detailed assignment of different bands in IR spectra of the gold(III) phthalocyanine chloride. The orientation of gold(III) phthalocyanine chloride molecules relative to the substrate surface was studied in detail using techniques based on the polarization dependent Raman spectroscopy. It was shown that gold(III) phthalocyanine chloride films deposited on quartz substrates at 100 °C exhibit a co-facial structure with the average tilt angles of Pc moieties of ∼70°.
AB - In the present work, the investigation of gold(III) phthalocyanine chloride (AuClPc) which received very little attention before is progressed further using a range of optical spectroscopic techniques. Thin films of gold(III) phthalocyanine chloride were produced by organic molecular beam deposition deposition and their structure was investigated by UV-visible spectroscopy, polarization dependent Raman spectroscopy and atomic force microscopy. Experimental observations were confirmed by theoretical analysis using quantum chemical calculations; the latter were used for the detailed assignment of different bands in IR spectra of the gold(III) phthalocyanine chloride. The orientation of gold(III) phthalocyanine chloride molecules relative to the substrate surface was studied in detail using techniques based on the polarization dependent Raman spectroscopy. It was shown that gold(III) phthalocyanine chloride films deposited on quartz substrates at 100 °C exhibit a co-facial structure with the average tilt angles of Pc moieties of ∼70°.
KW - DFT calculations
KW - Gold phthalocyanine
KW - Optical spectroscopy
KW - Polarized Raman spectroscopy
KW - Structure of thin films
KW - Vibrational spectroscopy
UR - http://www.scopus.com/inward/record.url?scp=84937895680&partnerID=8YFLogxK
U2 - 10.1016/j.dyepig.2015.05.017
DO - 10.1016/j.dyepig.2015.05.017
M3 - Article
AN - SCOPUS:84937895680
VL - 122
SP - 280
EP - 285
JO - Dyes and Pigments
JF - Dyes and Pigments
SN - 0143-7208
M1 - 4780
ER -
ID: 25436375